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Published: 01 August 2018
Fig. 7 (a) Motion of a domain wall through the energy landscape from one pinning site at “1” to the next at “2.” (b) Motion is accompanied by abrupt change in magnetization and formation of net magnetic dipole moment.
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001752
EISBN: 978-1-62708-178-8
... Abstract Nuclear magnetic resonance (NMR) is a form of radio frequency spectroscopy based on interactions between nuclear magnetic dipole or electric quadrupole moments and an applied magnetic field or electric-field gradient. This article provides an overview of the fundamental principles...
Abstract
Nuclear magnetic resonance (NMR) is a form of radio frequency spectroscopy based on interactions between nuclear magnetic dipole or electric quadrupole moments and an applied magnetic field or electric-field gradient. This article provides an overview of the fundamental principles of nuclear magnetic resonance with emphasis on nuclei properties, the basic equation of nuclear magnetic resonance, the classical theory of nuclear magnetization, line broadening, and measurement sensitivity. It describes the pulse-echo method for observing NMR. The article provides useful information on ferromagnetic nuclear resonance and nuclear quadrupole resonance, and illustrates the experimental arrangement of NMR with a block diagram. It also presents several application examples.
Image
Published: 01 August 2018
Fig. 10 Flux density as a function of applied external magnetic field ( H ) and resultant change in domain wall structure with increasing magnetization in iron. (a) Demagnetized state where domain structure is flux closed. (b) Movement of primarily 180° domain walls and formation of dipole
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Series: ASM Handbook
Volume: 17
Publisher: ASM International
Published: 01 August 2018
DOI: 10.31399/asm.hb.v17.a0006442
EISBN: 978-1-62708-190-0
..., with a resultant generation of Barkhausen noise emissions. Fig. 7 (a) Motion of a domain wall through the energy landscape from one pinning site at “1” to the next at “2.” (b) Motion is accompanied by abrupt change in magnetization and formation of net magnetic dipole moment. Microscopic Eddy Currents...
Abstract
This article discusses the principles and limitations of micromagnetic techniques, namely, magnetic Barkhausen noise (MBN) and magnetoacoustic emission (MAE). It also discusses various factors limiting the establishment of acceptance criteria for test components as they pertain to the successful application of MBN measurement and signal interpretation. The article provides an overview of basic magnetic phenomena and dynamics in ferromagnetic materials that underlie the origin of MBN emissions. It describes the changes in the domain structure of the ferromagnetic material under an applied external field. The relationship between uniaxial stress and angular-dependent strain is also discussed. The influence of stress on domain walls, and therefore, the generation of Barkhausen noise are described. The article also describes the directional and angular MBN measurements and provides information on detection, angular dependence, and advanced analysis methods of MBN emissions.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005896
EISBN: 978-1-62708-167-2
... field; it occurs because the external field alters the orbital velocity of electrons around their nuclei, thus changing the magnetic dipole moment. According to Lenz's law, the field of these electrons will oppose the magnetic field changes provided by the applied field; the resulting magnetic field...
Abstract
In an induction heating system, thermal and electromagnetic properties of heated materials make the greatest impact on the heat transfer and performance of induction heating process. This article focuses on major thermal properties, namely, thermal conductivity, heat capacity, and specific heat. It describes the two important electromagnetic properties, electrical resistivity (electrical conductivity) and magnetic permeability, which posses the most pronounced effect on the performance of the induction heating system, its efficiency, and selection of main design parameters. The article also discusses the magnetic properties of diamagnetic, paramagnetic, ferromagnetic, ferrimagnetic, antiferromagnetic, and metamagnetic materials.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003086
EISBN: 978-1-62708-199-3
... or ions tend to be aligned parallel to one another without the presence of an applied field, thereby producing a “permanent” magnetic moment. Above the Curie point, these materials become paramagnetic. Paramagnetic materials are those within which the permanent-magnetic dipole moments of atoms or ions...
Abstract
Material properties are the link between the basic structure and composition of the material and the service performance of a part or component. This article describes the most significant properties that must be considered when choosing a metal for a given application, namely physical properties (mass characteristics and thermal, electrical, magnetic, radiation, and optical properties), chemical properties (corrosion and oxidation resistance) and mechanical properties (tensile and yield strength, elongation, toughness, hardness, creep, and fatigue). The article also contains tables that list room-temperature physical properties, vapor pressures, and mechanical properties for various metals.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001750
EISBN: 978-1-62708-178-8
... constantly about its axis with a certain angular momentum. Associated with the intrinsic spin is a magnetic moment whose value is termed the Bohr magneton (β). If an external magnetic field is impressed on the system, the electron aligns itself with the direction of this field and precesses about this axis...
Abstract
Electron spin resonance (ESR), or electron paramagnetic resonance (EPR), is an analytical technique that can extract a great deal of information from any material containing unpaired electrons. This article explains how ESR works and where it applies in materials characterization. It describes a typical ESR spectrometer and explains how to tune it to optimize critical electromagnetic interactions in the test sample. It also identifies compounds and elements most suited for ESR analysis and explains how to extract supplementary information from test samples based on the time it takes electrons to return to equilibrium from their resonant state. Two of the most common methods for measuring this relaxation time are presented as are several application examples.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006650
EISBN: 978-1-62708-213-6
... of boron. The distribution of charges in the nucleus determines the magnitude and shape of the magnetic moment. A spherical distribution of charges leads to a magnetic dipole moment, while higher-order moments can be realized for nonspherical charge distributions. The easiest nuclei for NMR study...
Abstract
This article focuses on the application of solid-state nuclear magnetic resonance (NMR) spectroscopy in materials science, especially for inorganic and organic polymer solids. It begins with a discussion on the general principles of NMR, providing information on nuclear spin descriptions and line narrowing and spectral resolution and describing the impact of magnetic field on nuclear spins and the factors determining resonance frequency. This is followed by a description of various systems and equipment necessary for NMR spectroscopy. A discussion on general sampling for solid-state NMR, sample-spinning requirements, and extraneous signals is then included. Various factors pertinent to accurate calibration of the NMR spectrum are also described. The article provides information on some of the parameters both beneficial and problematic for processing NMR data. It ends with a description of the applications of NMR in glass science and ceramics.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001110
EISBN: 978-1-62708-162-7
... carrying localized magnetic moments (for example, manganese, iron, or chromium) ( Ref 34 ). Several large billets have been fabricated to investigate the benefits (and limitations) of manganese additions to the copper matrix ( Ref 35 , 36 ). The evaluation has included mechanical, electrical, thermal...
Abstract
Niobium-titanium alloys (NbTi) became the superconductors of choice in the early 1960s, providing a viable alternative to the A-15 compounds and less ductile alloys of niobium-zirconium. This can be attributed to the relative ease of fabrication, better electrical properties, and greater compatibility with copper stabilizing materials. This article discusses the ramifications of design requirements, selection criteria and processing methods of superconducting fibers and matrix materials. It provides information on the various steps involved in the fabrication of superconducting composites, including assembly, welding, isostatic compaction, extrusion, wire drawing, twisting, and final sizing. The article also provides a detailed account of the properties and applications of NbTi superconducting composites.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006662
EISBN: 978-1-62708-213-6
... of the force constant, that is, bond order. As masses increase, vibrational frequency decreases. For a molecular vibration to absorb infrared radiation, dipole moment must change during the vibration ( Ref 2 ). The infrared photon frequency must resonate with the vibrational frequency to excite...
Abstract
Infrared (IR) spectra have been produced by transmission, that is, transmitting light through the sample, measuring the light intensity at the detector, and comparing it to the intensity obtained with no sample in the beam, all as a function of the infrared wavelength. This article discusses the sampling techniques and applications of IR spectra as well as the molecular structure information it can provide. The discussion begins with a description of the general principle of IR spectroscopy. This is followed by a section on commercial IR instruments. Sampling techniques and accessories necessary in obtaining the infrared spectrum of a material are then discussed. The article presents various techniques and methods involved in IR qualitative analysis and quantitative analysis. It ends with a few examples of the applications of IR spectroscopy.
Book Chapter
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0005692
EISBN: 978-1-62708-178-8
... be present in an uncharged medium. 1 m) ing gases emerge from separate ports and are mixed in the flame itself. One of the electric dipole moment. A quantity charac- electrometric titration. A family of tech- gases, usually the oxidant, is used for teristic of a distribution of bound charges niques in which...
Abstract
This article is a compilation of definitions of terms related to materials characterization techniques.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001735
EISBN: 978-1-62708-178-8
... infrared radiation, dipole moment must change during the vibration ( Ref 2 ). The infrared photon frequency must resonate with the vibrational frequency to excite the molecule into the higher vibrational state. In addition, the electric dipole-transition moment associated with the molecular vibration being...
Abstract
Infrared (IR) spectroscopy is a useful technique for characterizing materials and providing information on the molecular structure, dynamics, and environment of a compound. This article provides the basic principles and instrumentation of IR spectroscopy. It discusses the sampling techniques of IR spectroscopy, namely, attenuated total reflectance spectroscopy, diffuse reflectance spectroscopy, infrared reflection-absorption spectroscopy, emission spectroscopy, and photoacoustic spectroscopy, and chromatographic techniques. Explaining the qualitative analysis of IR spectroscopy, the article provides information on spectral absorbance-subtraction, analysis of components in spectral matrix mixture, and determination of exact peak location of broad profiles. It discusses the quantitative analysis that mainly includes Beer's law for single compound in single wave number. The article also exemplifies the applications of IR spectroscopy.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006057
EISBN: 978-1-62708-175-7
... 8.4 12,300 22 0.28 At H = 100 Oe 7.2 1.14 11.4 0.88 8.8 12,300 22 0.28 (a) Magnetic saturation ( B sat ) values. (b) Samples sintered at 1250 °C (2280 °F), 45 min in dissociated ammonia. Source: Ref 1 , 3 The magnetic moments of adjacent atoms in ferromagnetic...
Abstract
Powder metallurgy (PM) techniques are effective in making magnetically soft components for use in magnetic part applications. This article provides an account of the factors affecting magnetism, permeability, and hysteresis losses. It includes information on the magnetic properties of PM materials that are used in the magnetic part applications, namely, pure iron, phosphorus irons, ferritic stainless steels, 50 nickel-50 iron, and silicon irons. The article describes the factors that affect and optimize magnetic properties. It contains a table that lists the magnetic properties possible in metal injection molding parts. The article also discusses ferromagnetic cores used in alternating current applications and some permanent magnets, such as rare earth-cobalt magnets and neodymium-iron-boron (neo) magnets.
Book Chapter
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006748
EISBN: 978-1-62708-213-6
... is the lightest resin particles. Highly ionized molecules are electric dipole moment. A quantity character- known particle that possesses an electric excluded from the resin particles by electro- istic of a distribution of bound charges equal charge. Its rest mass is approximately 9.1 static forces; weakly...
Abstract
This article is a compilation of terms and definitions related to materials characterization.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006667
EISBN: 978-1-62708-213-6
... and allow structural details of each species to be clearly distinguished ( Ref 13 ). Finally, a notable property of neutrons is that, due to their intrinsic magnetic dipole moment, their polarization can be affected by magnetic fields. This interaction is observed in coherent scattering from...
Abstract
This article provides a brief introduction to neutron diffraction as well as its state-of-the-art capabilities. The discussion covers the general principles of the neutron, neutron-scattering theory, generation of neutrons, types of incident radiation, and purposes of single-crystal neutron diffraction, powder diffraction, and pair distribution function analysis. The relationship between detector space and reciprocal space are presented. Various factors involved in sample preparation, calibration, and techniques used for analyzing diffraction data are described. The article also presents application examples and possible future developments in neutron diffraction.
Book Chapter
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006646
EISBN: 978-1-62708-213-6
... moment and a magnetic field at the nuclear site is useful for phase identification, for observing magnetic transitions, and for studying the local atomic environment of the resonating nucleus. This Zeeman effect is characterized by the Hamiltonian: (Eq 17) H = − μ · H 0 = − γ ℏ I · H...
Abstract
The Mossbauer effect (ME) is a spectroscopic method for observing nuclear gamma-ray fluorescence using the recoil-free transitions of a nucleus embedded in a solid lattice. This article provides an overview of the fundamental principles of ME, covering recoil-free fraction, absorption, selection rules, gamma-ray polarization, isomer shift, quadrupole interaction, and magnetic interaction. Experimental arrangement for obtaining ME spectra is described and several examples of the applications of ME are presented. The article contains tables listing some properties of Mossbauer transitions and principal methods used for producing ME sources.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001753
EISBN: 978-1-62708-178-8
... | < L < | I e + I g |. The number 2 L defines the multipolarity of the transition, that is, L = 1 (dipole), L = 2 (quadrupole), L = 3 (octapole), and so on. For each multipolarity L , there are two types of nuclear transitions—electric EL and magnetic ML. If P e and P g...
Abstract
The Mossbauer effect (ME) is a spectroscopic method for observing nuclear gamma-ray fluorescence based on recoil-free transitions in a nucleus embedded in a solid lattice. This article provides an overview of the fundamental principles of ME and related concepts such as recoil-free fraction, absorption cross section, gamma-ray polarization, isomer shift, and quadrupole and magnetic interactions. It illustrates the experimental arrangement for obtaining ME spectra and presents several application examples.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001736
EISBN: 978-1-62708-178-8
... and the attraction of the nuclei to the negative pole of the electric field. The extent to which this distortion occurs is a characteristic of the molecule known as its polarizability. The resulting separation of charge produces a momentary induced electric dipole moment that is usually expressed as the dipole...
Abstract
This article introduces the principles of Raman spectroscopy and the representative materials characterization applications to which Raman spectroscopy has been applied. It includes a discussion of light-scattering fundamentals and a description of the experimental aspects of the technique. Emphasis has been placed on the different instrument approaches that have been developed for performing Raman analyses on various materials. The applications presented in the article reflect the breadth of materials characterization uses for Raman spectroscopy and highlight the analysis of bulk material and of surface and near-surface species.
Book Chapter
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006685
EISBN: 978-1-62708-213-6
... to the negative pole of the electric field. The extent to which this distortion occurs is a characteristic of the molecule known as its polarizability. The resulting separation of charge produces a momentary induced electric dipole moment that is usually expressed as the dipole moment per unit volume and is known...
Abstract
This article introduces the principles of Raman spectroscopy and the representative materials characterization applications to which Raman spectroscopy has been applied. A discussion on light-scattering fundamentals and a description of the experimental aspects of the technique are included. Emphasis is placed on the different instrument approaches that have been developed for performing Raman analyses on various materials. The applications presented reflect the breadth of materials characterization uses for Raman spectroscopy and highlight the analysis of bulk material and of surface and near-surface species.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006005
EISBN: 978-1-62708-172-6
... molecule For comparison, carbon dioxide (CO 2 ), as pictured in Fig. 4 , has two polar C-O bonds, but the geometry of CO 2 is linear, so that the two bond dipole moments cancel and there is no net molecular dipole moment; the molecule is nonpolar. Fig. 4 Nonpolar covalent bonding between...
Abstract
This article provides an overview of chemistry and chemical interactions necessary to understand protective coatings. It includes information on elements, atoms, molecules, types of bonding, valence electrons, functional groups, polymer formation, and chemical bonding structures.
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