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Book Chapter
Liquid Metal and Solid Metal Induced Embrittlement
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003554
EISBN: 978-1-62708-180-1
... Abstract Metal-induced embrittlement is a phenomenon in which the ductility or fracture stress of a solid metal is reduced by surface contact with another metal in either liquid or solid form. This article summarizes the characteristics of solid metal induced embrittlement (SMIE) and liquid...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or fracture stress of a solid metal is reduced by surface contact with another metal in either liquid or solid form. This article summarizes the characteristics of solid metal induced embrittlement (SMIE) and liquid metal induced embrittlement (LMIE). It describes the unique features that assist in arriving at a clear conclusion whether SMIE or LMIE is the most probable cause of the problem. The article briefly reviews some commercial alloy systems where LMIE or SMIE has been documented. It also provides some examples of cracking due to these phenomena, either in manufacturing or in service.
Book Chapter
Liquid-Metal- and Solid-Metal-Induced Embrittlement
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006786
EISBN: 978-1-62708-295-2
... Abstract Metal-induced embrittlement is a phenomenon in which the ductility or the fracture stress of a solid metal is reduced by surface contact with another metal in either the liquid or solid form. This article summarizes some of the characteristics of liquid-metal- and solid-metal-induced...
Abstract
Metal-induced embrittlement is a phenomenon in which the ductility or the fracture stress of a solid metal is reduced by surface contact with another metal in either the liquid or solid form. This article summarizes some of the characteristics of liquid-metal- and solid-metal-induced embrittlement. This phenomenon shares many of these characteristics with other modes of environmentally induced cracking, such as hydrogen embrittlement and stress-corrosion cracking. The discussion covers the occurrence, failure analysis, and service failures of the embrittlement. The article also briefly reviews some commercial alloy systems in which liquid-metal-induced embrittlement or solid-metal-induced embrittlement has been documented and describes some examples of cracking due to these phenomena, either in manufacturing or in service.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003635
EISBN: 978-1-62708-182-5
... Abstract Liquid metal induced embrittlement (LMIE) is the reduction of the fracture resistance of a solid material during exposure to a liquid metal. This article discusses the mechanisms and occurrence condition of LMIE and describes the effects of metallurgical factors, such as grain size...
Abstract
Liquid metal induced embrittlement (LMIE) is the reduction of the fracture resistance of a solid material during exposure to a liquid metal. This article discusses the mechanisms and occurrence condition of LMIE and describes the effects of metallurgical factors, such as grain size, temperature and strain rate, stress, inert carriers, and fatigue, on LMIE. It provides a detailed discussion on LMIE in ferrous and nonferrous metals and their alloys. In addition, the article highlights the ways of preventing embrittlement in metals and alloys.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003636
EISBN: 978-1-62708-182-5
... Abstract Embrittlement that occurs below the melting point of the embrittling species is known as solid metal induced embrittlement (SMIE) of metals. This article provides a discussion on the characteristics and investigations of SMIE, liquid metal induced embrittlement, and delayed failure...
Abstract
Embrittlement that occurs below the melting point of the embrittling species is known as solid metal induced embrittlement (SMIE) of metals. This article provides a discussion on the characteristics and investigations of SMIE, liquid metal induced embrittlement, and delayed failure. It also describes the mechanism of SMIE.
Image
Liquid-metal-induced embrittlement and cracking evidence that occurred duri...
Available to PurchasePublished: 01 January 2002
Fig. 33 Liquid-metal-induced embrittlement and cracking evidence that occurred during torch brazing. 2% nital etch. 119×
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Image
Liquid-metal-induced embrittlement and cracking evidence that occurred duri...
Available to PurchasePublished: 15 January 2021
Fig. 36 Liquid-metal-induced embrittlement and cracking evidence that occurred during torch brazing. 2% nital etch. Original magnification: 119×
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Image
Liquid-metal-induced embrittlement that occurred in a galvanized steel comp...
Available to PurchasePublished: 01 June 2024
Fig. 26 Liquid-metal-induced embrittlement that occurred in a galvanized steel component. Cracking was spontaneous and intergranular where the molten zinc had entered the grain boundaries. Some of the morphology was coated with zinc. Original magnification: 500×
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Image
Copper-induced liquid metal embrittlement in a 0.5 wt% carbon steel that oc...
Available to PurchasePublished: 15 January 2021
Fig. 48 Copper-induced liquid metal embrittlement in a 0.5 wt% carbon steel that occurred when the steel was in contact with liquid copper at 1100 °C (2010 °F). 2% nital etch
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Zinc-induced liquid metal embrittlement in 321 austenitic stainless steel. ...
Available to PurchasePublished: 15 January 2021
Fig. 49 Zinc-induced liquid metal embrittlement in 321 austenitic stainless steel. Etched in Vilella's reagent
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Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001039
EISBN: 978-1-62708-161-0
... form of embrittlement and influences the behavior and properties of nearly all ferrous alloys and many metals. The article explains why hydrogen embrittlement is so widespread and reviews the many types of damage it can cause. It also explores other forms of embrittlement, including metal-induced...
Abstract
This article examines the embrittlement of iron and carbon steels. It describes compositional, processing, and service conditions that contribute to the problem and presents examples of how embrittlement influences mechanical properties. Embrittlement due to hydrogen is the most common form of embrittlement and influences the behavior and properties of nearly all ferrous alloys and many metals. The article explains why hydrogen embrittlement is so widespread and reviews the many types of damage it can cause. It also explores other forms of embrittlement, including metal-induced embrittlement, strain-age and aluminum nitride embrittlement, thermal embrittlement, quench cracking, 475 deg C and sigma phase embrittlement (in FeCr alloys), temper embrittlement, and embrittlement caused by neutron irradiation. In addition, the article covers stress-corrosion cracking along with properties and conditions that affect it, and the procedures to detect and evaluate it.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003632
EISBN: 978-1-62708-182-5
... to as hydrogen embrittlement), liquid-metal embrittlement, and solid metal induced embrittlement. In general, these different phenomena show many similarities, and it would at first seem appropriate to propose an all-encompassing mechanism to account for these behaviors. For example, all of these phenomena...
Abstract
This article discusses the fundamental aspects of environmentally induced cracking. It provides a theoretical basis for the evaluation, testing, and methods of protection against the cracking. The article describes the mechanisms of corrosion that produce cracking of metals and intermetallic compounds as a result of exposure to their environment.
Book Chapter
Introduction to Forms of Corrosion
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003603
EISBN: 978-1-62708-182-5
... is often externally applied. For hydrogen damage, liquid metal induced embrittlement, and solid metal induced embrittlement, the stress is induced by reactions with the environment. Microbiologically Influenced Corrosion The final article “Microbiologically Influenced Corrosion,” discusses...
Abstract
Corrosion is classified into two categories: corrosion that is not influenced by any other process and corrosion that is influenced by another process such as the presence of stresses or erosion. This article discusses uniform corrosion, localized corrosion, metallurgically influenced corrosion, and microbiologically influenced corrosion, which fit under the classification of corrosion that is not influenced by any outside process. It also explains mechanically assisted degradation and environmentally induced cracking, which fit under the classification of corrosion that is influenced by an outside process.
Image
Cadmium-plated 4140 steel nuts from a military jet engine that failed by li...
Available to PurchasePublished: 30 August 2021
Fig. 16 Cadmium-plated 4140 steel nuts from a military jet engine that failed by liquid metal induced embrittlement. (a) Fragmented and cracked nuts. (b) Typical fracture surface. (c) Electron fractograph showing brittle intergranular failure
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Image
Failed Ti-6Al-4V shear fasteners. The fasteners were cadmium plated for gal...
Available to PurchasePublished: 15 January 2021
Fig. 7 Failed Ti-6Al-4V shear fasteners. The fasteners were cadmium plated for galvanic compatibility with the aluminum structure. (a) Photograph showing failure at the head-to-shank fillet. (b) Intergranular fracture morphology. Failure was attributed to liquid-metal-induced embrittlement
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Image
Service failure of a low-alloy steel nut by liquid-metal-induced embrittlem...
Available to PurchasePublished: 15 January 2021
Fig. 4 Service failure of a low-alloy steel nut by liquid-metal-induced embrittlement (LMIE). Cadmium-plated, 4140 low-alloy steel (44 HRC) nuts were inadvertently used on bolts for clamps used to join ducts that carried hot (500 °C, or 930 °F) air from the compressor of a military jet engine
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Image
Failed nose landing gear socket assembly due to liquid-metal-induced embrit...
Available to PurchasePublished: 15 January 2021
Fig. 5 Failed nose landing gear socket assembly due to liquid-metal-induced embrittlement (LMIE). (a) Overall view of the air-melted 4330 steel landing gear axle socket. Arrow A indicates the fractured lug; arrow B, the bent but unfailed lug. Arrow C indicates the annealed A-286 steel
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Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006828
EISBN: 978-1-62708-329-4
... (3000 °F). Before these developments (circa 1950), the upper limit of the brazing process did not exceed 1150 °C (2100 °F). Some examples of problems to consider in filler-metal selection are the liquid metal induced embrittlement tendency of titanium alloys and nickel-base alloys brazed with silver...
Abstract
The various methods of furnace, torch, induction, resistance, dip, and laser brazing are used to produce a wide range of highly reliable brazed assemblies. However, imperfections that can lead to braze failure may result if proper attention is not paid to the physical properties of the material, joint design, prebraze cleaning, brazing procedures, postbraze cleaning, and quality control. Factors that must be considered include brazeability of the base metals; joint design and fit-up; filler-metal selection; prebraze cleaning; brazing temperature, time, atmosphere, or flux; conditions of the faying surfaces; postbraze cleaning; and service conditions. This article focuses on the advantages, limitations, sources of failure, and anomalies resulting from the brazing process. It discusses the processes involved in the testing and inspection required of the braze joint or assembly.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006777
EISBN: 978-1-62708-295-2
... Hydrogen embrittlement by grain-boundary absorption of hydrogen Stress-corrosion cracking, can be intergranular or transgranular Liquid metal induced embrittlement, for example, mercury in brass, lithium in 304 stainless steel Solid metal induced embrittlement Low-melting-temperature elements...
Abstract
This article briefly reviews the factors that influence the occurrence of intergranular (IG) fractures. Because the appearance of IG fractures is often very similar, the principal focus is placed on the various metallurgical or environmental factors that cause grain boundaries to become the preferred path of crack growth. The article describes in more detail some typical mechanisms that cause IG fracture. It discusses the causes and effects of IG brittle cracking, dimpled IG fracture, IG fatigue, hydrogen embrittlement, and IG stress-corrosion cracking. The article presents a case history on IG fracture of steam generator tubes, where a lowering of the operating temperature was proposed to reduce failures.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003540
EISBN: 978-1-62708-180-1
... absorption of hydrogen Stress-corrosion cracking (sometimes) Liquid metal induced embrittlement (LMIE), for example, mercury in brass, lithium in 304 stainless steel Solid metal induced embrittlement (SMIE) The following sections describe more detail of some typical embrittlement mechanisms...
Abstract
This article briefly reviews the various metallurgical or environmental factors that cause a weakening of the grain boundaries and, in turn, influence the occurrence of intergranular (IG) fractures. It discusses the mechanisms of IG fractures, including the dimpled IG fracture, the IG brittle fracture, and the IG fatigue fracture. The article describes some typical embrittlement mechanisms that cause the IG fracture of steels.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003543
EISBN: 978-1-62708-180-1
... of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals. atomic structure brittle cracking crack propagation crystalline structure ductile cracking ductility environmentally induced...
Abstract
Overload failures refer to the ductile or brittle fracture of a material when stresses exceed the load-bearing capacity of a material. This article reviews some mechanistic aspects of ductile and brittle crack propagation, including a discussion on mixed-mode cracking, which may also occur when an overload failure is caused by a combination of ductile and brittle cracking mechanisms. It describes the general aspects of fracture modes and mechanisms. The article discusses some of the material, mechanical, and environmental factors that may be involved in determining the root cause of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals.
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