This article addresses two issues on thermodynamics, namely, the calculation of solubility lines and the calculation of the activity of various components. It discusses alloying elements in terms of their influence on the activity of carbon. The article describes the desulfurization and deoxidation of cast iron and steel. It illustrates the thermodynamics of the iron-carbon system and the iron-silicon system. The article examines solubility and saturation degrees of carbon in multicomponent iron-carbon systems. One of the main applications of the thermodynamics of the iron-carbon system is the calculation of structure-composition correlations. The article concludes with information on the structural diagrams, such as Maurer diagram and Laplanche diagram, for cast iron.

Eutectoid and peritectoid transformations are classified as solid-state invariant transformations. This article focuses primarily on the structures from eutectoid transformations with emphasis on the classic iron-carbon system of steel. It reviews peritectoid phase equilibria that are very common in several binary systems. The addition of substitutional alloying elements causes the eutectoid composition and temperature to shift in the iron-carbon system. The article graphically illustrates the effect of various substitutional alloying elements on the eutectoid transformation temperature and effective carbon content. The partitioning effect of substitutional alloying elements, such as chromium, manganese, and silicon, in pearlitic steel is also illustrated.

Cast irons primarily are iron alloys that contain more than 2% carbon and from 1 to 3% silicon. This article provides a description of iron-iron carbide-silicon system; and discusses the classification, composition, and characteristics of cast irons, such as gray, ductile, malleable, compacted graphite, and white cast iron. A table shows the correspondence between commercial and microstructural classification, as well as final processing stage in obtaining common cast irons.

Cast iron exhibits a considerable amount of eutectic in the solid state. This article discusses the structure of liquid iron-carbon alloys to understand the mechanism of the solidification of cast iron. It illustrates nucleation of the austenite-flake graphite eutectic, austenite-spheroidal graphite eutectic, and austenite-iron carbide eutectic. The article provides a discussion on primary austenite and primary graphite. Depending on the carbon equivalent, the primary phase in cast iron can be either austenite for hypoeutectic cast iron or graphite for hypereutectic cast iron. The article also describes the growth of eutectic in cast iron in terms of isothermal solidification, directional solidification, and multidirectional solidification.

Cast iron, which usually refers to an in situ composite of stable eutectic graphite in a steel matrix, includes the major classifications of gray iron, ductile iron, compacted graphite iron, malleable iron, and white iron. This article discusses melting, pouring, desulfurization, inoculation, alloying, and melt treatment of these major ferrous alloys as well as carbon and alloy steels. It explains the principles of solidification by describing the iron-carbon phase diagram, and provides a pictorial presentation of the basic microstructures and processing steps for cast irons.

This article presents information regarding the use of protective coatings in municipal potable water systems, including raw water collection and transmission, water treatment plants, and treated water distribution. It provides useful guidance for the selection and use of protective coatings in these municipal water systems. The most commonplace corrosion-damage mechanisms are highlighted. The article describes the most common materials of construction found in municipal water systems, namely, cast iron, ductile iron, carbon steel, precast concrete cylinder pipe and reinforced concrete pipe, prestressed concrete tanks, and stainless steel. It provides information on the most common generic coating systems used for new steel tanks and water storage tanks. It concludes with a discussion of quality watch-outs when selecting or using protective coatings in municipal water systems.

This article describes the liquidus plots, isothermal plots, and isopleth plots used for a hypothetical ternary phase space diagram. It discusses the single-phase boundary (SPB) line and zero-phase fraction (ZPF) line for carbon-chromium-iron isopleth. The article illustrates the Gibbs triangle for plotting ternary composition and discusses the ternary three-phase phase diagrams by using tie triangles. It describes the peritectic system with three-phase equilibrium and ternary four-phase equilibrium. The article presents representative binary iron phase diagrams, showing ferrite stabilization (iron-chromium) and austenite stabilization (iron-nickel).

This article provides an overview of the different classification and designation systems of wrought carbon steel and alloy steel product forms with total alloying element contents not exceeding 5″. It lists the quality descriptors, chemical compositions, cast or heat composition ranges, and product analysis tolerances of carbon and alloy steels. The major designation systems discussed include the Society of Automotive Engineers (SAE)-American Iron and Steel Institute (AISI) designations, Unified Numbering System (UNS) designations, American Society for Testing and Materials (ASTM) designations, Aerospace Material Specification (AMS), and other international designations and specifications.

The term cast iron designates a group of materials that contain more than one constituent in their microstructure due to excess carbon that result in unique characteristics such as the fracture appearance and graphite morphology. This article discusses the classification of cast iron and the various metallurgical aspects, such as composition, alloying element, solidification, and graphite morphologies, of different types of cast iron. It describes the physical properties for various cast irons and the influence of microstructure and chemical composition on each property. The article provides a detailed account on thermal properties, conductive properties, magnetic properties, and acoustic properties of cast iron. It also discusses heat treatment, namely, stress relieving, annealing, normalizing, through hardening, and surface hardening. The article presents a discussion on the welding, machining and grinding, and coating of the types of cast iron.

Malleable iron is a cast ferrous metal that is initially produced as white cast iron and is then heat treated to convert the carbon-containing phase from iron carbide to a nodular form of graphite called temper carbon. This article provides a discussion on the melting practices, heat treatment, microstructure, production technologies, mechanical properties, and applications of ferritic, pearlitic, and martensitic malleable iron.

This article presents ternary alloy phase diagrams to be used primarily by engineers to solve industrial problems. The diagrams presented are for stable equilibrium conditions, with the exception of metastable conditions for some diagrams involving carbon and iron. In some ternary diagrams involving carbon and iron, the symbol M is used to represent both iron and the other metallic element when the two metals substitute for each other in a carbide phase.

This article discusses the ferromagnetic properties of soft magnetic materials, explaining the effects of impurities, alloying elements, heat treatment, grain size, and grain orientation on soft magnetic materials. It describes the types of soft magnetic materials, which include high-purity iron, low-carbon irons, silicon (electrical) steels, nickel-iron alloys, iron-cobalt alloys, ferritic stainless steels, amorphous metals, and ferrites (ceramics). Finally, the article provides a short note on alloys for magnetic temperature compensation.