This article focuses on the intermediate length scales, where transport phenomena govern the spatial and temporal evolution of a structure. It presents the cellular automaton (CA) and phase field (PF) methods that represent the state of the art for modeling macrostructure and microstructure. The article describes the principles of the PF method and provides information on the applications of the PF method. The CA model is introduced as a computationally efficient method to predict grain structures in castings using the mesoscopic scale of individual grains. The article discusses the coupling of the CA to macroscopic calculation of heat, flow, and mass transfers in castings and applications to realistic casting conditions.

This article begins with balance equations for mass, momentum, energy, and solute and the necessary boundary conditions for solving problems of interest in casting and solidification. The transport phenomena cover a vast range of length and time scales, from atomic dimensions up to macroscopic casting size and from nanoseconds for interface attachment kinetics to hours for casting solidification. The article describes how to determine which phenomena are most important at the particular length and time scale for the problem. It concludes with several examples of the application of transport phenomena in solidification, focusing in particular on microstructure formation.

This article describes the roll forming of components of nickel, titanium, and aluminum alloys. The metallurgical characteristics of the roll formed components, such as macrostructures, microstructures, tensile strength, and stress rupture performance, are discussed. The article compares the resulting properties of roll formed and conventionally forged components.

This article briefly discusses popular techniques for metals characterization. It begins with a description of the most common techniques for determining chemical composition of metals, namely X-ray fluorescence, optical emission spectroscopy, inductively coupled plasma optical emission spectroscopy, high-temperature combustion, and inert gas fusion. This is followed by a section on techniques for determining the atomic structure of crystals, namely X-ray diffraction, neutron diffraction, and electron diffraction. Types of electron microscopies most commonly used for microstructural analysis of metals, such as scanning electron microscopy, electron probe microanalysis, and transmission electron microscopy, are then reviewed. The article contains tables listing analytical methods used for characterization of metals and alloys and surface analysis techniques. It ends by discussing the objective of metallography.

This article describes the methods and equipments involved in the preparation of specimens for examination by light optical microscopy, scanning electron microscopy, electron microprobe analysis for microindentation hardness testing, and for quantification of microstructural parameters, either manually or by the use of image analyzers. Preparation of metallographic specimens generally requires five major operations: sectioning, mounting, grinding, chemical polishing, and etching. The article provides information on the principles of technique selection in mechanical polishing, and describes the procedures, advantages, and disadvantages of electrolytic and chemical polishing. It also provides a detailed account of procedures, precautions, and composition for preparation and handling of etchants.

This article discusses the visual and microscopic characteristics of fractures of cast alloys. The fractures include ductile rupture, transgranular brittle fracture, intergranular fracture, fatigue, and environmentally induced fracture. The article describes the factors that affect the fracture appearance.

This article describes the changes in structure and properties that occur when cold worked metals and alloys are annealed. Recovery, recrystallization, and grain growth are the three stages of structural change that occur when cold-worked metal is annealed. The driving force and extent of structural or property changes may depend on alloy structure and the degree of prior work.

This article provides a brief historical perspective, a classification of metallurgical processes, basic model development efforts, and an overview of the potential future directions for the modeling of metals processing. It describes the classification of material behavior models, which can be grouped broadly into three classes: statistical, phenomenological, and mechanistic models. The article also presents an overview of the potential directions for the modeling of metals processing.

Metallic nonelectrolytic alloy coatings produced from aqueous solutions are commercially used in several industries, including electronics, aerospace, medical, oil and gas production, chemical processing, and automotive. Nonelectrolytic coating systems use two types of reactions to deposit metal onto a part: electroless and displacement. This article explains the various types of electroless and dispersion alloy coating systems. It provides information on the processing of parts, process control, deposit analysis, and equipment used for coating nonelectrolytic displacement alloys. The article concludes with a discussion on the safety and environmental concerns associated with nonelectrolytic deposition processes.

The reflected light microscope is the most commonly used tool to study the microstructure of metals, composites, ceramics, minerals, and polymers. For the study of the microstructure of metals and alloys, light microscopy is employed in the reflected-light mode using either bright-field illumination, dark-field illumination, polarized light illumination, or differential interference contract, generally by the Nomarski technique. This article concentrates on how to reveal microstructure properly to enable the proper identification of the phases and constituents and, if needed, measuring the amount, size, and spacing of constituents, using the light optical microscope. The discussion covers the examination of microstructures using different illumination methods and includes a comparison between light optical images and scanning electron microscopy images of microstructure.

Modeling of structure formation in casting of alloys involves several length scales, ranging from the atomic level to macroscopic scale. Intermediate length scales are used to define the microstructure of the growing phases and the grain structure. This article discusses the principles and applications of phase field method and cellular automaton method for modeling the direct evolution of structure at the intermediate length scales, where transport phenomena govern the spatial and temporal evolution of the structure that involves nucleation and growth.

A number of nondestructive evaluation (NDE) methods, such as radiography, ultrasound, and eddy current, are available to detect flaws in solid materials. This article describes the fundamental aspects of these NDE methods in terms of operation principles. It presents some examples of the methods performed on various types of flaws resulting from solid-state welding processes.

This article describes the metallographic technique for nonferrous metals and special-purpose alloys. These include aluminum alloys, copper and copper alloys, lead and lead alloys, magnesium alloys, nickel and nickel alloys, magnetic alloys, tin and tin alloys, titanium and titanium alloys, refractory metals and alloys, zinc and zinc alloys, and wrought heat-resisting alloys. The preparation of specimens for metallographic technique includes operations such as sectioning, mounting, grinding, polishing, and etching of nonferrous metals and alloys. The article contains tables that list the etchants for macroscopic examination and microscopic examination of nonferrous metals and special-purpose alloys.

Proper sectioning of the surface to be examined is a very important step in preparing steel specimens. The first step in preventing damage to the metallurgical structure is to minimize the amount of sectioning that is done. This article discusses the various metallographic techniques, namely mounting, grinding, polishing, and etching involved in the microstructural analysis of carbon and alloy steels, case hardening steels, cast iron, ferrous powder metallurgy alloys, wrought and cast stainless steels, tool materials, steel castings, iron-chromium-nickel heat-resistant casting alloys and different product forms of steels.

Metalworking is one of the three major technologies used to fabricate metal products. This article tabulates the classification of metal forming processes. It discusses different types of metalworking equipment, including rolling mills, ring-rolling machines, and thread-rolling and surface-rolling machines. The article outlines the significant characteristics of pressing-type machines: load and energy characteristics, time-related characteristics, and accuracy characteristics. It summarizes different specialized processes such as advanced roll-forming methods, equal-channel angular extrusion, incremental forging, and microforming. The article describes the thermomechanical processing of nickel- and titanium-base alloys and concludes with information on the advancements in process simulation.

Electroslag remelting (ESR) is commonly used to produce the highest levels of quality in plate steels, particularly in thick plates. This article provides an overview of the ESR and discusses the major components and operations of the ESR furnaces. It describes the principles of ingot solidification and various defects of remelted ingot such as tree ring patterns, freckles, and white spots. The article explains several variations of ESR such as pressure electroslag remelting, remelting under reduced pressure, and electroslag rapid remelting. It examines the features of steel ESR and superalloy ESR.

The vacuum arc remelting (VAR) process is widely used to improve the cleanliness and refine the structure of standard air melted or vacuum induction melted (VIM) ingots and also used in the triplex production of superalloys. This article illustrates the VAR process and the capabilities and variables of the VAR process. It also presents a discussion on the melt solidification, resulting structure, and ingot defects. The article concludes with a discussion on VAR process of superalloy, and titanium and titanium alloy.

This article provides an overview of the types, properties, and applications of traditional and advanced ceramics and glasses. Principal product areas for traditional ceramics include whitewares, glazes, porcelain enamels, structural clay products, cements, and refractories. Advanced ceramics include electronic ceramics, optical ceramics, magnetic ceramics, and structural ceramics.

Titanium metal passes through three major steps during processing from ore to finished product: reduction of titanium ore to sponge (porous form), melting of sponge and scrap to form ingot, and remelting and casting into finished shape. This article describes primary fabrication, including all operations that convert ingot into general mill products, such as billet, bar, plate, sheet, strip, tube, and wire. The section on secondary fabrication describes processes such as die forging, extrusion, hot and cold forming, machining, chemical milling, and joining. The article presents a short note on powder metallurgy products of titanium. Casting processes and properties are covered in the final section.

This article presents the three levels of investigations of distortion engineering. On Level 1, the parameters and variables influencing distortion in every manufacturing step must be identified. More than 200 parameters can affect distortion. The design of experiments approach allows for the investigation of larger numbers of parameters by a limited number of samples, and can be structured into system analysis, test strategy, test procedure, and test evaluation. Level 2 focuses on understanding the distortion mechanisms by using the concept of distortion potential and its carriers. Distortion engineering aims to compensate distortion using the so-called compensation potential (Level 3). Level 3 discusses the measures to improve homogeneity, and respectively the symmetry, of the carriers of the distortion potential. The article also discusses the compensation of the resulting size and shape changes of the existing asymmetries by well-directed insertions of additional inhomogeneity/asymmetries in one or more of the distributions of the carriers.