The rate and form of corrosion that occur in a particular situation depend on many complex variables. This article discusses the rate of corrosion of lead in natural and domestic water depending on the degree of water hardness caused by calcium and magnesium salts. Lead exhibits consistent durability in all types of atmospheric exposure, including industrial, rural, and marine. The article tabulates the corrosion of lead in various natural outdoor atmospheres and the corrosion of lead alloys in various soils. It explains the factors that influence in initiating or accelerating corrosion: galvanic coupling, differential aeration, alkalinity, and stray currents. The resistance of lead and lead alloys to corrosion by a wide variety of chemicals is attributed to the polarization of local anodes caused by the formation of a relatively insoluble surface film of lead corrosion products. The article also provides information on the corrosion rate of lead in chemical environments.

Molten salts, in contrast to aqueous solutions in which an electrolyte (acid, base, salt) is dissolved in a molecular solvent, are essentially completely ionic. This article begins with an overview of the thermodynamics of cells and classification of electrodes for molten salts: reference electrodes and indicator electrodes. It explains that corrosion in molten salts can be caused by the solubility of the metal in the salt, particularly if the metal dissolves in its own chloride. The article describes the factors that affect the corrosion of titanium, namely, the titanium chloride content of the magnesium chloride melt, magnesium or sodium content, and oxygen content of the product. It concludes with a discussion on the oxygen activity in the titanium metal product.

This article begins with a discussion on the corrosion characteristics of unalloyed magnesium and two major magnesium alloy systems. It shows the effects of iron and 13 other elements on the saltwater corrosion performance of magnesium in binary alloys with increasing levels of the individual elements. The article illustrates the effect of increasing iron, nickel, and copper contamination on the standard ASTM B 117 salt-spray performance of the die-cast AZ91 test specimens as compared to the range of performance observed for cold-rolled steel and die-cast aluminum alloy 380 samples. It discusses the effect of heat treating and cold working on the corrosion rates of the die-cast AZ91 alloy. The article concludes with a description on the causes of corrosion failures in magnesium alloys.

This article begins with a discussion on the environmental factors that induce corrosion in magnesium alloys. It reviews the factors that determine the severity of different forms of localized corrosion, namely, galvanic corrosion, corrosion fatigue, and stress-corrosion. The article discusses corrosion protection in magnesium assemblies and the protective coating systems used in corrosion protection practices. Protection schemes for specific applications and the production of novel magnesium alloys with improved corrosion resistance are also reviewed. The article concludes with a discussion on the corrosion of bulk vapor-deposited alloys and magnesium-matrix composites.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

This article discusses the effects of heavy metal impurities, environmental factors, the surface condition (such as as-cast, treated, and painted), and the assembly practice on the corrosion resistance of a magnesium or a magnesium alloy part. It provides information on stress-corrosion cracking and galvanic corrosion of magnesium alloys, as well as the surface protection of magnesium assemblies achieved by inorganic surface treatments.

Filiform corrosion has been observed to occur under a wide range of organic coatings and proceeds with the same general characteristics on steel, aluminum, and magnesium. This article describes the standard tests for filiform corrosion, characteristics and mechanisms of filiform corrosion in steels, as well as coated aluminum and magnesium. It concludes with information on the prevention and mitigation of filiform corrosion accomplished through the adjustment of the environment and changes in the substrate and coating systems.

Aluminum, a commonly used base material for brazing, can be easily fabricated by most manufacturing methods, such as machining, forming, and stamping. This article outlines non-heat-treatable wrought alloys typically used as base metals for the brazing process. It highlights chloride-active and fluoride-active types of fluxes that are used for torch, furnace, or dip brazing processes. The article explains the steps to be performed, including the designing of joints, preblaze cleaning, assembling, brazing techniques (dip brazing, furnace and torch brazing, fluxless vacuum brazing), flux removal techniques, and postbraze heat treatment processes. It concludes with information on the safety precautions to be followed during the brazing process.

This article provides a summary of the conventional technologies used for titanium powder production. It focuses on the various processes for titanium powder production, namely, Hunter, Kroll, Armstrong, MER, TIRO, FFC-Cambridge, Chinuka, and CSIR processes. Employment of titanium powder significantly improves the synthesis of titanium and its alloys.

Surface treatments are applied to magnesium parts primarily to improve their appearance and corrosion resistance. Mechanical and chemical cleaning methods are used singly or in combination, depending on the specific application and product involved to ensure repetitive reliability. This article focuses on mechanical finishing methods, namely, barrel tumbling, polishing, buffing, vibratory finishing, fiber brushing, and shot blasting. It provides useful information on process control and difficulties with chemical and anodic treatments of magnesium alloys. The use and applications of plating and organic finishing of magnesium alloys are also reviewed. The article concludes with a description of health and safety precautions to be followed during the surface treatment process.

Metal contamination of the environment reflects both natural sources and industrial activity, affecting human health. This article begins with a discussion on the level of metal exposure resulting in toxicological effects, the factors influencing toxicity of metals, and carcinogenicity of metal compounds. It discusses some commonly used chelating agents for treating metal intoxication, and clinical effectiveness in treating poisoning by different metals. The metals discussed are grouped into four categories: (1) major toxic metals with multiple effects, including arsenic, beryllium, cadmium, chromium, lead, mercury, and nickel; (2) essential metals with potential for toxicity, including cobalt, copper, iron, manganese, molybdenum, selenium, and zinc; (3) metals with toxicity related to medical therapy, including aluminum, bismuth, gallium, gold, lithium, and platinum; and (4) minor toxic metals, including antimony, barium, indium, magnesium, silver, tellurium, thallium, tin, titanium, uranium, and vanadium. The main factors included in the discussion are their disposition, toxicity, biological factors and treatment.

This article reviews the melt processing and casting of non-ferrous alloys, such as nickel alloys, titanium alloys, and lead alloys. It describes the lead refining steps, namely, copper drossing, softening, desilvering, zinc removal, bismuth removal, and final refining.

This article briefly describes the basic attributes of chromate conversion coatings and the processes for applying them. It provides information on the influence of substrate microstructure on the performance of coating deposits and on the mechanism of substrate protection supplied by chromate coatings. The article also discusses the development of replacement technologies in response to environmental constraints that have developed around the use of chromium-base compounds.

This article describes the influences of the operational environments of U.S. Navy aircraft during corrosion-control process. The most widely used materials in airframe structures and components, such as aluminum, steel, titanium, and magnesium alloy systems, are reviewed. The article provides information on the inspections steps, corrosion-control issues, and corrosion-prevention strategies for naval aircraft. It contains a table that lists typical locations of corrosion on the aircraft. The article also provides examples of aircraft corrosion damage.

This article focuses on lubricants classified as either internal combustion engine or nonengine lubricants, and the lubricant additives. The functional groups of chemically active and inert additives, as well as friction modifiers and other additives, are described in detail. The chemically active additives include dispersants, detergents, antiwear, and extreme-pressure agents, oxidation inhibitors, and rust and corrosion inhibitors. The chemically inert additives include emulsifiers, demulsifiers, pour-point depressants, foam inhibitors, and viscosity improvers. The article also discusses the multifunctional nature of additives and concludes with information on lubricant formulation.

Corrosion of metals is defined as deterioration caused by chemical or electrochemical reaction of the metal with its environment. This article provides information on corrosion of iron and steel by aqueous and nonaqueous media. It discusses the corrosive environments of carbon and alloy steels, namely atmospheric corrosion, soil corrosion, corrosion in fresh water and seawater. The article describes the corrosion process in concrete, which tends to create conditions that increase the rate of attack. The focus is on the stress-corrosion cracking of steels; an environmentally induced crack propagation that results from the combined interaction of mechanical stress and corrosion reactions. The article tabulates a guide on corrosion prevention for carbon steels in various environments. It also discusses protection methods of steel from corrosion, including coatings, such as temporary protection, cleaning, hot dip coating, electroplating, thermal spray coatings, conversion coatings, thin organic coatings, and inhibitors.

This article is a comprehensive collection of engineering property data in tabulated form for ceramics and glasses. Data are provided for physical and mechanical properties of ceramic materials and color of ceramics fired under oxidizing and reducing conditions. The article also lists the materials characterization techniques for ceramics and glasses.

This article provides information about the selection of brazing processes and filler metals and describes the brazing (heating) methods, including manual torch brazing, furnace brazing, induction brazing, dip brazing, resistance brazing and specialized brazing processes such as diffusion and exothermic brazing. The article explains joint design, filler materials, fuel gases, equipment, and fluxes in the brazing methods. The article also describes the brazing of steels, stainless steels, cast irons, heat-resistant alloys, aluminum alloys, copper and copper alloys, and titanium and titanium alloys.

This article provides information about the selection of brazing processes and filler metals and describes the brazing (heating) methods, including manual torch brazing, furnace brazing, induction brazing, dip brazing, resistance brazing and specialized brazing processes such as diffusion and exothermic brazing. The article explains joint design, filler materials, fuel gases, equipment, and fluxes in the brazing methods. The article also describes the brazing of steels, stainless steels, cast irons, heat-resistant alloys, aluminum alloys, copper and copper alloys, and titanium and titanium alloys.

Tantalum is one of the most versatile corrosion-resistant metals known. The outstanding corrosion resistance and inertness of tantalum are attributed to a very thin, impervious, protective oxide film that forms on exposure of the metal to slightly anodic or oxidizing conditions. This article provides a discussion on the mechanism of corrosion resistance and on the behavior of tantalum in different corrosive environments, namely, acids; salts; organic compounds; reagents, foods, and pharmaceuticals; body fluids and tissues; and gases. It contains several tables that summarize the effects of acids, salts, and miscellaneous corrosive reagents on tantalum and applications for tantalum equipment in chemical, pharmaceutical, and other industries. Finally, the article presents a discussion on hydrogen embrittlement, the galvanic effects, and cathodic protection of tantalum and describes the corrosion resistance of different types of tantalum-base alloys.