Electrode potential is a key parameter in the thermodynamic and kinetic processes that drive aqueous corrosion. This article discusses the complexities associated with measuring electrode potential and explains where and how to use reference electrodes to improve measurement accuracy. It describes a three-electrode approach that compensates for measurement error stemming from nonequilibrium conditions. It also examines electrode materials and behaviors and offers insights on selection and operating conditions.

This article discusses a tool for the conversion of measurements made against various reference electrodes at different temperatures. It reviews different electrode potential temperature coefficients, namely, isothermal temperature coefficient and thermal temperature coefficient. The article contains a table that lists the electrode potentials and conversion factors for various reference electrodes.

Potentiometric membrane electrodes are electrochemical devices that can be used to quantify numerous ionic and nonionic species. This class of electrochemical sensors can be divided into ion-selective and gas-sensing membrane electrodes. The first half of this article mainly focuses on the subclasses, the membrane potential, electrode selectivity limitations and the methods of analysis of the ion-selective membrane electrodes. These methods of analysis include the use of calibration curves, addition techniques, subtraction techniques, and titration. The second half outlines gas sensing membrane electrodes, and discusses important elements that must be considered in addition to the potentiometric membrane electrode to ensure proper electrode response. These elements are reference electrodes, temperature controls, recording of the potential with respect to time, electrode storages, and sample pretreatment. The article also explains the applications of the potentiometric membrane electrodes with the aid of an example.

This article provides a general introduction on casting processes and design techniques. It discusses the process steps and methods of the main categories of shape casting methods, namely, expendable molds with permanent patterns, expendable molds with expendable patterns, and metal or permanent mold processes. The article lists the general guidelines of geometry in casting design. It describes the three separate contractions that are a result of cooling: liquid-liquid contraction, solid-solid contraction, and liquid-solid contraction. Factors influencing the solidification sequence of simple shapes, such as T-sections, X-sections, and L-sections, are discussed. The article also presents an overview of geometric factors that influence heat transfer and transport phenomena. It concludes with a description of the structure and properties of castings.

This article presents common conventions and definitions in corrosion, electrochemical cells, cathodic protection (CP), electricity, and oxidation. Evans diagrams for impressed current CP in neutral or basic environment and galvanic or sacrificial CP, in both neutral or basic environment and acidic environment, are illustrated.

This article introduces filling and feeding concepts from the general perspective of what constitutes a good casting practice. It briefly reviews the concepts that may help to clarify and quantify objectives for more effective mold-filling designs. The article describes the preprimed filling system through various partial solutions to the prepriming approach. It discusses the six individual parts of the naturally pressurized filling system, namely, offset stepped pouring basin, sprue, sprue/runner junction, runner, gates, and feeding via feeders. The article also lists the key features of the system.

Superconductivity has been found in a wide range of materials, including pure metals, alloys, compounds, oxides, and organic materials. Providing information on the basic principles, this article discusses the theoretical background, types of superconductors, and critical parameters of superconductivity. It discusses the magnetic properties of selected superconductors and types of stabilization, including cryogenic stability, adiabatic stability, and dynamic stability. The article also focuses on alternating current losses in superconductors, including hysteresis loss, penetration loss, eddy current loss, and radio frequency loss. Furthermore, the article describes the flux pinning phenomenon and Josephson effects.

Gray cast iron is one of the most tolerant of metals when used with poorly designed filling systems. Good filling systems are necessary for the production of sound and acceptable ductile iron castings. This article presents an outline description of well-designed filling systems for all varieties of cast iron and all varieties of molds. It discusses the general conditions for the filling system layout, including the downsprue, sprue/runner junction, and runner. Both gray cast iron and compacted graphite iron exhibit a growth of graphite in direct contact with the liquid metal. The article concludes with a discussion on feeding of ductile iron.

Temperature control in heat treating is of paramount importance in maintaining the quality and achieving the desired metallurgical results. This article provides a detailed account of the factors affecting temperature control in heat treating furnaces, with information on temperature control systems, including contact sensors, noncontact sensors, controllers, energy-flow regulators, measurement instruments, and set-point programmers. Common contact sensors include temperature scales, thermocouples, and resistance temperature detectors, whereas optical pyrometers and on-line radiation thermometers fall under the noncontact type. The article describes two types of instrumentation used in heat treating: field test instruments for temperature-uniformity surveys and system-accuracy tests; and controlling, monitoring, and recording instruments for digital instrumentation.

Thermocouple devices are the most widely used devices for measurement of temperature in the metals industry. Favorable characteristics of these devices include good accuracy, suitability over a wide temperature range, fast thermal response, ruggedness, high reliability, low cost, and great versatility of application. Thermocouples are grouped into two broad categories, namely, standard thermocouples, including five base-metal thermocouples and three noble-metal thermocouples that have been given letter designations, and nonstandard thermocouples, including iridium-rhodium, platinum-molybdenum, platinel, and tungsten-rhenium thermocouples. This article discusses the basic principles, classification, and properties of thermocouples, and the techniques for insulating and protecting thermocouple wires from the operating environment.

Steel storage tanks are the primary means for storing large volumes of liquids and gaseous products. The stored fluid could be water, but it could also be volatile, corrosive, and flammable fluid requiring special precautions for storage as well. Corrosion is generally worst where the tank is in contact with the soil. This article describes the soil characteristics and addresses cathodic protection (CP) criteria for submerged metallic piping systems. It provides information on the data required for designing a CP system, alone or in conjunction with a protective coating system. These data are collected from predesign site assessments, tank electrical characteristics, and soil-resistivity measurements. The article addresses NACE Standard RP0169, which gives requirements and desired characteristics for coating in conjunction with CP. It also explains the methods of protecting aboveground storage tanks and underground storage tanks.

This article provides a discussion on ten rules for the effective production of reliable castings. These rules include good-quality melt, liquid front damage, liquid front stop, bubble damage, core blows, shrinkage damage, convection damage, segregation, residual stress, and location points.

This article describes various methods of electrochemical analysis, namely coulometry, electrogravimetry, voltammetry, electrometric titration, and nanometer electrochemistry. The discussion covers the general uses, sample requirements, application examples, advantages, and limitations of these methods. Some of the factors pertinent to electrochemical cells are also provided. In addition, the article provides information on various potentiometric membrane electrodes used to quantify numerous ionic and nonionic species.

Casting offers a great amount of component design flexibility. This article discusses six casting design parameters that drive the geometry of casting design from a process standpoint. It provides information on the design of junctions and addresses considerations of secondary operations in design. The article describes the factors that control casting tolerances and presents specific tips for designing castings with uniform wall thickness, unequal sections, thin sections, economical coring, functional packaging, and core design. The article provides a framework for analyzing all manners of manufacturing as possible conversion candidates for casting. It concludes with a discussion on different metalcasting design projects.

This article focuses on the corrosion fatigue testing of steel in high-temperature water and discusses critical experimental issues associated with it. It provides information on the fundamental aspects of environmental crack advancement in general. The article explains the concepts and role of environmentally assisted crack growth in corrosion fatigue. It also discusses the fatigue test methods, including crack initiation testing and crack propagation testing. The article describes the specific types and influence rankings of experimental variables in corrosion fatigue.

Molten salts, in contrast to aqueous solutions in which an electrolyte (acid, base, salt) is dissolved in a molecular solvent, are essentially completely ionic. This article begins with an overview of the thermodynamics of cells and classification of electrodes for molten salts: reference electrodes and indicator electrodes. It explains that corrosion in molten salts can be caused by the solubility of the metal in the salt, particularly if the metal dissolves in its own chloride. The article describes the factors that affect the corrosion of titanium, namely, the titanium chloride content of the magnesium chloride melt, magnesium or sodium content, and oxygen content of the product. It concludes with a discussion on the oxygen activity in the titanium metal product.

This article is a comprehensive collection of terms related to corrosion fundamentals, testing, and protection.

Control of temperature and furnace atmospheres has become increasingly critical to successful heat treating. Temperature instrumentation and control systems used in heat treating include temperature sensors, controllers, final control elements, measurement instruments, and set-point programmers. This article describes these items and discusses the classifications and control of furnace atmospheres. The article also describes the surface carbon control devices available for the wide variety of furnace atmospheres and evaluation of carbon control. Finally, the article provides a set of guidelines for safety procedures that are common to all industrial heat treating furnace installations.