Unlike gray iron, which contains graphite flakes, ductile iron has an as-cast structure containing graphite particles in the form of small, rounded, spheroidal nodules in a ductile metallic matrix. This article discusses the raw materials that are used for ductile iron production and outlines the most common and important requirements for controlling the composition of ductile iron. Treatment to produce ductile iron involves the addition of magnesium to change the form of the graphite, followed by or combined with inoculation of a silicon-containing material to ensure a graphitic structure with freedom from carbides. The article describes the methods of magnesium treatment, control of magnesium content, and inoculation. It concludes with a discussion on the metallurgical controls of ductile iron production.

Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out during inoculation and nucleation of molten cast iron, assisting in the formation of cast iron. The different types of cast irons are gray cast iron, nodular cast iron, compacted graphite iron, malleable cast iron, and alloyed cast iron. The article provides an overview of the melt treatment processes carried out in cast steel, wrought and cast aluminum, and copper materials.

This article describes the modification and inoculation of cast iron, and schematically illustrates the major effects of inoculation in gray cast irons. Inoculation could be considered as a common liquid-state treatment for all commercial cast irons (gray/compacted/ductile irons), while modification is essential to produce compacted graphite iron (intermediate level) and ductile iron. The article discusses the most important aspects of a gray cast iron inoculation treatment and the factors influencing its inoculation efficiency. It describes the modification and inoculation of ductile cast iron and compacted graphite cast iron.

This article reviews the production stages of iron foundry casting, with particular emphasis on the melting practices, molten metal treatment, and feeding of molten metal into sand molds. It discusses the molten metal treatments for high-silicon gray, high-nickel ductile, and malleable irons. Foundry practices are also described for compacted graphite, high-silicon ductile, and high-alloy white irons.

This article discusses the melting and pouring practices, heat treatment, and applications of different types of high-alloy graphitic iron, namely, high-silicon gray irons, high-silicon ductile irons, nickel-alloyed austenitic irons, austenitic gray irons, austenitic ductile irons, and aluminum-alloyed irons.

Cast iron, which usually refers to an in situ composite of stable eutectic graphite in a steel matrix, includes the major classifications of gray iron, ductile iron, compacted graphite iron, malleable iron, and white iron. This article discusses melting, pouring, desulfurization, inoculation, alloying, and melt treatment of these major ferrous alloys as well as carbon and alloy steels. It explains the principles of solidification by describing the iron-carbon phase diagram, and provides a pictorial presentation of the basic microstructures and processing steps for cast irons.

Magnesium-matrix composites (MgMCs) are very promising as structural materials because of their low density, high specific strength, and excellent castability. This article provides information on the characteristics, mechanical properties, and applications of magnesium alloys and composites. It discusses the microstructures used for the most common magnesium alloys used in metal-matrix composites, namely, magnesium-aluminum, magnesium-rare earth and magnesium-lithium alloys. The article focuses on the most common methods of heat treatment, including solution heat treatment, precipitation strengthening or aging, and annealing, applied to these alloys. Finally, it describes the microstructural aspects and precipitate-matrix relationships of MgMCs as well as the heat treatment methods for MgMCs.

During the melting and solidification of cast irons, certain trace (minor) elements may unintentionally accumulate to an extent that they have a detrimental effect on the microstructure of castings. This article discusses the residual elements, trace elements, and tramp elements in cast irons. Elements that influence the matrix structure of cast irons are commonly classified as ferrite-promoting elements or pearlite-promoting elements. The article describes the effects of minor elements on microstructure and properties of cast irons. It discusses the use of a combination of tools to control the effects of minor elements on the structure and properties of cast irons. The article concludes with information on allowable levels of trace and tramp elements in cast irons.