Search Results for liquid-solid-state bonding

Diffusion bonding is only one of many solid-state joining processes wherein joining is accomplished without the need for a liquid interface (brazing) or the creation of a cast product via melting and resolidification. This article offers a qualitative summary of the theory of diffusion bonding. It discusses factors that affect the relative difficulty of diffusion bonding oxide-bearing surfaces. These include surface roughness prior to welding, mechanical properties of the oxide, relative hardness of the metal and its oxide film, and prestraining or work hardening of the material. The article describes the mechanism of diffusion bonding in terms of microasperity deformation, diffusion-controlled mass transport, and interface migration. It concludes with a discussion on diffusion bonding with interface aids.

Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.

Thermodynamic descriptions have become available for a large number of alloy systems and allow the calculation of the phase diagrams of multicomponent alloys. This article begins with a discussion on three laws of thermodynamics: the Law of Conservation of Energy, the Second Law of Thermodynamics, and the Third Law of Thermodynamics. It informs that for transformations that occur at a constant temperature and pressure, the relative stability of the system is determined by its Gibbs free energy. The article describes the Gibbs free energy of a single-component unary system and the Gibbs free energy of a binary solution. It schematically illustrates the structure of a binary solid solution with interatomic bonds and shows how the equilibrium state of an alloy can be obtained from the free-energy curves at a given temperature. The article concludes with information on the construction of eutectic and binary phase diagrams from Gibbs free-energy curves.

This article begins with the one-component, or unary, diagram for magnesium. The diagram shows what phases are present as a function of the temperature and pressure. When two metals are mixed in the liquid state to produce a solution, the resulting alloy is called a binary alloy. The article describes the various types of solid solutions such as interstitial solid solutions and substitutional solid solutions. Free energy is important because it determines whether or not a phase transformation is thermodynamically possible. The article discusses the thermodynamics of phase transformations and free energy, as well as kinetics of phase transformations. It concludes with a description of solid-state phase transformations that occur when one or more parent phases, usually on cooling, produces a phase or phases.

Diffusion welding involves minimal pressurization, but relatively high temperatures and long periods of time. This article discusses the process variants of diffusion welding: solid-phase and liquid-phase processes. It describes the diffusion welding of carbon and low-alloy steels, high-strength steels, stainless steels, and aluminum-base alloys. The article provides a discussion on dissimilar metal combinations, such as ferrous-to-ferrous combinations, nonferrous-to-nonferrous combinations, ferrous-to-nonferrous combinations, and metal-ceramic joining.

This article describes the mechanism, advantages and disadvantages, fundamentals, capabilities, variations, equipment used, and weldability of metals in solid-state welding processes, including diffusion bonding, explosion welding, friction welding, ultrasonic welding, upset welding, and deformation welding.

Many applications of ceramics and glasses require them to be joined to each other or to other materials such as metals. This article focuses on ceramic joining technologies, including glass-metal sealing, glass-ceramic/metal joining, ceramic-metal joining, ceramic-ceramic joining, and the more advanced joining of nonoxide ceramics. It also discusses metallizing, brazing, diffusion bonding, and chemical bonding.

This article provides a fundamentals-based description of solid-state resistance projection welding. It details simple analytical tools to understand the variety of mechanisms that occur during resistance projection welding. Factors relating to the quality of solid projection are discussed, in addition to an explanation of the mechanisms of bonding for solid projection welding. The article reviews how these mechanisms are affected by heat balance, current profile, and mechanical characteristics of the welding equipment. It also presents the design of projection welding mechanical systems.

This article describes the solid-phase and liquid-phase processes involved in diffusion bonding of metals. It provides a detailed discussion on the diffusion bonding of steels and their alloys, nonferrous alloys, and dissimilar metals. Ceramic-ceramic diffusion welding and a variation on this process in which ceramic powder compacts are simultaneously sintered and bonded are also discussed.

This article provides information on thermal spray coating features, which combine to determine the properties of a coating. These include the lamellar or layered splat structure, entrapped unmelted or resolidified particles, pores, oxide inclusions, grains, phases, cracks, and bond interfaces. The article describes the sources of porosity and the factors that control the final coating porosity levels. The article also lists the materials most suitable for thermal spraying processes.

This article provides a qualitative summary of the theory of diffusion bonding, as distinguished from the mechanisms of other solid-state welding processes. Diffusion bonding can be achieved for materials with adherent surface oxides, but the resultant interface strengths of these materials are considerably less than that measured for the parent material. The article describes three stages of diffusion bonding: microasperity deformation, diffusion-controlled mass transport, and interface migration. It concludes with information on diffusion bonding with interface aids.

The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can exist as a solid, liquid, and/or gas, depending on the specific combination of temperature and pressure. It describes the accomplishment of conversion between weight percentage and atomic percentage in a binary system by the use of formulas. The article analyzes the effects of alloying on melting/solidification and on solid-state transformations. It explains the construction of phase diagrams by the Gibbs phase rule and the Lever rule. The article also reviews the various types of alloy systems that involve solid-state transformations. It concludes with information on the sources of phase diagram.

This article describes the high-temperature solid-state welding process used to join members of similar or dissimilar materials by three stages, namely, primary bonding, bond-surface extension, and elimination of the original joining surface. It lists the various advantages and disadvantages of the high-temperature solid-state welding process. The article discusses important process parameters for high-temperature solid-state welding, such as temperature, pressure, welding time, and welding atmosphere. It concludes with information on the application of the process in the fields of aerospace and nuclear engineering.

Strategies for the lubrication of mechanical systems operating in extreme environments must exclude the liquid lubricants and greases and rely on alternative methods of lubrication, such as gases and solids. This article provides a survey of some of the more effective alternative methods of lubrication. It provides a discussion on the solid materials that have been most commonly used as lubricants: carbon-base materials, transition metal dichalcogenides, polymers, and soft metals.

This article focuses on the various criteria considered in the selection of product forms, joint types, solders, and filler metals for brazing and soldering of base material components.

Liquid metal induced embrittlement (LMIE) is the reduction of the fracture resistance of a solid material during exposure to a liquid metal. This article discusses the mechanisms and occurrence condition of LMIE and describes the effects of metallurgical factors, such as grain size, temperature and strain rate, stress, inert carriers, and fatigue, on LMIE. It provides a detailed discussion on LMIE in ferrous and nonferrous metals and their alloys. In addition, the article highlights the ways of preventing embrittlement in metals and alloys.

This article describes high-performance liquid chromatography and ultra-high-performance liquid chromatography that are used to separate and quantify the chemical components in any sample that can be dissolved in a liquid. This includes pharmaceutical drugs, medicinal plant extracts, food constituents, flavors, fragrances, industrial chemicals, pesticides, and pollutants. Readers are introduced to the most commonly employed mode, reverse-phase chromatography, with examples and an exclusive focus on commercially available instruments and consumables. The discussion covers the various processes involved in liquid chromatography, including assessing a separation of sample components, adjusting the mobile phase, choosing the stationary phase, optimizing a separation, preparing real samples, and analyzing complex samples.

This article describes the coating materials, surface-preparation requirements, and application techniques used to protect underground pipelines. It provides a valuable insight into the types of polymer-based coatings that are both cost-effective and widely accepted in the pipeline industry.

This article describes low-temperature solid-state welding processes in relation to the interlayer fabrication method, welding method, and welding parameters. The interlayer fabrication method is used to produce vacuum coated interlayers, electrodeposited interlayers, and foil interlayers. The article discusses welding methods, including uniaxial compression and hot isostatic pressing. The article provides information on the effect of base-metal surface finish on the tensile strength of joints solid-state welded using silver interlayers in tabular form and addresses the surface cleaning steps of base-metals.