Dynamic mechanical analysis (DMA) is a powerful tool for studying the viscoelastic properties and behavior of a range of materials as a function of time, temperature, and frequency. This article describes various systems and equipment used in DMA setup and discusses the processes involved in preparation of test specimen for DMA measurements. Some factors to be considered when calibrating the DMA instrument are provided, along with a description on processes for interpreting the temperature and frequency dependence of DMA curves as well as the applications of DMA.

Mechanical properties are often the most important properties in the design and selection of engineering plastics. Temperature, molecular structure, crystallinity, viscoelasticity, and effects of environment, fillers and reinforcements are considered as the basic factors affecting the mechanical properties of engineering plastics. The testing methods for determining mechanical properties, including stress-strain test, modulus-directed tensile test, strength test, strength-directed tensile test, impact test, and dynamic mechanical test are discussed.

This article focuses on the evaluation of mechanical properties of freestanding films and films adherent to their substrates. Common methods of testing freestanding films, including uniaxial tensile testing, uniaxial creep testing, biaxial testing, and beam-bending methods, are discussed. For films which are adherent to their substrates, indentation testing is used to evaluate hardness, creep, and strength.

This article reviews the various types of mechanical testing methods, including hardness testing; tension testing; compression testing; dynamic fracture testing; fracture toughness testing; fatigue life testing; fatigue crack growth testing; and creep, stress-rupture, and stress-relaxation testing. Shear testing, torsion testing, and formability testing are also discussed. The discussion of tension testing includes information about stress-strain curves and the properties described by them.

Tensile testing of fiber-reinforced composite materials is performed to determine uniaxial tensile strength, Young’s modulus, and Poisson’s ratio relative to principal material directions, and helps in the prediction of the properties of laminates. Beginning with an overview of the fundamentals of tensile testing of fiber-reinforced composites, this article describes environmental exposures that can occur during specimen preparation and testing. These include exposures during specimen preparation, and planned exposure such as moisture, damage (impact), and thermal cycling. The article also discusses the test methods of the four major types of mechanical testing of polymer-matrix composites: tensile, compression, flexural, and shear.

The response of titanium and titanium alloys to heat treatment depends on the composition of the metal, the effects of the alloying elements on the alpha-beta crystal transformation, and the thermomechanical processing utilized during processing of the alloy. This article provides a detailed discussion on the effects of heat treatment on the mechanical properties for three general classes of titanium alloys, namely, alpha and near-alpha titanium alloys, alpha-beta alloys, and beta alloys.

The properties of carbon and alloy steels are dependent on the relationships between chemical composition, processing, and microstructure. This article discusses the effects of alloying and residual elements on the mechanical properties of carbon and alloy steels. Tables listing values for the mechanical properties of selected carbon and alloy steels in the hot-rolled, normalized, annealed, and quenched-and tempered condition are provided.

This article summarizes some of the issues and approaches in performing computational analyses of mechanical behavior, distortion, and hot tearing during solidification. It presents the governing equations and describes the methods used to solve them. The article reviews the finite element formulation, multidomain approaches, and arbitrary Lagrangian Eulerian method in solidification modeling. It illustrates the sand casting of braking disks and continuous casting of steel slabs.

The constitutive relations for metalworking include elements of behavior at ambient temperature as well as high-temperature response. This article presents equations for strain hardening and strain-rate-sensitive flow, with alternate sections on empirically determined properties, followed by the models of constitutive behavior. It provides a discussion on creep mechanisms involving dislocation and diffusional flow, such as the Nabarro-Herring creep and the Coble creep. The equations for the several creep rates are also presented. Research on the mechanism of the superplastic flow in fine-grain metals has encompassed many ideas, such as the diffusional creep, dislocation creep with diffusional accommodation at grain boundaries, and concepts of grain-mantle deformation. The article concludes with information on the kinetics of superplastic deformation processes, including low stress behavior, concurrent grain growth, and high stress behavior.

This article, to develop an understanding of the underlying mechanisms governing deformation at elevated temperatures, discusses the phenomenological effects resulting from temperature-induced thermodynamic and kinetic changes. It describes the deformation behavior of engineering materials using expressions known as constitutive equations that relate the dependence of stress, temperature, and microstructure on deformation. The article reviews the characteristics of creep deformation and mechanisms of creep, such as power-law creep, low temperature creep, power-law breakdown, diffusional creep, twinning during creep deformation, and deformation mechanism maps. It discusses the creep-strengthening mechanisms for most structural engineering components. The article provides a description of the microstructural modeling of creep in engineering alloys.

The processing of steel involves five distinct sets of texture development mechanisms, namely, austenite deformation, austenite recrystallization, gamma-to-alpha transformation, ferrite deformation, and static recrystallization during annealing after cold rolling. This article provides an introduction on crystallographic textures. It discusses the effects of austenite rolling and recrystallization on the texture and transformation behavior of recrystallized austenite and deformed austenite. The article illustrates the overall summary of the rolling and transformation behavior. It details cold-rolling textures, annealing textures, and recrystallization textures of steel samples. The article concludes with a summary of texture development during cold rolling and annealing.

This article discusses the identifying characteristics of the forms or mechanisms of corrosion that commonly attack copper metals, as well as the most effective means of combating each. It tabulates corrosion ratings of wrought copper alloys in various corrosive media. The article describes the corrosion behavior of copper alloys in specific environments. It reviews the corrosion characteristics of copper and copper alloys in various acids, alkalis, salts, organic compounds, and gases. The article provides information on the behavior of copper alloys that is susceptible to stress-corrosion cracking in various industrial and chemical environments. It concludes with a discussion on various corrosion testing methods, including aqueous corrosion testing, dynamic corrosion tests, and stress-corrosion testing.

This article focuses on the analyzing and modeling of stress-strain behavior of polycrystals of pure face-centered cubic (fcc) metals in the range of temperatures and strain rates where diffusion is not important. It presents a phenomenological description of stress-strain behavior and provides information on the physical background, alternative interpretations, and directions of research. The quantitative description of strain hardening of fcc polycrystals is provided. The article also discusses the modeling of stress-strain behavior in body-centered cubic metals, hexagonal metals, stage IV work hardening, and the various classes of single-phase alloys.

This article illustrates the three techniques for producing glassy metals, namely, liquid phase quenching, atomic or molecular deposition, and external action technique. Devitrification of an amorphous alloy can proceed by several routes, including primary crystallization, eutectoid crystallization, and polymorphous crystallization. The article demonstrates a free-energy versus composition diagram that summarizes many of the devitrification routes. It provides a historical review of the corrosion behavior of fully amorphous and partially devitrified metallic glasses. The article describes the general corrosion behavior and localized corrosion behavior of transition metal-metal binary alloys, transition metal-metalloid alloys, and amorphous simple metal-transition metal-rare earth metal alloys. It concludes with a discussion on the environmentally induced fracture of glassy alloys, including hydrogen embrittlement and stress-corrosion cracking.

Weathering steels contain deliberate additions of alloying elements intended to increase the atmospheric corrosion resistance of steel. This article provides an overview of atmospheric corrosion testing. It describes the estimation of the atmospheric corrosion behavior of weathering steels by two methods such as short-term exposure tests and calculation of a corrosion index based on the steel composition. The article highlights some generalities about corrosion mechanisms. Based on the mechanism of atmospheric corrosion resistance of weathering steel, working rules for creating the protective oxide film have evolved. The article also provides case histories that illustrate both the violations of these rules and suggestions on how to avoid certain maintenance problems that may be encountered with weathering steels.

The concept of surface integrity for grinding operations can be extended to encompass six different groups of key factors: visual, dimensional, residual stress, tribological, metallurgical, and others. This article discusses the importance of these factors in the performance and behavior of finishing methods in various manufactured parts. Special emphasis is given to residual stresses and their influence on the final mechanical properties of a manufactured part.

Semisolid metal (SSM) processing is a special die casting process, where partially solidified metal slurry is injected into a die cavity to form die cast components. This article discusses the flow behavior of SSM slurry with emphasis on viscosity, rheological behavior, and yield strength. It illustrates microstructural formation of semisolids, under forced convection. The article concludes with an illustration that compares two SSM processes, namely, thixocasting and rheocasting.

Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.

This article focuses on the forging behavior and practices of carbon and alloy steels. It presents general guidelines for forging in terms of practices, steel selection, forgeability and mechanical properties, heat treatments of steel forgings, die design features, and machining. The article discusses the effect of forging on final component properties and presents special considerations for the design of hot upset forgings.