Martensitic stainless steels are the least corrosion-resistant of all stainless alloys. The traditional martensitic stainless steels are iron/chromium/carbon alloys, sometimes with a small amount of nickel and/or molybdenum. This article provides an overview on the influences of the various possible alloying elements on the key properties of martensitic stainless steels. It describes the various preparation processes, namely, atmosphere selection, cleaning, and preheating, prior to heat treatment for these steels. Common heat treatment methods include annealing, hardening, tempering, and stress relieving. The article lists the compositions of casting alloys and also describes the effect of tempering temperature on the hardness, strength, ductility, and toughness properties of the alloys.

This article describes general welding characteristics such as weld microstructure and weldability. The correlations of preheating and postweld heat treatment practices with carbon contents and welding characteristics of martensitic stainless steels are reviewed. The article contains a table that lists the electrodes and welding rods suitable for use as filler metals in the welding of martensitic stainless steels. It provides specific arc welding procedural recommendations for the commonly welded martensitic stainless steels. Martensitic stainless steel joining methods such as laser-and electron-beam welding, resistance welding, flash welding, and friction welding, are discussed.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of martensitic stainless steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fracture surface, high-cycle fatigue fracture, tensile-shear fracture, intergranular crack, fatigue striations, and microvoid coalescence of conveyor-chain links, hub socket of aircraft propellers, and automotive intake valves of these steels.

Stainless steels are widely used at elevated temperatures when carbon and low-alloy steels do not provide adequate corrosion resistance and/or sufficient strength at these temperatures. This article deals with the wrought stainless steels used for high temperature applications. It gives some typical compositions of wrought heat-resistant stainless steels, which are grouped into ferritic, martensitic, austenitic, and precipitation-hardening (PH) grades. Quenched and tempered martensitic stainless steels are essentially martensitic and harden when air cooled from the austenitizing temperature. These alloys offer good combinations of mechanical properties. The article focuses on mechanical property considerations and corrosion resistance considerations of stainless steels. The corrosion and oxidation resistance of wrought stainless steels is similar to that of cast stainless steels with comparable compositions.

Stainless steels are used for medical implants and surgical tools due to the excellent combination of properties, such as cost, strength, corrosion resistance, and ease of cleaning. This article describes the classifications of stainless steels, such as austenitic stainless steels, martensitic stainless steels, ferritic stainless steels, precipitation-hardening stainless steels, and duplex stainless steels. It contains a table that lists common medical device applications for stainless steels. The article discusses the physical metallurgy and physical and mechanical properties of stainless steels. Medical device considerations for stainless steels, such as fatigue strength, corrosion resistance, and passivation techniques, are reviewed. The article explains the process features of implant-grade stainless steels, including type 316L, type 316LVM, nitrogen-strengthened, ASTM F1314, ASTM F1586, ASTM F2229, and ASTM F2581 stainless steels.

This article provides an overview of the identification systems for various grades of wrought stainless steels, namely, the American Iron and Steel Institute numbering system, the Unified Numbering System, and proprietary designations. It elaborates on five major families of stainless steels, as defined by the crystallographic structure. These include ferritic stainless steels, austenitic stainless steels, martensitic stainless steels, and precipitation-hardening stainless steels. The mechanism of corrosion protection for stainless steels is reviewed. The article examines the effects of composition, processing, design, fabrication, and external treatments on the corrosion of stainless steels. Various forms of corrosion, namely, general, galvanic, pitting, crevice, intergranular, stress-corrosion cracking, erosion-corrosion, and oxidation, are reviewed. Corrosion testing for; corrosion in atmosphere, water, and chemical environments; and the applications of stainless steels in various industries are also discussed.

Stainless steels, based on forging pressure and load requirements, are more difficult to forge because of the greater strength at elevated temperatures and the limitations on the maximum temperatures at which stainless steels can be forged without incurring microstructural damage. This article discusses the forging methods, primary mill practices (primary forging and ingot breakdown), trimming, and cleaning operations of stainless steels. It describes the use of forging equipment, dies, and die material in the forging operation. The article provides an overview of the forgeability of austenitic stainless steels, martensitic stainless steels, precipitation-hardening stainless steels, and ferritic stainless steels. It concludes with a discussion on the heating and lubrication of dies.

This article addresses consumable selection and procedure development for the welding of stainless steels. The WRC-1992 diagram and the Schaeffier diagram, are used to illustrate the rationale behind many filler-metal choices. The article discusses the basic metallurgy and base metals of five major families of stainless steels: martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, precipitation-hardening (PH) stainless steels, and duplex ferritic-austenitic stainless steels. Stainless steels of all types are weldable by virtually all welding processes. The article describes the common arc welding processes with regard to procedure and technique errors that can lead to loss of ferrite control with the common austenitic stainless steel weld metals that are designed to contain a small amount of ferrite for protection from hot cracking. The arc welding processes include shielded-metal arc welding, gas-tungsten arc welding, and gas-metal arc welding.

This article briefly describes the welding of various stainless steels to dissimilar steels. The stainless steels include austenitic stainless steels, ferritic stainless steels, and martensitic stainless steels. The dissimilar steels include carbon and low-alloy steels. In addition, the article provides information on the cladding of austenitic stainless steel to carbon or low-alloy steels.

Metallurgical variables, mainly carbon distribution and the presence of nitrogen and metallic phases, can influence the corrosion behavior of austenitic, ferritic, duplex, and martensitic stainless steels. This article describes the effects of these metallurgical and processing variables on the susceptibility of the stainless steels to intergranular corrosion and intergranular stress-corrosion cracking and their testing methods. It explains the effect of sigma and related phases on the corrosion behavior of stainless steels.

This article discusses the composition, characteristics, and properties of the five groups of wrought stainless steels: martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, duplex stainless steels, and precipitation-hardening stainless steels. The selection of stainless steels may be based on corrosion resistance, fabrication characteristics, availability, mechanical properties in specific temperature ranges and product cost. The fabrication characteristics of stainless steels include formability, forgeability, machinability, and weldability. The product forms of wrought stainless steels are plate, sheet, strip, foil, bar, wire, semifinished products, pipes, tubes, and tubing. The article describes tensile properties, elevated-temperature properties, subzero-temperature properties, physical properties, corrosion properties, and fatigue strength of stainless steels. It characterizes the experience of a few industrial sectors according to the corrosion problems most frequently encountered and suggests appropriate grade selections. Corrosion testing, surface finishing, mill finishes, and interim surface protection of stainless steels are also discussed.

This article describes the sintering behavior of austenitic, ferritic, and martensitic stainless steels. It presents different sintering schedules that are selected by Metal Powder Industries Federation (MPIF). The article provides information on the equipment and atmospheres used for sintering and the steps involved in the process. It discusses the factors that influence the dimensional changes in sintering, namely, powder-related, compaction-related, and sintering-related factors.

This article discusses two categories of stainless steel casting alloys and their nomenclature. It provides information on two situations in which welding of stainless steel castings is required. These situations are based on casting defects and selection of welding processes. The article presents compositions and typical microstructures of corrosion-resistant stainless steel casting alloys in tabular form. It presents special considerations for the welding of martensitic stainless steel castings. The article reviews the two most serious problems encountered in the welding of stainless steel castings, namely, solidification hot cracking and heat-affected zone hot cracking. It concludes with a discussion on the some useful considerations for welding corrosion-resistant alloys to avoid defects.

Air hardening steel is a type of steel that has deep hardenability and can be hardened in large sections by air cooling. This article discusses the principles of heat treatment of air-hardening steel, and describes the recommended heat treating practices for air-hardening high-strength structural steels, namely, H11 Mod, H13 steel, 300M steel, D-6A and D-6AC, and AF1410 steel. It also provides information on recommended heat treating practices for air-hardening martensitic stainless steels.

Stainless steels are primarily alloys of iron and chromium. They are grouped into five families, primarily based on their microstructure: ferritic, austenitic, martensitic, duplex, and precipitation hardening. Three out of the five families of stainless steels, namely, austenitic, ferritic, and martensitic, are well suited for manufacture via conventional powder metallurgy (PM) processes. This article presents the iron-chromium partial phase diagram to illustrate the changes in the temperature range when pure iron is alloyed with chromium. It describes AISI and UNS numbering systems, which are used as an identification system for stainless steels. The article tabulates the material designations of stainless steels in accordance with the Metal Powder Industries Federation. It also details the characteristics and chemical composition of wrought and PM stainless steels.

Stainless steels are an important class of engineering alloys used in both wrought and cast form for a wide range of applications and in many environments. This article aids in the selection of stainless steels based on weldability and service integrity. Stainless steels are classified by microstructure and are described as ferritic, martensitic, austenitic, or duplex. The article illustrates compositional ranges of the ferritic, martensitic, austenitic, and duplex alloys in the Schaeffler diagram. It describes the metallurgical aspects of welded stainless steels to be considered for particular engineering applications and service conditions. The article discusses the microstructural evolution of the weld metal and the heat-affected zone, susceptibility to defect formation during welding, mechanical and corrosion properties, and weld process tolerance.

Stainless steels are characterized as having relatively poor wear resistance and tribological properties, but they are often required for a particular application because of their corrosion resistance. This article describes the classification of stainless steels and wear. Stainless steels have been classified by microstructure and are categorized as austenitic, martensitic, ferritic, or duplex. The main categories of wear are related to abrasion, erosion, adhesive wear, and surface fatigue. The article presents a list that proposes the alloy family that could be the optimal selection for a particular wear mode. The corrosion modes include dry sliding, tribocorrosion, erosion, erosion-corrosion, cavitation, dry erosion, erosion-oxidation, galling and fretting.

Stainless steels are iron-base alloys containing minimum of approximately 11% Cr, and owing to its excellent corrosion resistance, are used for wide range of applications. These applications include nuclear reactor vessels, heat exchangers, oil industry tubular, chemical processing components, pulp and paper industries, furnace parts, and boilers used in fossil fuel electric power plants. The article provides a brief introduction on corrosion resistance of wrought stainless steel and its designations. It lists the chemical composition and describes the physical and mechanical properties of five major stainless steel families, of which four are based on the crystallographic structure of the alloys, including martensitic, ferritic, austenitic, or duplex. The fifth is precipitation-hardenable alloys, based on the type of heat treatment used. The article further discusses the factors in the selection of stainless steel, namely corrosion resistance, fabrication characteristics, product forms, thermally induced embrittlement, mechanical properties in specific temperature ranges, and product cost.

This article summarizes the key mechanical characteristics of various types of stainless steel, including ferritic, austenitic, martensitic, precipitation hardening, and duplex steels. Particular emphasis is on fracture properties and corrosion fatigue. The article tabulates typical room-temperature mechanical properties and fatigue endurance limits of stainless steels. Stainless steels are susceptible to embrittlement during thermal treatment or elevated-temperature service. The article discusses embrittlement in terms of sensitization, 475 deg C embrittlement, and sigma-phase embrittlement. It also describes the effect of environment on fatigue crack growth rate.

This article describes metallographic preparation and examination techniques for stainless steels and maraging steels. It presents a series of micrographs demonstrating microstructural features of these alloys. Procedures used to prepare stainless steels for macroscopic and microscopic examination are similar to those used for carbon, alloy, and tool steels. Cutting and grinding must be carefully executed to minimize deformation because the austenitic grades work harden readily. The high-hardness martensitic grades that contain substantial undissolved chromium carbide are difficult to polish while fully retaining the carbides. Unlike carbon, alloy, and tool steels, etching techniques are more difficult due to the high corrosion resistance of stainless steels and the various second phases that may be encountered. The microstructures of stainless steels can be quite complex. Matrix structures vary according to the type of steel, such as ferritic, austenitic, martensitic, precipitation hardenable, or duplex.