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Book Chapter
Noble and Precious Metal Applications in Biomaterials with Emphasis on Dentistry
Available to PurchaseSeries: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005670
EISBN: 978-1-62708-198-6
... information on gold coatings and iridium oxide coatings for stents. biomedical applications dentistry direct gold dental filling materials direct silver dental filling materials gallium alloys gold gold coatings high-copper amalgam alloys iridium iridium oxide coatings mechanical properties...
Abstract
This article focuses on the use of noble and precious metals for biomedical applications. These include gold, platinum, palladium, ruthenium, rhodium, iridium, and osmium. The physical and mechanical properties of noble and precious metals are presented in tables. A brief discussion on the ancient history of noble and precious metal use in dentistry is provided. The article discusses the use of direct gold dental filling materials, direct silver dental filling materials, traditional amalgam alloys, high-copper amalgam alloys, and gallium alloys in biomedical applications. It also provides information on gold coatings and iridium oxide coatings for stents.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003829
EISBN: 978-1-62708-183-2
... Abstract This article characterizes the corrosion resistance of precious metals, namely, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold. It provides a discussion on the general fabricability; atomic, structural, physical, and mechanical properties; oxidation...
Abstract
This article characterizes the corrosion resistance of precious metals, namely, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold. It provides a discussion on the general fabricability; atomic, structural, physical, and mechanical properties; oxidation and corrosion resistance; and corrosion applications of these precious metals. The article also tabulates the corrosion rates of these precious metals in corrosive environment, namely, acids, salts, and halogens.
Book Chapter
Precious Metals and Alloys
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003150
EISBN: 978-1-62708-199-3
.... Iridium Does not tarnish at room temperature, but heating in air at temperatures above 600 °C (1110 °F) will produce a thin oxide tarnish. At temperatures above 1000 °C (1830 °F), a volatile oxide forms. Platinum Resistant to oxidation at all temperatures up to its melting point of 1769 °C (3216 °F...
Abstract
Precious metals include gold, silver, and six platinum-group metals, namely, platinum, palladium, ruthenium, rhodium, osmium, and iridium. This article focuses on the consumption, trade practices, properties, product forms, and applications of these metals and their alloys.
Book Chapter
Precious Metals
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001087
EISBN: 978-1-62708-162-7
... of uses, ranging from electrical conductors and contacts to components for chemical equipment. Silver is also used in various chemical processes, including catalytic applications such as the production of formaldehyde or the oxidation of ethylene. Silver coatings are applied to glass and ceramics...
Abstract
Precious metals are of inestimable value to modern civilization. This article discusses the resources and consumption, trade practices, and special properties of precious metals and its alloys, including ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold, and tabulates the industrial applications of precious metals. It provides information on the commercial forms (wire, rod, sheet, strip, ribbon, and foil) and uses of precious metals, including semifinished products, precious metal powders, industrial uses, coatings, and jewelry.
Book Chapter
Protective Coatings for Carbon-Carbon Composites
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001318
EISBN: 978-1-62708-170-2
... ). Coating technology for carbon-carbon has been driven primarily by the aerospace and defense industries, in applications where the composite is exposed to high-temperature oxidizing environments. Advanced applications include hot-section components for limited-life missile engines, exhaust components...
Abstract
Carbon-carbon is a unique composite material in which a nonstructural carbonaceous matrix is reinforced by carbon fibers to create a heat-resistant structural material that finds application in the aerospace and defense industries. This article provides a detailed account of the fundamentals of protecting carbon-carbon composites and explains the various coating deposition techniques, namely, pack cementation, chemical vapor deposition, and slurry coatings. It includes information on the practical limitations of coatings for the carbon-carbon composites.
Book Chapter
Introduction to Fundamentals of Corrosion in Gases
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003716
EISBN: 978-1-62708-182-5
.... In most cases, corrosion resistance at high temperatures does not accompany the good mechanical properties of structural materials; therefore, protective coatings must be applied. Electrochemical principles are insufficient to understand the mechanism of oxidation. For gaseous reactions, a basic...
Abstract
This article provides an introduction to the fundamentals of corrosion in gases. It tabulates the structures and properties of oxides as well as the physical properties of pure metals.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001254
EISBN: 978-1-62708-170-2
... or oxygen-bearing environments, the platinum-group metals are coated with a very thin layer of the appropriate metal oxide. This film is referred to as a passive layer , and it serves to prevent the underlying metal from corroding. Thus, anodes fabricated from PGMs are insoluble (inert) in most...
Abstract
The electroplating of platinum-group metals (PGMs) from aqueous electrolytes for engineering applications is limited principally to palladium and, to a lesser extent, to platinum, rhodium, and thin layers of ruthenium. This article provides a discussion on the plating operations of these PGMs along with the types of anodes used in the process.
Book Chapter
Thermocouple Materials
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003158
EISBN: 978-1-62708-199-3
... alloy/20 alloy is not good when compared with that of the standard type K couple. 19 alloy/20 alloy thermocouples should not be used in oxidizing atmospheres above 650 °C (1200 °F). Iridium-Rhodium Three iridium-rhodium thermocouples are commercially available: 60Ir-40Rh/Ir (the most widely used...
Abstract
Thermocouple devices are the most widely used devices for measurement of temperature in the metals industry. Favorable characteristics of these devices include good accuracy, suitability over a wide temperature range, fast thermal response, ruggedness, high reliability, low cost, and great versatility of application. Thermocouples are grouped into two broad categories, namely, standard thermocouples, including five base-metal thermocouples and three noble-metal thermocouples that have been given letter designations, and nonstandard thermocouples, including iridium-rhodium, platinum-molybdenum, platinel, and tungsten-rhenium thermocouples. This article discusses the basic principles, classification, and properties of thermocouples, and the techniques for insulating and protecting thermocouple wires from the operating environment.
Book Chapter
Surface Engineering of Refractory Metals and Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001313
EISBN: 978-1-62708-170-2
... are efforts to reduce the thickness of the natural oxide on TZM. Iridium coatings about 12 μm (475 μin.) thick, plated in a fused cyanide bath, over chromium on nickel over gold strike-coated molybdenum, offered oxidation protection for about 1 2 h in air at 1000 °C (1830 °F). A typical...
Abstract
This article addresses surface cleaning, finishing, and coating operations that have proven to be effective for molybdenum, tungsten, tantalum, and niobium. It describes standard procedures for abrasive blasting, molten caustic processing, acid cleaning, pickling, and solvent and electrolytic cleaning as well as mechanical grinding and finishing. The article also provides information on common plating and coating methods, including electroplating, anodizing, and oxidation-resistant coatings.
Book Chapter
Properties of Precious Metals
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001088
EISBN: 978-1-62708-162-7
... windshields, and microelectronic components. Silver anodes of various shapes are used in the electroplating industry. In the chemical industry, silver is used as a catalyst for the dehydrogenation of methanol to make formaldehyde, and in the oxidation of ethylene to ethylene oxide. Silver may also be used...
Abstract
This article discusses the chemical composition, fabrication characteristics, applications, mechanical properties, mass characteristics, thermal properties, electrical properties, optical properties, and chemical properties of precious metals, namely, silver, gold, platinum, and palladium and their corresponding alloys.
Book Chapter
Introduction to Corrosion of Nonferrous Metals and Specialty Products
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003814
EISBN: 978-1-62708-183-2
... to corrosive environments from passive oxide films, which heal rapidly in air if scratched. Decorative chromium coatings are generally less than 1.2 μm (0.05 mil) thick, while coatings thicker than this are used to resist both corrosion and wear. In this Section, the reader learns of the preplating...
Abstract
Nonferrous metals and alloys are widely used to resist corrosion. This article describes the corrosion behavior of the most widely used nonferrous metals, such as aluminum, copper, nickel, and titanium. It also provides information on several specialty nonferrous products that cannot easily be categorized by elemental base.
Book Chapter
Carbon-Carbon Composites
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003064
EISBN: 978-1-62708-200-6
... was achieved, significant problems associated with volatile oxide formation, adherence, and the high CTE of iridium limited the usefulness of this technology. More recently, radio-frequency magnetron sputtering has been used to apply uniform iridium coatings that are maintained during high-temperature heat...
Abstract
Carbon-carbon composites (CCCs) are introduced in fields that require their high specific strength and stiffness, in combination with their thermoshock resistance, chemical resistance, and fracture toughness, especially at high temperatures. The use of CCCs has expanded as the price of carbon fibers has dropped and their mechanical properties have increased. This article begins with an overview of the carbon conversion processes, fiber properties and microstructures, and interfacial bonding and environmental interaction of carbon fibers, followed by a detailed discussion on the various techniques available for processing CCCs for specific applications, including preform fabrication (fiber weaving), densification, application of protective coatings, and joining. The article closes with a description of the mechanical and physical properties and applications of CCCs. The main applications of CCCs, in terms of money and mass, are in the military, space, and aircraft industries.
Book Chapter
Metallography and Microstructures of Precious Metals and Precious Metal Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003776
EISBN: 978-1-62708-177-1
... micrographs, comparing and contrasting the microstructural features of gold, platinum, iridium, palladium, and ruthenium-base alloys. It examines pure gold, intermetallic gold compounds, gold and platinum jewelry alloys, platinum-containing shape memory alloys, and alloys consisting of platinum, aluminum...
Abstract
This article explains how to prepare precious metal test samples for metallographic examination. It discusses cutting, mounting, grinding, polishing, and etching and addresses some of the challenges of working with small, relatively soft specimens. It includes dozens of example micrographs, comparing and contrasting the microstructural features of gold, platinum, iridium, palladium, and ruthenium-base alloys. It examines pure gold, intermetallic gold compounds, gold and platinum jewelry alloys, platinum-containing shape memory alloys, and alloys consisting of platinum, aluminum, and copper.
Book Chapter
Refractory Metals and Alloys
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003151
EISBN: 978-1-62708-199-3
... Abstract The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. They are readily degraded by oxidizing environments at moderately low temperatures. Protective coating systems have been developed, mostly for niobium alloys, to permit their use in high-temperature...
Abstract
The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. They are readily degraded by oxidizing environments at moderately low temperatures. Protective coating systems have been developed, mostly for niobium alloys, to permit their use in high-temperature oxidizing aerospace applications. This article discusses the properties, processing, applications, and classes of refractory metals and its alloys, namely molybdenum, tungsten, niobium, tantalum and rhenium. It also provides an outline of the coating processes used to improve their oxidation resistance.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001098
EISBN: 978-1-62708-162-7
... oxidation resistance at elevated temperatures, is the United States thermometric reference standard. This standard can be obtained from the National Institute of Standards and Technology (formerly NBS). The change in emf with temperature for two electrical conductors A and B, which are, respectively...
Abstract
This article provides an in-depth review of thermocouples and the metals from which they are made. It explains how dissimilar metal conductors in contact at opposite ends can generate an electromotive force if the junctions are heated or cooled to different temperatures. The article discusses thermocouple circuits and instrumentation, calibration methods, insulation requirements, operating ranges, measurement errors, and maintenance procedures. It also provides property data and emf curves for common metals and thermocouple types, and contains information on color coding used around the world.
Book Chapter
Processing of Carbon-Carbon Composites
Available to PurchaseBook: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003422
EISBN: 978-1-62708-195-5
... attractive alternative. Protective Coatings Coating technology for carbon-carbon has been driven primarily by the aerospace and defense industries, in applications where the composite is exposed to high-temperature oxidizing environments. Advanced applications include hot-section components...
Abstract
This article describes the manufacture, post-processing, fabrication, and properties of carbon-carbon composites (CCCs). Manufacturing techniques with respect to the processibility of different geometries of two-directional and multiaxial carbon fibers are listed in a table. The article discusses matrix precursor impregnants, liquid impregnation, and chemical vapor infiltration (CVI) for densification of CCCs. It presents various coating approaches for protecting CCCs, including pack cementation, chemical vapor deposition, and slurry coating. Practical limitations of coatings are also discussed. The article concludes with information on the mechanical properties of CCCs.
Book Chapter
Electrical Contact Materials
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001097
EISBN: 978-1-62708-162-7
... providing a circuit of low resistance. In some applications, such as knife switches, plugs, and bolted connectors, contact surfaces are protected with grease or coatings of silver, nickel, or tin. In power circuits, where oxidation of copper is troublesome, contacts frequently are coated with silver. Vacuum...
Abstract
Electrical contacts are metal devices that make and break electrical circuits. This article provides information on materials selection criteria and failure modes of make-break contacts. It describes the property requirements for make-break arcing contacts, namely, electrical conductivity, mechanical properties, chemical properties, fabrication properties, and thermal properties. The article presents a brief note on brush contact materials and their interdependence factors for sliding contacts. It also describes the type of commercial contact materials for electrical contacts, namely, copper metals, silver metals, gold metals, metals of the platinum group, precious metal overlays, tungsten and molybdenum, aluminum, and composite materials. Finally, the article provides information on composite manufacturing methods, and tabulates the physical, and mechanical properties of electrical contact materials, including copper, silver, gold, platinum, palladium, and composites.
Book Chapter
Corrosion of Intermetallics
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003837
EISBN: 978-1-62708-183-2
... reported to have better mechanical properties than platinum aluminides and yet still offer a comparable level of corrosion resistance ( Ref 42 ), whereas the addition of rhodium is thought to increase both coating stability and oxidation resistance ( Ref 43 ). However, the performance of iridium-modified...
Abstract
This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. Thermodynamic principles in the context of high-temperature corrosion and information on oxidation; sulfidation; hot corrosion of NiAl-, FeAl-, and TiAl-based intermetallics; and silicides are included. The article explores the thermodynamic consideration, ordering influencing kinetics, stress-cracking corrosion, and hydrogen embrittlement of aqueous corrosion. It also explains the practical issues dealing with the corrosion problems.
Book Chapter
Properties and Performance of Ceramic-Matrix and Carbon-Carbon Composites
Available to PurchaseBook: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003449
EISBN: 978-1-62708-195-5
... to the fibers during processing. However, both carbon and boron nitride are susceptible to environmental degradation at elevated temperatures. As a result, a variety of alternative multilayer and oxide-base coatings are in the design/feasibility stage. Mechanical and Physical Properties In CFCCs...
Abstract
This article discusses the mechanisms for enhancing the reliability of three types of ceramic-matrix composites: discontinuously reinforced ceramic-matrix composites, continuous fiber ceramic composites, and carbon-carbon composites. It also presents examples of their mechanical and physical properties. Examples that illustrate the properties of commercially available materials are also provided.
Book Chapter
Chemical Vapor Deposition of Nonsemiconductor Materials
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001283
EISBN: 978-1-62708-170-2
... and a metal in solution with another metal. A common reaction involves coating iron objects (such as turbine blades) with chromium, using chromium powder and ammonium iodide as reactants and aluminum oxide as an inert filler. Parts and chemicals are loaded in a molybdenum container that is then sealed...
Abstract
This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.
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