Search Results for iron

This article presents a discussion on the melting, pouring, and shakeout practices; composition control; molds, patterns, and casting design; heat treatment; and applications of different classes of nickel-chromium white irons and high-chromium white irons.

Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out during inoculation and nucleation of molten cast iron, assisting in the formation of cast iron. The different types of cast irons are gray cast iron, nodular cast iron, compacted graphite iron, malleable cast iron, and alloyed cast iron. The article provides an overview of the melt treatment processes carried out in cast steel, wrought and cast aluminum, and copper materials.

The solidification of hypoeutectic cast iron starts with the nucleation and growth of austenite dendrites, while that of hypereutectic iron starts with the crystallization of primary graphite in the stable system or cementite in the metastable system. This article begins with a discussion on the nucleation and growth of austenite dendrites. It describes the nucleation of lamellar graphite, spheroidal graphite, and austenite-iron carbide eutectic. The article reviews three main graphite morphologies crystallizing from the iron melts during solidification: lamellar (LG), compacted or vermicular (CG), and spheroidal. It discusses the metastable solidification of austenite-iron carbide eutectic and concludes with information on gray-to-white structural transition of cast iron.

The control of the solidification process of cast iron requires understanding and control of the thermodynamics of the liquid and solid phases and of the kinetics of their solidification, including nucleation and growth. This article addresses issues that allow for the determination of probability of formation and relative stability of various phases. These include the influence of temperature and composition on solubility of various elements in iron-base alloys; calculation of solubility lines, relevant to the construction of phase diagrams; and calculation of activity of various components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems, along with saturation degree and carbon equivalent.

Thin-wall gray cast iron (TWGCI) can be seen as a potential material for the preparation of lightweight castings in automotive engineering applications. This article discusses the most important challenges for TWGCI: cooling rate, solidification, macrostructure, microstructure, and chilling tendency. It reviews the tensile properties and thermophysical properties of gray cast iron. The article describes the variables that influence molten iron preparation: charge materials, melting furnace thermal regime, chemical composition, modification and inoculation treatment, holding time/pouring procedure, mold properties (mold temperature, thermophysical properties of mold and mold coating), and casting design.

Cast irons, like steels, are iron-carbon alloys but with higher carbon levels than steels to take advantage of eutectic solidification in the binary iron-carbon system. This article introduces the solid-state heat treatment of iron castings and describes the various processes of heat treatment of cast iron. It provides information on stress relieving, annealing, normalizing, through hardening, and surface hardening of these castings. The article discusses general considerations for the heat treatment of cast iron. Cast irons are occasionally nitrided for various applications with the aim of enhancing surface hardness and corrosion resistance of the products. The article describes molten salt bath cyaniding and ion nitriding of cast iron.

This article is a compilation of ternary alloy phase diagrams for which iron (Fe) is the first-named element in the ternary system. The diagrams are presented with element compositions in weight percent. The article includes 16 phase diagrams: Fe-Mn-Ni liquidus projection; Fe-Mn-Ni isothermal section at 750 °C; Fe-Mn-Ni isothermal section at 850 °C; Fe-Mn-Ni isothermal section at 650 °C; Fe-Mn-Ni isothermal section at 550 °C; Fe-Mo-Nb isothermal section at 1050 °C; Fe-Mo-Nb isothermal section at 1150 °C; Fe-Mo-Nb isothermal section at 900 °C; Fe-Mo-Ni liquidus projection; Fe-Mo-Ni isothermal section at 1100 °C; Fe-Mo-Ni isothermal section at 1200 °C; Fe-Ni-W liquidus and solidus projections; Fe-Ni-W isothermal section at 1500 °C; Fe-Ni-W isothermal section at 1455 °C; Fe-Ni-W isothermal section at 1465 °C; and Fe-Ni-W isothermal section at 1400 °C.

This article is a compilation of binary alloy phase diagrams for which iron (Fe) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article is a collection of two iron-carbon phase diagrams.

This article is a pictorial representation of commonly observed microstructures in iron-base alloys (carbon and alloy steels, cast irons, tool steels, and stainless steels) that occur as a result of variations in chemical analysis and processing. It reviews a wide range of common and complex mixtures of constituents (single or combination of two phases) that are encountered in iron-base alloys and the complex structure that is observed in these microstructures. The single-phase constituents discussed in the article include austenite, ferrite, delta ferrite, cementite, various alloy carbides, graphite, martensite, and a variety of intermetallic phases, nitrides, and nonmetallic inclusions. The article further describes the two-phase constituents including, tempered martensite, pearlite, and bainite and nonmetallic inclusions in steel that consist of two or more phases.

This article provides information on soldering iron and the most common soldering iron tip. It describes the classifications of hand soldering equipment based on its temperature control method. These are constant-voltage, variable temperature, and tip-temperature-controlled soldering irons. The article also reviews the selection criteria of the soldering iron.

A significant amount of the worldwide demand for metals is met with recycled materials acquired by metal producers in the form of purchased scrap. This article focuses primarily on the methods and technology used to process and repurpose the vast amounts of purchased scrap that recirculate in the industrial supply chain. It describes the U.S. market for iron and steel scrap, providing information on scrap use by industry, factors influencing demand, and the purchased scrap supply. Iron and steel recycling is discussed separately from stainless steel and superalloy recycling in this article, as the scrap industry treats them differently. The scrap processing of iron involves collection, separation and sorting, size reduction and compaction, detinning, blending, and incineration. The recycling of stainless steels and superalloys follows the same process, but requires several additional steps, including secondary nickel refining, degreasing, and separation of metallurgical wastes.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of iron-base superalloys and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the neutron irradiation effect, fracture mode, fracture toughness, sulfidation corrosion failure, and interdendritic attack of gas sampling line couplings of coal-gasification pilot plants of these superalloys.

This article describes the metallographic specimen preparation procedures for cast iron test samples, including mounting, grinding, polishing, and etching. It discusses the makeup and use of black-and-white and selective color etchants and where one might be preferred over the other. The article provides information on nearly 100 micrographs, discussing the microstructure of flake graphite in gray iron, nodular graphite in ductile iron, and temper graphite in malleable iron. It also examines the matrix microstructures of gray, ductile, compacted, and malleable cast iron samples.

ASTM specification A 48 classifies gray irons in terms of tensile strength. The usual microstructure of gray iron is a matrix of pearlite with graphite flakes dispersed throughout. Section sensitivity effects are used in the form of a wedge test in production control to judge the suitability of an iron for pouring a particular casting. Mechanical property values obtained from test bars are sometimes the only available guides to the mechanical properties of the metal in production castings. Gray iron castings are used widely in pressure applications such as cylinder blocks, manifolds, pipe and pipe fittings, compressors, and pumps. Where high impact resistance is needed, gray iron is not recommended. The machinability of most gray cast iron is superior to that of most other cast irons of equivalent hardness, as well as to that of virtually all steel. Gray iron is used widely for machine components that must resist wear.

Malleable iron possesses considerable ductility and toughness because of its combination of nodular graphite and a low-carbon metallic matrix. The desired formation of temper carbon in malleable irons has two basic requirements. First, graphite should not form during the solidification of the white cast iron, and second, graphite must also be readily formed during the annealing heat treatment. These two metallurgical requirements influence the useful compositions of malleable irons and the melting, solidification, and annealing procedures. There are two basic types of malleable iron: blackheart and whiteheart. This article considers only the blackheart type and describes the metallurgical factors of malleable iron. It discusses the mechanical properties of pearlitic and martensitic malleable irons. The article provides additional information on the properties and heat treatment of ferritic, pearlitic, and martensitic malleable irons. The article lists some of the typical applications of malleable iron castings.

This article discusses the compositions, properties, and typical applications for ductile irons that are defined by U.S. and international standards . It describes the various methods used to test and inspect the metallurgical control processes in ductile iron production. The article discusses the effect of composition, graphite shape, and section size on the properties of ductile iron. The article also describes the mechanical properties of ductile iron at elevated temperatures. The heat treatment of ductile iron castings produces a significant difference in mechanical properties from as-cast ductile iron. A ductile iron generally has higher hardenability than a eutectoid steel with comparable alloy content. The article also discusses the physical properties of ductile iron, including density, thermal conductivity, electrical conductivity, electrical resistivity, and magnetic properties. Ductile iron has been chosen in many instances on the basis of significantly lower machining costs, which resulted in lower overall cost of the part.

This article discusses the classification schemes for cast irons and describes the characteristics of major categories, including gray iron, white iron, ductile iron, compacted graphite iron, mottled iron, malleable iron, and austempered ductile iron. It also discusses some of the basic principles of cast iron metallurgy. When discussing the metallurgy of cast iron, the main factors of influence on the structure include chemical composition, cooling rate, liquid treatment, and heat treatment. In terms of commercial status, cast irons can be classified as common cast irons and special cast irons. Special cast irons differ from the common cast irons mainly in the higher content of alloying elements. Alloying elements can be added in common cast iron to enhance some mechanical properties. They influence both the graphitization potential and the structure and properties of the matrix.

This article discusses the chemical composition, castability, mechanical properties at room temperature and elevated temperature, and physical properties of compacted graphite (CG) cast iron. The change in graphite morphology from the flake graphite (FG) in the base iron to the CG in the final iron is achieved by liquid treatment with different minor elements. CG irons have strength properties close to those of spheroidal graphite (SG) irons, at considerably higher elongations than those of FG iron, and with intermediate thermal conductivities. The main factors affecting the mechanical properties of CG irons both at room temperatures and at elevated temperatures are composition, structure (nodularity and matrix), and section size. The article also discusses the applications of CG irons that stem from their relative intermediate position between FG and SG irons. The tables in the article list the values for tensile properties, hardness, thermal conductivity, fatigue strengths, endurance ratios, and compressive properties of CG, FG, and SG irons.

This article begins with an overview of classes and applications of gray iron. It discusses the castability of gray iron in terms of section sensitivity and fluidity. The article provides information on the dimensions of prevailing sections recommended for gray irons and reviews the properties and specifications of test bar. Properties of gray iron, such as fatigue limit, pressure tightness, impact resistance, machinability, and dimensional stability, at both room and elevated temperature, are reviewed. Wear behavior of gray iron castings during sliding contact under conditions of normal lubrication is also discussed. The article evaluates the use of alloys and heat treatment to modify as-cast properties. It concludes with information on the physical properties of gray iron castings.