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Mohan Sai Kiran Kumar Yadav Nartu, Shashank Sharma, Srinivas Aditya Mantri, Sameehan S. Joshi, Mangesh V. Pantawane ...
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laser-synthesized coatings
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Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006421
EISBN: 978-1-62708-192-4
... tribological performance of structural materials in lubricated and nonlubricated environments. It discusses the fundamentals of various laser materials interactions and reviews laser-based surface-modification strategies, including laser surface heating and melting, laser-synthesized coatings, and laser-based...
Abstract
Lasers evolved as a versatile materials processing tool due to their advantages such as rapid, reproducible processing, chemical cleanliness, ability to handle variety of materials, and suitability for automation. This article focuses on state-of-the-art laser applications to improve tribological performance of structural materials in lubricated and nonlubricated environments. It discusses the fundamentals of various laser materials interactions and reviews laser-based surface-modification strategies, including laser surface heating and melting, laser-synthesized coatings, and laser-based design approaches such as laser patterning and dimpling. Laser-surface modification of novel materials, such as high-entropy alloys and metallic glasses, is explored. The article provides an overview of hybrid techniques involving laser as a secondary tool, as well as a discussion on the improved capabilities of laser surface engineering for tribological applications by means of integrated computational process modeling.
Book Chapter
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006885
EISBN: 978-1-62708-392-8
... coatings on AZ31B (Mg-3Al-1Zn-0.2Mn) alloy Use of a continuous-wave Nd:YAG laser with variable laser track overlap to synthesize patterned hydroxyapatite coatings of tens of micrometers thickness Comparison of coatings with complete surface coverage and coatings with alternate bands...
Abstract
This article focuses on the directed-energy deposition (DED) additive manufacturing (AM) technique of biomedical alloys. First, it provides an overview of the DED process. This is followed by a section describing the design and development of the multiphysics computational modeling of the layer-by-layer fusion-based DED process. A brief overview of the primary governing equations, boundary conditions, and numerical methods prescribed for modeling laser-based metal AM is then presented. Next, the article discusses fundamental concepts related to laser surface melting and laser-assisted bioceramic coatings/composites on implant surfaces, with particular examples related to biomedical magnesium and titanium alloys. It then provides a review of the processes involved in DED of biomedical stainless steels, Co-Cr-Mo alloys, and biomedical titanium alloys. Further, the article covers novel applications of DED for titanium-base biomedical implants. It concludes with a section on the forecast of DED in biomedical applications.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001106
EISBN: 978-1-62708-162-7
... on the tools, can include laser cutting, electrodischarge machine cutting, grinding, lapping, and polishing steps. Polycrystalline Diamond With a Metallic Second Phase Polycrystalline diamond with a metallic second phase has a microstructure of diamond grains with the metallic phase mostly at the grain...
Abstract
Synthetic diamond and cubic boron nitride are among a class of superhard materials from the boron-carbon-nitrogen-silicon family of elements. This article focuses on the two materials, the forms in which they are produced, and their respective properties. Synthetic diamond and cubic boron nitride compounds are available in the form of grit and sintered polycrystalline blanks of various size, shape, and composition. The article explains how superabrasive grains made from these materials can be used in lapping, polishing, and grinding applications, and how diamond and boron nitride blanks can be mounted to suitable substrates to form ultrahard cutting edges and tools.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005808
EISBN: 978-1-62708-165-8
... ). Therefore, in practice, it is essential to apply a black coating on the substrate surface to enhance effective absorptivity. Without such a coating, only a small fraction of the laser beam energy will be conducted into the bulk substrate material, thus failing to acquire the desired surface temperature...
Abstract
Laser surface hardening is a noncontact process that provides a chemically inert and clean environment as well as flexible integration with operating systems. This article provides a brief discussion on the various conventional surface-modification techniques to enhance the surface and mechanical properties of ferrous and nonferrous alloys. The techniques are physical vapor deposition, chemical vapor deposition, sputtering, ion plating, electroplating, electroless plating, and displacement plating. The article describes five categories of laser surface modification, namely, laser surface heat treatment, laser surface melting such as skin melting or glazing, laser direct metal deposition such as cladding, alloying, and hardfacing, laser physical vapor deposition, and laser shock peening. The article provides detailed information on absorptivity, laser scanning technology, and thermokinetic phase transformations. It also describes the influence of cooling rate on laser heat treatment and the effect of processing parameters on temperature, microstructure, and case depth hardness.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005682
EISBN: 978-1-62708-198-6
... routes are based on electrophoresis, sol-gel, and electrochemical processing ( Ref 47 ). Recently, laser-induced calcium-phosphate-base surface coatings have been successfully deposited to obtain desired biological properties in terms of cell adhesion, differentiation, and proliferation ( Ref 48...
Abstract
This article outlines the selection criteria for choosing an implant material for biomedical devices in orthopedic, dental, soft-tissue, and cardiovascular applications. It details the development of various implants, such as metallic, ceramic, and polymeric implants. The article discusses specific problems associated with implant manufacturing processes and the consequent compromises in the properties of functionally graded implants. It describes the manufacturing of the functionally-graded hip implant by using the LENS process. The article reviews four different types of tissue responses to the biomaterial. It discusses the testing methods of implant failure, such as in vitro and in vivo assessment of tissue compatibility.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006641
EISBN: 978-1-62708-213-6
... insertion ( Ref 3 , 4 ), electrothermal vaporization ( Ref 5 ), high-voltage spark ( Ref 6 ), laser ablation ( Ref 7 ), and many other approaches. Laser ablation is by far the most versatile, widely used direct solid-introduction technique. Laser ablation involves the conversion of a solid material...
Abstract
This article discusses the basic principles of inductively coupled plasma mass spectrometry (ICP-MS), covering different instruments used for performing ICP-MS analysis. The instruments covered include the sample-introduction system, ICP ion source, mass analyzer, and ion detector. Emphasis is placed on ICP-MS applications in the semiconductor, photovoltaic, materials science, and other electronics and high-technology areas.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006434
EISBN: 978-1-62708-192-4
... of the CF x transfer film on the counterface. Decades later, composite thin films were grown by pulsed laser deposition using WS 2 and CF x targets ( Ref 22 ). The resulting films were found to have carbon and fluorine bonding different from CF x , but with W and S present as WS 2 . The films...
Abstract
Solid lubricants consist of materials placed at the interface between moving bodies to mitigate friction and wear. This article begins with a historical overview of solid lubricants and discuses the characteristics and fundamental aspects of solid lubricants. It describes the material categories of solid lubricant coatings, including graphite, graphite fluoride, transition metal dichalcogenides, diamond-like-carbon, polymeric materials, and metallic films. The article presents a description of deposition methods from the simplest processes involving burnishing and impingement in open air to modern vacuum-based methods for solid lubricants. It concludes with a discussion on metrics that can be used to qualify solid lubricants in high-consequence applications.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004156
EISBN: 978-1-62708-184-9
... in the field or shop, alternative processes lack such flexibility. In particular, coatings applied by laser cladding and diffusion processes must be done in the shop on replacement panels. Following the coating applications, these panels are then installed on the furnace walls in areas where severe corrosion...
Abstract
The presence of certain impurities in coal and oil is responsible for the majority of fireside corrosion experienced in utility boilers. In coal, the primary impurities are sulfur, alkali metals, and chlorine. The most detrimental impurities in fuel oil are vanadium, sodium, sulfur, and chlorine. This article describes the two categories of fireside corrosion based on location in the furnace: waterwall corrosion in the lower furnace and fuel ash corrosion of superheaters and reheaters in the upper furnace. It discusses prevention methods, including changes to operating parameters and application of protective cladding or coatings.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006891
EISBN: 978-1-62708-392-8
... is referred to as a crawling state of a myriopod; it was fabricated with piezoelectric jetting and multiple-wavelength curing lasers. Urethane and epoxy, which are both photocurable materials, were used to fabricate the main part of the robot. The materials were printed onto the substrate using piezoelectric...
Abstract
Piezoelectric jetting is a common form of additive manufacturing technology. With the development of material science and manufacturing devices, piezoelectric jetting of biomaterials has been applied to various fields including biosensors, tissue engineering, deoxyribonucleic acid (DNA) synthesis, and biorobots. This article discusses the processes involved in piezoelectric jetting of biosensors and biorobots and the applications of piezoelectric jetting for tissue engineering and producing DNA. In addition, it reviews the challenges and perspectives of piezoelectric jetting.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006853
EISBN: 978-1-62708-392-8
.... Laser Treatment In contrast with sandblasting and acid etching techniques, laser treatment exerts zero risk of surface contamination, because there is no direct contact between the laser and the biomaterial ( Ref 51 ). Laser surface treatments also tend to improve material wettability by altering...
Abstract
One of the most frequently cited advantages of ceramics in dentistry relates to aesthetics, and the same applies for dental implants. Zirconia has emerged as the material of choice for nonmetal implants. This article introduces the reader to zirconia as an implant material, its properties, manufacturing processes, and the particular surface modifications and treatments that have rendered its surfaces biologically compatible with peri-implant soft and hard tissues.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006886
EISBN: 978-1-62708-392-8
... Abstract Hydroxyapatite (HA) is one of the most popular materials in tissue scaffold engineering due to its similarity to the nature of human bone; it accounts for more than half of the total weight of the latter. Selective laser sintering (SLS) is an additive manufacturing method that is used...
Abstract
Hydroxyapatite (HA) is one of the most popular materials in tissue scaffold engineering due to its similarity to the nature of human bone; it accounts for more than half of the total weight of the latter. Selective laser sintering (SLS) is an additive manufacturing method that is used in producing tissue engineering parts from HA feedstocks. This article provides a brief overview of the process itself, along with a detailed review of HA-based tissue engineering applications using SLS. Discussion on the various polymer composites is presented. A detailed overview of selected publications on HA-based SLS studies is listed, which provides insight regarding technical aspects of processing HA powder feedstocks.
Book Chapter
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003685
EISBN: 978-1-62708-182-5
.... , Ion Implantation , p 605 – 610 • Horwitz J.S. , Pulsed-Laser Deposition , p 621 – 626 • Mattox D.M. , Growth and Growth-Related Properties of Films Formed by Physical Vapor Deposition , p 538 – 555 • Mattox D.M. , Ion Plating , p 582 – 592...
Abstract
Vapor-deposition processes fall into two major categories, namely, physical vapor deposition (PVD) and chemical vapor deposition (CVD). This article describes major deposition processes such as sputtering, evaporation, ion plating, and CVD. The list of materials that can be vapor deposited is extensive and covers almost any coating requirement. The article provides a table of some corrosion-resistant vapor deposited materials. It concludes with an overview of the applications of CVD and PVD coatings and a discussion on coatings for graphite, the aluminum coating of steel, and alloy coatings for aircraft turbines, marine turbines, and industrial turbines.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006863
EISBN: 978-1-62708-392-8
... The sheet lamination process is mostly used to produce colored objects in high resolution. Thin, layered materials such as aluminum foil or paper-based filaments are cut into appropriately shaped layers by using lasers or sharp blades. The layers are coated with adhesive and successively glued together...
Abstract
Of the seven additive manufacturing (AM) processes, this article focuses on the vat photopolymerization, or simply vat polymerization, process, while briefly discussing the other six AM processes. Vat polymerization and its characteristics, AM applications in medical fields, and the regulatory challenges of vat polymerization-based bioprinting are presented.
Series: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006887
EISBN: 978-1-62708-392-8
... techniques such as selective laser sintering, binder jet printing, and direct ink writing ( Ref 5 - 7 ). Biological materials with organic or inorganic constituents have been selected and used. Geometric distributions should be modulated according to individual osseous tissues ( Ref 8 ). Bioscaffold...
Abstract
Stereolithographic (STL) additive manufacturing (AM) can be used to fabricate practical components. This article discusses the processes involved in STL-AM of biological scaffolds, providing information on bioscaffold processing, cavity arrangements, and microlattice distributions. Within the last topic, the sub-topic of scaffold modulation is discussed.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006377
EISBN: 978-1-62708-192-4
... of testing environment (dry nitrogen switched to humid air) is shown in Fig. 2(a) for dry sliding on a pulsed-laser-deposited WS 2 coating at a contact load of 1 N (0.22 lbf) ( Ref 17 , 18 ). Figure 2(a) also shows that the transfer films formed in dry nitrogen were smooth, tenacious, and firmly...
Abstract
Transition metal dichalcogenides (TMD) are solid lubricant materials, specifically, intrinsic solid lubricants, whose crystal structure facilitates interfacial sliding/shear to achieve low friction and wear in sliding contacts and low torque in rolling contacts. This article provides information on sliding friction and wear behavior of unbonded, bonded, and vapor-deposited pure and composite MoS 2 and WS 2 coatings. It discusses the rolling-torque behavior and applications of vapor-deposited pure and composite MoS 2 and WS 2 coatings. The article concludes with information on various forms of TMD lubrication, namely, oils, greases, microparticle and nanoparticle additives.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006838
EISBN: 978-1-62708-329-4
... at specific locations on a build platform or part. The materials in the AM jetting processes involved controlled deposition of curable polymers or atomized melt (material jetting) or powder deposition with binder resins (binder jetting). Other AM technologies emerged with the development of selective laser...
Abstract
This article provides an overview of metal additive manufacturing (AM) processes and describes sources of failures in metal AM parts. It focuses on metal AM product failures and potential solutions related to design considerations, metallurgical characteristics, production considerations, and quality assurance. The emphasis is on the design and metallurgical aspects for the two main types of metal AM processes: powder-bed fusion (PBF) and directed-energy deposition (DED). The article also describes the processes involved in binder jet sintering, provides information on the design and fabrication sources of failure, addresses the key factors in production and quality control, and explains failure analysis of AM parts.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003732
EISBN: 978-1-62708-177-1
... in Metals and Alloys , 2nd ed. , Chapman and Hall , 1997 5. Zeng D.W. , Xie C.S. , and Yung K.C. , Mesostructured Composite Coatings on SAE 1045 Carbon Steel Synthesized in situ by Laser Surface Alloying , Mater. Lett. , Vol 6 , 2002 , p 680 – 684 10.1016/S0167-577X(02)00578...
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003054
EISBN: 978-1-62708-200-6
... disilicide is 3.5 × 10 −7 Ω · m at room temperature and increases nearly linearly to 4 × 10 −6 Ω · m at 1700 °C (3090 °F). Molybdenum disilicide elements form a surface coating of silicon dioxide (SiO 2 ) in air that prevents the oxidation of molybdenum disilicide. The breakdown of this coating limits...
Abstract
Sintering provides the interparticle bonding that generates the attractive forces needed to hold together the otherwise loose ceramic powder mass. It also improves hardness, strength, transparency, toughness, electrical conductivity, thermal expansion, magnetic saturation, corrosion resistance, and other properties. This article discusses the fundamentals of sintering and its effects on pore structures and particle density. It addresses some of the more common sintering methods, including solid-state, liquid-phase, and gas pressure sintering, and presents alternative processes such as reaction sintering and self-propagating, high-temperature synthesis. It also describes several pressure densification methods, including hot isostatic pressing, gas pressure sintering, molten particle deposition, and sol-gel processing. The article concludes with a section on grain growth that discusses the underlying mechanisms and kinetics and the relationship between grain growth and densification.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003063
EISBN: 978-1-62708-200-6
... as the basal plane is oriented such that basal slip does not occur. Fig. 6 The edge-defined, film-fed growth process of making a single-crystal Al 2 O 3 fiber. Source: Ref 6 Other Oxide Compositions The laser-heated floating zone method has been used to make a variety of oxide fibers ( Fig...
Abstract
Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006360
EISBN: 978-1-62708-192-4
... are shown in Fig. 1 . There are many other possible laboratory methods used for DLC deposition as well, such as laser ablation, hybrid plasma source/sputtering, ion beam-assisted deposition, and high-power impulse magnetron sputtering (HIPIMS), that are under development or are emerging in industry...
Abstract
This article describes two variations of carbon-base coatings: diamondlike carbon (DLC) coatings and polycrystalline diamond (PCD) coatings. It discusses the basics of a few deposition methods as they apply to industrially relevant coatings. The methods include deposition of tungsten-containing hydrogenated amorphous carbon films, deposition of tetrahedral amorphous carbon films, and deposition of silicon-incorporated hydrogenated amorphous carbon films. The most common deposition technologies for diamond films are also discussed. The article provides information on surface preparation for DLC and diamond deposition. It also provides a discussion on the coating composition and structure, mechanical and tribological properties, and applications of DLC and diamond coatings. The quality control techniques for DLC and diamond coatings are specified to meet customer requirements and ensure repeatable quality.
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