This article introduces basic physical metallurgy concepts that may be useful for understanding and interpreting variations in metallographic features and how processing affects microstructure. It presents some basic concepts in structure-property relationships. The article describes the use of equilibrium binary phase diagrams as a tool in the interpretation of microstructures. It reviews an account of the two types of solid-state phase transformations: isothermal and athermal. The article discusses isothermal transformation and continuous cooling transformation diagrams which are useful in determining the conditions for proper heat treatment (solid-state transformation) of metals and alloys. The influence of the mechanisms of phase nucleation and growth on the morphology, size, and distribution of grains and second phases is also described.

This article introduces the mechanism of diffusion and the common types of heat treatments such as annealing and precipitation hardening, which are applicable to most ferrous and nonferrous systems. Three distinct processes occur during annealing: recovery, recrystallization, and grain growth. The article also describes the various types of solid-state transformations such as isothermal transformation and athermal transformation, resulting from the heat treatment of nonferrous alloys. It provides information on the homogenization of chemical composition within a cast structure.

This article presents an outline of the physical metallurgical principles that are associated with heat treating of steels. It describes the iron-carbon phase diagram and various types of transformation diagrams, including isothermal transformation diagrams, continuous heating transformation diagrams, and continuous cooling transformation diagrams. The primary design criteria for heat treating of steels this article covers are the minimization of distortion and undesirable residual stresses. The article presents the theoretical and empirical guidelines to understand sources of common heat-treating defects and how they can be controlled. It also presents an example to demonstrate how thermal and transformation-induced strains cause dimensional changes and residual stresses.

This article discusses the classification of carbon steels based on carbon content, and tabulates the compositional limits of medium- and high-carbon steels based on the AISI code and other similar codes. It describes recrystallization annealing and spheroidizing of carbon steels, and discusses the classification of carbon steels for heat treatment. The article also discusses the estimation of continuous cooling curves from isothermal transformation curves. It provides information on the Jominy end-quench test and the Grossmann method and the procedures to increase hardenabilty of carbon steels. The article includes information on the purpose of tempering and heat treating guidelines for different grades of steels, including cast carbon steels.

This article provides a detailed discussion on the factors involved in the selection of steels for austempering, including section thickness limitations of steel parts and modifications of austempering practice. The selection of steel for an austempered component is based on the processing characteristics of the heat treating equipment employed. It is also based on the hardenability and transformation characteristics of the steel alloy as indicated by time-temperature-transformation and isothermal-transformation diagrams. The article contains tables that compare the dimensional changes that occur in stabilizer bars as a result of oil quenching and tempering with those that resulted from austempering. It also discusses the production applications of austempering and the problems encountered in austempering together with their solutions.

Similar to the eutectic group of invariant transformations is a group of peritectic reactions, in which a liquid and solid phase decomposes into a solid phase on cooling through the peritectic isotherm. This article describes the equilibrium freezing and nonequilibrium freezing of peritectic alloys. It informs that peritectic reactions or transformations are very common in the solidification of metals. The article discusses the formation of peritectic structures that can occur by three mechanisms: peritectic reaction, peritectic transformation, and direct precipitation of beta from the melt. It provides a discussion on the peritectic structures in iron-base alloys and concludes with information on multicomponent systems.

The heat treatment of steel is based on the physical metallurgical principles that relate to its processing, properties, and structure. The microstructures that result from the heat treatment of steel are composed of one or more phases in which the atoms of iron, carbon, and other elements in steel are associated. This article describes the phases of heat treated steel, and provides information on effect of temperature change and the size of carbon atoms relative to that of iron atoms during the heat treatment.

This article provides a discussion on the transformations of various categories of bainite in ferrous systems. These include upper bainite, lower bainite, inverse bainite, granular bainite, and columnar bainite. The article also provides information on the bainite transformations in nonferrous systems.

The transformation of austenite of cast irons represents a more complex and less studied subject. This article discusses the general features of the decomposition of austenite into bainite. It describes the heat treatment cycles of austempered cast iron microstructure. The article reviews several factors, such as presence of graphite and austenite grain size, which affect the transformation rate of austenite during austempering of free-graphite cast irons.

Cast irons, like steels, are iron-carbon alloys but with higher carbon levels than steels to take advantage of eutectic solidification in the binary iron-carbon system. This article introduces the solid-state heat treatment of iron castings and describes the various processes of heat treatment of cast iron. It provides information on stress relieving, annealing, normalizing, through hardening, and surface hardening of these castings. The article discusses general considerations for the heat treatment of cast iron. Cast irons are occasionally nitrided for various applications with the aim of enhancing surface hardness and corrosion resistance of the products. The article describes molten salt bath cyaniding and ion nitriding of cast iron.

This article discusses factors involved in selecting welding processes and consumables and establishing procedures and practices for the arc welding of low-alloy steels. It provides information on welding consumables in terms of filler metals and fluxes and shielding gases. The article describes the various categories of low-alloy steels, such as high-strength low-alloy (HSLA) structural steels, high-strength low-alloy quenched and tempered(HSLA Q&T) structural steels, low-alloy steels for pressure vessels and piping, medium-carbon heat-treatable (quenched and tempered) low-alloy (HTLA) steels, ultrahigh-strength low-alloy steels, and low-alloy tool and die steels. It concludes with a discussion on repair practices for tools and dies.

Tool steels are prepared for metallographic examination in the same way as carbon steels with a few variations owing to hardness and alloying differences. This article explains what makes tool steels different and how to compensate for it when sectioning, mounting, grinding, polishing, and etching. It provides information and data on composition, hot working, austenitizing, tempering, and powder metal manufacturing and explains how it affects tool steel microstructure, using more than 100 detailed images.

Ductile cast irons are heat treated primarily to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article discusses the most important heat treatments of ductile irons and their purposes. International standards of ductile iron provided by ASTM International, the International Organization for Standardization (ISO), and SAE International are presented in a table. The article explains basic structural differences between the ferritic, pearlitic, martensitic, and ausferritic classes. It presents recommended practices for annealing ductile iron castings for different alloy contents and for castings with and without eutectic carbides. The article discusses the induction surface hardening and remelt hardening of ductile iron. It concludes with information on the effect of heat treatment on fatigue strength of ductile iron.

This article focuses on the modeling of microstructure evolution during thermomechanical processing in the two-phase field for alpha/beta and beta titanium alloys. It also discusses the mechanisms of spheroidization, the coarsening, particle growth, and phase decomposition in titanium alloys, with their corresponding equations.

Metallographic techniques for ductile irons are similar to those for other cast irons but more difficult than for steels, because graphite retention is a challenging task. This article presents recommended procedures to prepare ductile irons. It discusses three contemporary approaches for preparing ductile cast iron specimens with a wide range of phases and constituents as well as variations in graphite morphologies. A wide variety of matrix microstructures can be obtained in ductile irons. Examples are presented using a variety of etchants. Control of the nodularity of graphite in ductile irons is critical to their performance. The article presents details concerning the characterization of the graphite nodules.

Successful hardening depends on the hardenability of steel composition, the geometry of parts, the quenching system, and on the heat treating process used. This article provides a brief overview of the computation and use of quench factor analysis (QFA) to quantify as-quenched hardness for carbon and low-alloy steels. As a single-value parameter alternative to Grossmann H-values, QFA is a potential method to qualify a quenching medium or process or to effectively monitor variation of quench severity due to either the quenchant or the system. The article describes the procedures for experimentally determining the quench factors by using a type 304 austenitic stainless steel probe. Typical examples of the utilization of QFA for quenchant characterization are provided. The article also describes the methods for experimentally generating time-temperature-property curves.

Dual-phase steels are a new class of high-strength low alloy (HSLA) steels characterized by a microstructure consisting of about 20% hard martensite particles dispersed in a soft ductile ferrite matrix. In addition to high tensile strength, in the range of 550 MPa (80 ksi), dual-phase steels exhibit continuous yielding behavior, a low 0.2% offset yield strength, and a higher total elongation than other HSLA steels of similar strength. The article discusses some of the more pertinent aspects of dual-phase steels, such as heat treatment, microstructure, mechanical properties, chemical composition, and manufacturability. In general, these steels have a carbon content of less than 0.1%, which ensures that they can be spot welded. However, newer high-carbon dual-phase steels in development are generating interest due to their unique combination of total elongation and tensile strength.

This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.

Steels may be annealed to facilitate cold working or machining, to improve mechanical or electrical properties, or to promote dimensional stability. This article, using iron-carbon phase diagram, describes the types of annealing processes, namely, subcritical annealing, intercritical annealing, supercritical or full annealing, and process annealing. Spheroidizing is performed for improving the cold formability of steels. The article provides guidelines for annealing and tabulates the critical temperature values for selected carbon and low-alloy steels and recommended temperatures and time cycles for annealing of alloy steels and carbon steel forgings. Different combinations of annealed microstructure and hardness are significant in terms of machinability. Furnaces for annealing are of two basic types, batch furnaces and continuous furnaces. The article concludes with a description of the annealing processes for steel sheets and strips, forgings, bars, rods, wires, and plates.

Computer simulation of microstructural evolution during hot rolling of steels is a major topic of research and development in academia and industry. This article describes the methodology and procedures commonly employed to develop microstructural evolution models to simulate microstructural evolution in steels. It presents an example of the integration of finite element modeling and microstructural evolution models for the simulation of metal flow and microstructural evolution in a hot rolling process.