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in Metallography and Microstructures of Low-Carbon and Coated Steels
> Metallography and Microstructures
Published: 01 December 2004
Fig. 51 (a) Microstructure of a brass coating with a clear lacquer film on a low-carbon sheet with a 45° mount. (b) Microstructure of a nickel coating on low-carbon sheet without the 45° angle. 2% nital etch. 1000×
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Image
Published: 01 January 2003
Fig. 2 Filiform corrosion on a clear-lacquered steel hammerhead exposed to humid conditions. Fine filaments have extended over the entire surface of the hammerhead, with filiforms originating at corners, grind marks, or other sites where the coating varies in thickness.
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Image
Published: 01 January 2003
Fig. 3 A lacquered steel can lid exhibiting filiform corrosion showing both large and small filaments partially oriented in the rolling direction of the steel sheet. Without this 10× magnification by a light microscope, the filiforms look like fine striations or minute tentacles.
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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
... be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Image
Published: 01 January 2005
Fig. 47 Occasional premature discoloration was noted on polished and coated steel indoor furniture, which worsened over several weeks with threadlike features (filiform corrosion). The polished carbon steel sections were absent of visual blemishes prior to coating with a clear lacquer
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Image
Published: 01 January 2003
Fig. 11 Scratches in a nitrocellulose coating on aluminum induced by light abrasion. Hills and valleys in the foil are induced by a diamond-imprint gravure roll that applies the nitrocellulose as a lacquer. Scanning electron microscopy. 200×
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Image
Published: 01 January 2005
Fig. 48 The filiform corrosion problems of Fig. 47 are exacerbated by handling the unlacquered parts without gloves. Fingerprints are obvious in this photograph. Corrosion form and mechanism Localized corrosion, filiform corrosion Material Carbon steel, lacquer coated Product
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Image
Published: 01 January 2003
Fig. 1 Filiform corrosion on cast aluminum alloy automotive wheels that were lacquered with a clear coat to prevent dulling of the aluminum. Arrows indicate sites of significant activity. Note that each filiform originates at sharp corners where the clear coat is very thin, cracked, or severed.
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Image
Published: 15 June 2019
Fig. 23 Filiform corrosion on cast aluminum alloy automotive wheels that were lacquered with a clear coat to prevent dulling of the aluminum. Arrows indicate sites of significant activity. Note that each filiform originates at sharp corners where the clear coat is very thin, cracked
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Image
Published: 01 January 1994
Fig. 2 Five-year Gulf Coast corrosion performance of coated AZ91D die cast magnesium (left) versus cold-rolled carbon steel (right). Both panels were cleaned, iron phosphatized, coated with 18 μm (0.7 mil) of baked cathodic epoxy primer and 12 to 20 μm (0.5 to 0.8 mil) of acrylic lacquer
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Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006504
EISBN: 978-1-62708-207-5
... by an anodic coating or clear lacquer. Anodizing is the more popular protective treatment, because it does not alter the original texture of a surface. Clear lacquers smooth out roughened surfaces and produce various degrees of gloss, which may be undesirable. Anodizing of a blasted aluminum surface results...
Abstract
The necessary precursor to a proper and durable finish is the preparation of the active aluminum surface to receive the desired protective finish that will allow it to have a long and attractive service life. This article helps those who work with aluminum in the many varieties of applications of such products. It describes the two main categories of cleaning that can be used with most any metal, namely, mechanical cleaning and chemical cleaning. The article provides a discussion on the laboratory evaluation of cleaners, field testing of cleaners, and cleaner types and procedures. It also describes the special cleaning procedures for aluminum alloys, such as steam cleaning and rotary wire-brush cleaning. The article reviews the use of temporary coatings and the use of maintenance coatings on aluminum. It provides information on the handling and storage procedures of aluminum alloys and the cleaning of specific applications of aluminum.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003614
EISBN: 978-1-62708-182-5
... aluminum magnesium FILIFORM CORROSION occurs on metallic surfaces coated with organic films that are typically 0.05 to 0.1 mm (2 to 4 mil) thick. Common objects such as a coated aluminum automobile wheel ( Fig. 1 ) and a lacquered hammerhead ( Fig. 2 ) are susceptible. The pattern of attack...
Abstract
Filiform corrosion has been observed to occur under a wide range of organic coatings and proceeds with the same general characteristics on steel, aluminum, and magnesium. This article describes the standard tests for filiform corrosion, characteristics and mechanisms of filiform corrosion in steels, as well as coated aluminum and magnesium. It concludes with information on the prevention and mitigation of filiform corrosion accomplished through the adjustment of the environment and changes in the substrate and coating systems.
Image
Published: 01 January 2005
to passivate and produce a corrosion-resistant oxide barrier film. The tines of the forks were ground and polished and generally reflective; a lacquer coating was disturbed by filaments of filiform attack. The plastic enclosure, which was moist and contained chlorides, experienced condensation and evaporation
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Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001309
EISBN: 978-1-62708-170-2
... parts (d) Satin Greaseless compound Loose cloth wheel 305 diam by 50–510 wide 12 diam by 2–20 wide 1800 (a) Clean brush often by running pumice stone across face of wheel. (b) Lacquer after scratch brushing. (c) Lacquer after finishing. (d) Chromium plate after finishing...
Abstract
The selection of surface treatments for copper and copper alloys is generally based on application requirements for appearance and corrosion resistance. This article describes cleaning, finishing, and coating processes for copper and copper alloys. These processes include pickling and bright dipping, abrasive blast cleaning, chemical and electrochemical cleaning, mass finishing, polishing and buffing, electroless plating, immersion plating, electroplating, passivation, coloring, and organic coatings.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006018
EISBN: 978-1-62708-175-7
... steel, tungsten carbide Lacquers Silver, brass, bronze, aluminum Mechanical (peen) plating Zinc, lead, tin, brass, copper, cadmium Slurry coating Nickel Roof coatings Aluminum Spray coating Iron, aluminum, zinc, tin, nickel alloys, copper, bronze, stainless steel, tungsten...
Abstract
Metal powders are used as fuels in solid propellants, fillers in various materials, such as polymers or other binder systems, and for material substitution. They are also used in food enrichment, environmental remediation market, and magnetic, electrical, and medical application areas. This article reviews some of the diverse and emerging applications of ferrous and nonferrous powders. It also discusses the functions of copier powders and the processes used frequently for copier powder coating.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003818
EISBN: 978-1-62708-183-2
Abstract
This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.
Book Chapter
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006531
EISBN: 978-1-62708-207-5
... and lacquered or painted; applies to products that are strain hardened and subjected to some thermal operation during the subsequent painting or lacquering operation H41 Strain hardened and lacquered or painted to a temper below 1 4 -hard condition H42 Strain hardened and lacquered or painted...
Abstract
This article presents a summary of aluminum temper designations, and applicable aluminum alloys and product forms for temper designations used in the United States (ANSI H35.1), Europe (EN 515), and internationally (ISO 2107).
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006489
EISBN: 978-1-62708-207-5
... on aluminum products. The process may be used for final finishing, but it is more often used as an intermediate step prior to anodizing, conversion coating, lacquering, or other finishing treatments. Chemical etching also is used in conjunction with buffing or chemical brightening. The advantage...
Abstract
Etching aluminum can be a pretreatment step for anodizing, chemical conversion coating, metal-to-rubber bonding, and a host of other processes. Chemical etching, using either alkaline or acid solutions, produces a matte finish on aluminum products. This article describes the alkaline etching and acid etching of aluminum. Alkaline etching reduces or eliminates surface scratches, nicks, extrusion die lines, and other imperfections. Acid etching can be done without heavy smut problems, particularly on aluminum die castings. Hydrochloric, hydrofluoric, nitric, phosphoric, chromic, and sulfuric acids are used in acid etching. The article presents a flow chart of the operations used in acid etching.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001277
EISBN: 978-1-62708-170-2
...-linking agents that require heat for polymerization. Lacquers Lacquers are compositions based on natural or synthetic thermoplastic film-forming materials dissolved in organic solvent. These dry primarily by solvent evaporation. Lacquers are generally characterized by fast drying properties...
Abstract
Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.
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