Malleable iron is a cast ferrous metal that is initially produced as white cast iron and is then heat treated to convert the carbon-containing phase from iron carbide to a nodular form of graphite called temper carbon. This article provides a discussion on the melting practices, heat treatment, microstructure, production technologies, mechanical properties, and applications of ferritic, pearlitic, and martensitic malleable irons.

Malleable iron, like ductile iron, possesses considerable ductility and toughness because of its combination of nodular graphite and low-carbon metallic matrix. This article discusses melting practices such as batch cold melting and duplexing, and their control mechanisms. It schematically illustrates the microstructure of annealed ferritic malleable iron, which is characterized by microstructures consisting of uniformly dispersed fine particles of free carbon in a matrix of ferrite or tempered martensite. The article describes the digital solidification analysis technology, simulation technologies, and smart engineering for the production of malleable iron. It provides information on the applications of ferritic and pearlitic malleable irons.

Malleable iron is a type of cast iron that has most of its carbon in the form of irregularly shaped graphite nodules. This article tabulates the typical composition of malleable iron and specifications, and applications of malleable iron castings. It discusses the metallurgical control of malleable irons with emphasis on its composition and heat treatment. The article provides information on the specifications and mechanical properties of different types of malleable irons, such as ferritic, pearlitic, and martensitic malleable irons.

Malleable iron possesses considerable ductility and toughness because of its combination of nodular graphite and a low-carbon metallic matrix. The desired formation of temper carbon in malleable irons has two basic requirements. First, graphite should not form during the solidification of the white cast iron, and second, graphite must also be readily formed during the annealing heat treatment. These two metallurgical requirements influence the useful compositions of malleable irons and the melting, solidification, and annealing procedures. There are two basic types of malleable iron: blackheart and whiteheart. This article considers only the blackheart type and describes the metallurgical factors of malleable iron. It discusses the mechanical properties of pearlitic and martensitic malleable irons. The article provides additional information on the properties and heat treatment of ferritic, pearlitic, and martensitic malleable irons. The article lists some of the typical applications of malleable iron castings.

Malleable iron is a type of cast iron that has most of its carbon in the form of irregularly shaped graphite nodules instead of flakes, as in gray iron, or small graphite spherulites, as in ductile iron. This article discusses the production of malleable iron based on the metallurgical criteria: to produce solidified white iron throughout the section thickness; and to produce the desired graphite distribution (nodule count) upon annealing. It describes the induction heating and quenching or flame heating and quenching for surface hardening of fully pearlitic malleable iron. Laser and electron beam techniques also have been used for hardening selected areas on the surface of pearlitic and ferritic malleable iron castings that are free from decarburization.

Malleable iron, like ductile iron, possesses considerable ductility and toughness because of its combination of nodular graphite and low-carbon metallic matrix. There are two basic types of malleable iron: blackheart and whiteheart. This article focuses on the blackheart malleable iron and discusses the chemical composition of malleable iron. A summary of mechanical properties and specifications of malleable iron castings is presented in a table. The article also reviews the mechanical properties of ferritic malleable iron and pearlitic and martensitic-pearlitic malleable irons.

This article focuses on heat treatment of malleable and compacted-graphite irons to produce ferritic and pearlitic malleable irons. It describes the heat treatment cycles of malleable iron, including martempering, tempering, bainitic heat treatment, and surface hardening. The article provides information on the mechanical and physical properties of compacted-graphite irons, which are determined by the graphite shape and the pearlite/ferrite ratio.

This article discusses criteria that can be used for the classification of cast iron: fracture aspect, graphite shape, microstructure of the matrix, commercial designation, and mechanical properties. It addresses the main factors of influence on the structure of cast iron, including chemical composition, cooling rate, and heat treatment. The article describes some basic principles of cast iron metallurgy. It discusses the main effects of the chemical composition of ductile iron and compacted graphite (CG) iron. The composition of malleable irons must be selected in such a way as to produce a white as-cast structure and to allow for fast annealing times. Some typical compositions of malleable irons are presented in a table. The article concludes with information on special cast irons.

This article introduces the general principles and applications of heat treatment to iron castings. It provides a detailed discussion on the heat treatment processes, namely, stress relieving, annealing, normalizing, throughhardening, and surface hardening for various types of cast irons. These include gray iron, ductile iron, compacted graphite iron, white iron, malleable iron, and high-alloy iron. The article describes how to control temperature and atmosphere during the heat treatment of the iron castings.

Cast irons and carbon steels are brazeable materials, although the brazeability of cast iron is lower than that of carbon steel. The article provides a detailed discussion on the brazeability of different types of cast iron (malleable iron, ductile iron, and gray iron), carbon steels, and dissimilar metals. It describes the factors considered in the selection of filler-metal for cast iron and carbon steel brazing, such as temperature and environment, brazed joint design, heat source, and heat-treatment requirements. The article also discusses the basic considerations in cleaning and fixturing procedures, filler metal and flux/atmosphere feeding procedures, and the heating methods of cast iron and carbon steel brazing.

This article describes some examples of the different welding processes for gray, ductile, and malleable irons. These processes include fusion welding, repair welding, shielded metal arc welding, gas metal arc welding, flux cored arc welding, gas tungsten arc welding, submerged arc welding, oxyfuel welding, and braze welding. The article discusses various special techniques, such as groove-face grooving, studding, joint design modifications, and peening, for improving the strength of a weld or its fitness for service. The article describes other fusion welding methods such as electrical resistance welding and thermite welding. It reviews thermal spraying processes, such as flame spraying, arc spraying, and plasma spraying, of a cast iron.

The term cast iron designates a group of materials that contain more than one constituent in their microstructure due to excess carbon that result in unique characteristics such as the fracture appearance and graphite morphology. This article discusses the classification of cast iron and the various metallurgical aspects, such as the composition, alloying element, solidification, and graphite morphologies, of different types of cast iron. It describes the physical properties for various cast irons and the influence of microstructure and chemical composition on each property. The article provides a detailed account on thermal properties, conductive properties, magnetic properties, and acoustic properties of cast iron. It also examines heat treatment, namely, stress relieving, annealing, normalizing, through hardening, and surface hardening. The article presents a discussion on the welding, machining and grinding, and coating of the types of cast iron.

The cast iron family includes several different groups, including gray iron, ductile iron, compacted graphite iron, malleable iron, white iron, and many different grades within each of these alloy groups. This article addresses issues specific to gray iron, but in many instances the discussion can be related to the other cast iron groups and the various grades within those groups. It discusses the usage of techniques and procedures in cast iron fractography. The article presents a list of common defects that can initiate failure.

This article discusses the compositions, properties, and typical applications for ductile irons that are defined by U.S. and international standards . It describes the various methods used to test and inspect the metallurgical control processes in ductile iron production. The article discusses the effect of composition, graphite shape, and section size on the properties of ductile iron. The article also describes the mechanical properties of ductile iron at elevated temperatures. The heat treatment of ductile iron castings produces a significant difference in mechanical properties from as-cast ductile iron. A ductile iron generally has higher hardenability than a eutectoid steel with comparable alloy content. The article also discusses the physical properties of ductile iron, including density, thermal conductivity, electrical conductivity, electrical resistivity, and magnetic properties. Ductile iron has been chosen in many instances on the basis of significantly lower machining costs, which resulted in lower overall cost of the part.

This article discusses the five basic matrix structures in cast irons: ferrite, pearlite, bainite, martensite, and austenite. The alloying elements, used to enhance the corrosion resistance of cast irons, including silicon, nickel, chromium, copper, molybdenum, vanadium, and titanium, are reviewed. The article provides information on classes of the cast irons based on corrosion resistance. It describes the various forms of corrosion in cast irons, including graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. The cast irons suitable for the common corrosive environments are also discussed. The article reviews the coatings used on cast irons to enhance corrosion resistance, such as metallic, organic, conversion, and enamel coatings. It explains the basic parameters to be considered before selecting the cast irons for corrosion services.