Thin-wall gray cast iron (TWGCI) can be seen as a potential material for the preparation of lightweight castings in automotive engineering applications. This article discusses the most important challenges for TWGCI: cooling rate, solidification, macrostructure, microstructure, and chilling tendency. It reviews the tensile properties and thermophysical properties of gray cast iron. The article describes the variables that influence molten iron preparation: charge materials, melting furnace thermal regime, chemical composition, modification and inoculation treatment, holding time/pouring procedure, mold properties (mold temperature, thermophysical properties of mold and mold coating), and casting design.

This article discusses the characterization of gray iron structures, following the sequence of structure formation, as it applies to unalloyed or low-alloyed gray iron. Austenite grains are the basic crystallographic entities of the metallic matrix in gray cast iron precipitated from the liquid melt. The article describes the macrostructure and dendrite morphology of primary austenite. Eutectoid transformation in the solid state causes the transformation of austenite to pearlite and/or ferrite, producing the as-cast structure. The article discusses the observations of the graphite and ferritic/pearlitic structure in as-cast gray iron.

This article focuses on the intermediate length scales, where transport phenomena govern the spatial and temporal evolution of a structure. It presents the cellular automaton (CA) and phase field (PF) methods that represent the state of the art for modeling macrostructure and microstructure. The article describes the principles of the PF method and provides information on the applications of the PF method. The CA model is introduced as a computationally efficient method to predict grain structures in castings using the mesoscopic scale of individual grains. The article discusses the coupling of the CA to macroscopic calculation of heat, flow, and mass transfers in castings and applications to realistic casting conditions.

This article begins with balance equations for mass, momentum, energy, and solute and the necessary boundary conditions for solving problems of interest in casting and solidification. The transport phenomena cover a vast range of length and time scales, from atomic dimensions up to macroscopic casting size and from nanoseconds for interface attachment kinetics to hours for casting solidification. The article describes how to determine which phenomena are most important at the particular length and time scale for the problem. It concludes with several examples of the application of transport phenomena in solidification, focusing in particular on microstructure formation.

This article describes the roll forming of components of nickel, titanium, and aluminum alloys. The metallurgical characteristics of the roll formed components, such as macrostructures, microstructures, tensile strength, and stress rupture performance, are discussed. The article compares the resulting properties of roll formed and conventionally forged components.

The science of physical metallurgy is a very broad topic that includes the structure of metals. This article introduces the general structural features of metals. It provides background, general references, and some connections among the subject matter explored more fully in the specialized articles included in the other parts of this section. The article includes information on the origins of structures, and single-phase and multiphase microstructures. It discusses some important topics, such as grain structure and substructure, that are not covered systematically and comprehensively in the other articles. Finally, the article also brings in the scale of structural features and the concept of hierarchical relations among them.

The ferrous metals are the most significant class of commercial alloys. This article describes the solidification structures of plain carbon steel, low-alloy steel, high-alloy steel, and cast iron, with illustrations. The formation of nonmetallic inclusions in the liquid before and during solidification is also discussed.

This article illustrates the polymer matrices used for composite materials. It describes the use of prepeg materials in manufacturing high-performance composites. The article discusses the various infusion processes for the development of fiber-reinforced composites, namely, resin transfer molding, vacuum-assisted resin transfer molding, and resin film infusion. It explains the composite- and matrix-toughening methods for fiber-reinforced composites, such as dispersed-phase toughening and interlayer toughening. The article concludes with information on optical microscopy, which provides an insight into the micro- and macrostructure of fiber-reinforced composites.

This article briefly reviews the analysis methods for spalling of striking tools with emphasis on field tests conducted by A.H. Burn and on the laboratory tests of H.O. McIntire and G.K. Manning and of J.W. Lodge. It focuses on the metallography and fractography of spalling. The macrostructure and microstructure of spall cavities are described, along with some aspects of the numerous specifications for striking/struck tools. The article also describes the availability of spall-resistant metals and the safety aspects of striking/struck tools in railway applications.

This article describes the characterization of welds as a sequence of procedures, where each procedure is concerned with a finer scale of detail. The first level of characterization involves information that may be obtained by direct visual inspection and measurement of the weld. The article discusses nondestructive evaluation of welds by encompassing techniques that are used to characterize the locations and structure of internal and surface defects, including radiography, ultrasonic testing, and liquid penetrant inspection. It reviews the macrostructural characterization of a sectioned weld, including features such as number of passes; weld bead size, shape, and homogeneity; and the orientation of beads in a multipass weld. The article provides examples that describe how welds are characterized according to the procedures.

Optical metallography, one of the most common materials characterization techniques, uses visible light to magnify structural features of interest. This article discusses the use of optical methods to evaluate micro and macrostructure and relate it to process conditions and material behavior. It covers the steps involved in sample preparation, including sectioning, mounting, grinding, polishing, and etching, and presents several examples of macro and microanalysis on various metals and alloys.

The process of fatigue failure consists of three stages: initial fatigue damage leading to crack initiation; crack propagation to some critical size; and final, sudden fracture of the remaining cross section. Variations in mechanical properties, composition, microstructure, and macrostructure, along with their subsequent effects on fatigue life, have been studied extensively to aid in the appropriate selection of steel to meet specific end-use requirements. The metallurgical variables having the most pronounced effects on the fatigue behavior of carbon and low-alloy steels are strength, ductility, cleanliness, residual stresses, surface conditions, and aggressive environments. The article discusses the stress-based and strain-based approach to fatigue. The application of fatigue data in engineering design is complicated by the characteristic scatter of fatigue data; variations in surface conditions of actual parts; variations in manufacturing processes such as bending, forming, and welding; and the uncertainty of environmental and loading conditions in service.

This article is a comprehensive collection of tables listing: dangerous reactions of chemicals and designations of etchants; chemical-polishing solutions for irons and steels and nonferrous materials; attack-polishing solutions, macrostructure etchants for iron and steel; and major microstructure etchants for common phases and constituents in ferrous materials.

This article describes the microstructure and metallographic practices used for medium- to high-carbon steels as well as for low-alloy steels. It explains the microstructural constituents of plain carbon and low-alloy steels, including ferrite, pearlite, and cementite. The article provides information on how to reveal the various constituents using proven metallographic procedures for both macrostructural and microstructural examination. Emphasis is placed on the specimen preparation procedures such as sectioning, mounting, grinding, and polishing. The article illustrates the use of proven etching techniques for plain carbon and low-alloy steels.

Thermite welding (TW) is a fusion welding process in which two metals become bonded after being heated by superheated metal that has experienced an aluminothermic reaction. This article describes the thermite welding principles by presenting equations of the aluminothermic reaction that occurs in thermite welding. It provides information on the applications of thermite welding: rail welding, electrical connections, and railroad applications. The article concludes with a discussion on the associated safety aspects.

This introductory article provides basic information on the various aspects of solid-state transformation: multiphase microstructures, substructures, and crystallography, which assist in characterizing the morphology of phase transformations. It contains a flowchart that illustrating the classification of transformations by growth processes.

This article begins with a description of indirect and direct semisolid metalworking processes. It then provides information on alloy compositions of common aluminum semisolid metalworking alloys and primary die-cast magnesium alloys in a tabular form. The article describes the macroscopic examination of defects, which occur in semisolid metalworking with illustrations. It discusses the macroscopic examination of gating systems and semisolid feedstocks. The article also provides information on feedstock microstructures, direct semisolid metalworking component microstructures, and indirect semisolid metalworking component microstructures of series 300 aluminum casting alloys and magnesium die-casting alloys.

This article provides a review of metallographic procedures and techniques for analyzing the microstructure of fusion welded joints. It discusses sample preparation, the use of backing plates, and common sectioning methods. It identifies the various types of defects that can occur in arc welded metals, organizing them according to the sectioning method by which they are observed. It describes the relationship between weld bead morphology and sectioning direction and its effect on measurement error. The article examines micrographs from stainless steel, aluminum, and titanium alloy joints, highlighting important details such as solidification and solid-state transformation structures and what they reveal about the welding process. Besides arc welding, it also discusses laser and electron beam welding methods, resistance and spot welding, and the welding of dissimilar metals.

The most common aluminum alloy systems are aluminum-silicon, aluminum-copper, and aluminum-magnesium. This article focuses on the grain structure, eutectic microstructure, and dendritic microstructure of these systems. It provides information on microsegregation and its problems in casting of alloys. The article also illustrates the casting defects such as macroporosity, microshrinkage, and surface defects, associated with the alloys.

This article provides an overview of the origin of metallography. It presents information on how to select a section from a specimen and prepare it for macroscopic analysis. The article describes the macroscopic analysis of steel fracture surfaces with emphasis on ductile, brittle, and fatigue fracture with illustrations. It discusses microanalysis with a focus on the method of light microscopy and includes information of scanning electron microscope in fractography. The article also explains the characteristics of solidification, transformation, deformation structures, and discontinuities that are present in a microstructure. It concludes with information on image analysis.