This article provides information on the salt baths used for a variety of heat treatments, including heating, quenching, interrupted quenching (austempering and martempering), case hardening, and tempering. It describes two general types of salt bath systems for steel hardening: the first type uses atmosphere austenitizing followed by salt quench and the second type employs austenitizing salt baths with rapid transfer to the quench salt. The article provides a detailed account on the construction, advantages and disadvantages, and limitations of isothermal quenching furnaces, submerged-electrode furnaces, immersed-electrode furnaces, and externally heated furnaces. It discusses the important applications of various furnace designs, including the austempering of ductile iron, the hardening of tool steels, and the isothermal annealing of high-alloy steels.

Air hardening steel is a type of steel that has deep hardenability and can be hardened in large sections by air cooling. This article discusses the principles of heat treatment of air-hardening steel, and describes the recommended heat treating practices for air-hardening high-strength structural steels, namely, H11 Mod, H13 steel, 300M steel, D-6A and D-6AC, and AF1410 steel. It also provides information on recommended heat treating practices for air-hardening martensitic stainless steels.

Molten salt, including nitrite/nitrate salts, is the quenching medium most commonly used in austempering and marquenching of ferrous materials. This article describes the use of molten salts in the quenching of ferrous materials. It provides information on the processing and operation of salt quenching including considerations of time, temperature, environment, and safety, as well as critical characteristics such as the composition of the quenchant, agitation, and water additions.

Cast irons, like steels, are iron-carbon alloys but with higher carbon levels than steels to take advantage of eutectic solidification in the binary iron-carbon system. This article introduces the solid-state heat treatment of iron castings and describes the various processes of heat treatment of cast iron. It provides information on stress relieving, annealing, normalizing, through hardening, and surface hardening of these castings. The article discusses general considerations for the heat treatment of cast iron. Cast irons are occasionally nitrided for various applications with the aim of enhancing surface hardness and corrosion resistance of the products. The article describes molten salt bath cyaniding and ion nitriding of cast iron.

This article provides general information on the definition, purposes, and quench equipment for direct-forge quenching (DFQ) and direct heat treatment (DHT) processes that are widely used in automotive and various other mechanical industries. It discusses the technological advances in these processes and their ability to produce high-quality components at low production cost from microalloyed steels. Further, the article describes the influence of carbon contents on toughness of microalloyed direct heat treated steels. It focuses on the DFQ and DHT steel technologies applied in continuous rolling mills to produce various DHT steels for machining and cold forming applications.

This article provides a detailed discussion on the heating equipment used for austenitizing, quenching, and tempering tool steels. These include salt bath furnaces, controlled atmosphere furnaces, fluidized-bed furnaces, and vacuum furnaces. The article discusses the types of nitriding and nitrocarburizing processes and the equipment required for heat treating tool steels to improve hardness, wear resistance, and thermal fatigue. The various nitriding and nitrocarburizing processes covered are salt bath nitrocarburizing, gas nitriding and nitrocarburizing, and plasma nitriding and nitrocarburizing.

This article summarizes some of the effects of the major alloying elements in low-alloy steels and the heat treating for some common types of low-alloy steels. Coverage includes common alloys of the following low-alloy steel types: low-alloy manganese steels, low-alloy molybdenum steels, low-alloy chromium-molybdenum steels, low-alloy nickel-chromium-molybdenum steels, low-alloy nickel-molybdenum steels, low-alloy chromium steels, low-alloy chromium-vanadium steels, and low-alloy silicon-manganese steels. The article reviews heat treating parameters and processing considerations for each category of steel, including spherodizing, normalizing, annealing, hardening, and tempering.

This article discusses the classification of carbon steels based on carbon content, and tabulates the compositional limits of medium- and high-carbon steels based on the AISI code and other similar codes. It describes recrystallization annealing and spheroidizing of carbon steels, and discusses the classification of carbon steels for heat treatment. The article also discusses the estimation of continuous cooling curves from isothermal transformation curves. It provides information on the Jominy end-quench test and the Grossmann method and the procedures to increase hardenabilty of carbon steels. The article includes information on the purpose of tempering and heat treating guidelines for different grades of steels, including cast carbon steels.

This article discusses the important characteristics of fluidized beds. The total space occupied by a fluidized bed can be divided into three zones: grid zone, main zone, and above-bed zone. The article discusses the various types of atmospheres of fluidized beds, such as oxidizing and decarburizing atmosphere; nitrocarburizing and nitriding atmosphere; carburizing and carbonitriding atmosphere; and chemical vapor deposition atmosphere. External resistance heating, external combustion heating, internal resistance heating, direct resistance heating, submerged combustion heating, and internal combustion heating can be used to achieve the heat input for a fluidized bed. The article also describes the operations, design considerations, and applications of fluidized-bed furnaces in heat treating. Thermochemical surface treatments, such as carburizing, carbonitriding, nitriding, and nitrocarburizing, are also discussed. Finally, the article reviews the principles and applications of fluidized-bed heat treatment.

This article provides a detailed discussion on various recommended heat treating practices, including normalizing, annealing, austenitizing, quenching, tempering, stress relieving, preheating, and martempering, for various low- and un-alloyed cold-work hardening tool steels. The steels discussed include water-hardening tool steels, shock-resisting tool steels, oil hardening cold-work tool steels, low-alloy special-purpose tool steels, and carbon-tungsten special-purpose tool steels.

Quenching refers to the rapid cooling of metal from the solution treating temperature, typically between 465 and 565 deg C (870 and 1050 deg F) for aluminum alloys. This article provides an overview on the appropriate quenching process and factors used to determine suitable cooling rate. It describes the quench sensitivity and severity of alloys, quench mechanisms and the different types of quenchants used in immersion, spray, and fog quenching. The article provides a detailed description of the quench-factor analysis that mainly includes residual stress and distortion, which can be controlled by proper racking. It concludes with information on agitation and the quench tank system used in the quenching of aluminum alloys.

This article introduces some of the general sources of heat treating problems with particular emphasis on problems caused by the actual heat treating process and the significant thermal and transformation stresses within a heat treated part. It addresses the design and material factors that cause a part to fail during heat treatment. The article discusses the problems associated with heating and furnaces, quenching media, quenching stresses, hardenability, tempering, carburizing, carbonitriding, and nitriding as well as potential stainless steel problems and problems associated with nonferrous heat treatments. The processes involved in cold working of certain ferrous and nonferrous alloys are also covered.

Ductile cast irons are heat treated primarily to create matrix microstructures and associated mechanical properties not readily obtained in the as-cast condition. This article discusses the most important heat treatments of ductile irons and their purposes. International standards of ductile iron provided by ASTM International, the International Organization for Standardization (ISO), and SAE International are presented in a table. The article explains basic structural differences between the ferritic, pearlitic, martensitic, and ausferritic classes. It presents recommended practices for annealing ductile iron castings for different alloy contents and for castings with and without eutectic carbides. The article discusses the induction surface hardening and remelt hardening of ductile iron. It concludes with information on the effect of heat treatment on fatigue strength of ductile iron.

Steels may be annealed to facilitate cold working or machining, to improve mechanical or electrical properties, or to promote dimensional stability. This article, using iron-carbon phase diagram, describes the types of annealing processes, namely, subcritical annealing, intercritical annealing, supercritical or full annealing, and process annealing. Spheroidizing is performed for improving the cold formability of steels. The article provides guidelines for annealing and tabulates the critical temperature values for selected carbon and low-alloy steels and recommended temperatures and time cycles for annealing of alloy steels and carbon steel forgings. Different combinations of annealed microstructure and hardness are significant in terms of machinability. Furnaces for annealing are of two basic types, batch furnaces and continuous furnaces. The article concludes with a description of the annealing processes for steel sheets and strips, forgings, bars, rods, wires, and plates.

This article describes the heat treating (stress relieving, normalizing, annealing, quenching, tempering, martempering, austempering, and age hardening) of different types of steels, including ultrahigh-strength steels, maraging steels, and powder metallurgy steels. Tabulating the recommended temperatures for normalizing and austenitizing, it provides information on mechanism, cooling media, principal variables, process procedures, and applications of heat treating. In addition, the article gives a short note on the cold and cryogenic treatment of steel.

Forging of nickel-base alloys results in geometries that reduce the amount of machining to obtain final component shapes and involves deformation processing to refine the grain structure of components or mill products. This article discusses the heating practice, die materials, and lubricants used in nickel-base alloys forging. It describes two major forging processing categories for nickel-base alloys: primary working and secondary working categories. Primary working involves the deformation processing and conversion of cast ingot or similar bulk material into a controlled microstructure mill product, such as billets or bars, and secondary working refers to further forging of mill product into final component configurations.

This article focuses on heat treating of the most important H-series and low-alloy hot-work tool steels, namely, normalizing, annealing, stress relieving, preheating, austenitizing, quenching, tempering, and surface hardening. It describes the heat-treating procedure for hot-work tools using examples. The article provides information on the North American Die-Casting Association's requirements for steel grades and heat treatment of dies made of hot-work tool steels. It also describes the chemical compositions and mechanical and metallurgical properties of hot-work tool steels.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. This article describes surface hardening of gray irons by flame and induction heating. It provides information on the classification of the gray irons in ASTM specification. The article presents examples that illustrate the use of stress relieving to eliminate distortion and cracking. It describes the three annealing treatments of gray iron: ferritizing annealing, medium (or full) annealing, and graphitizing annealing. The article discusses the parameters of the tensile strength and hardness of a normalized gray iron casting. These include combined carbon content, pearlite spacing, and graphite morphology. The article concludes with a discussion on the induction hardening of gray iron castings.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. The heat treatment of gray irons can considerably alter the matrix microstructure with little or no effect on the size and shape of the graphite achieved during casting. This article provides a detailed account of classes of gray iron, and heat treating methods of gray irons with examples. These methods include stress relieving, annealing, normalizing, transformation hardening, austenitizing, quenching, austempering, martempering, flame hardening, induction hardening, and nitriding.

This article provides a detailed discussion on the factors involved in the selection of steels for austempering, including section thickness limitations of steel parts and modifications of austempering practice. The selection of steel for an austempered component is based on the processing characteristics of the heat treating equipment employed. It is also based on the hardenability and transformation characteristics of the steel alloy as indicated by time-temperature-transformation and isothermal-transformation diagrams. The article contains tables that compare the dimensional changes that occur in stabilizer bars as a result of oil quenching and tempering with those that resulted from austempering. It also discusses the production applications of austempering and the problems encountered in austempering together with their solutions.