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Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004001
EISBN: 978-1-62708-185-6
... Abstract This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing...
Abstract
This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing of the gamma aluminides with particular reference to production scaleable techniques, including vacuum arc and cold-hearth melting, isothermal forging, conventional hot forging, and extrusion. The selection and design of manufacturing methods, in the context of processing-cost trade-offs for gamma titanium aluminide alloys, are also discussed.
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Published: 01 January 2002
Fig. 57 Sigma (σ) phase in cast heat-resistant alloy HH, type II. Intermetallic phases, such as σ, can greatly reduce the ductility of many high-temperature alloys in service at temperatures from 480 to 955 °C (900 to 1750 °F).
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Image
Published: 01 December 2004
Fig. 40 50Sn-50In alloy. Structure is a eutectic of globular tin-rich intermetallic phase (light) in a matrix of dark indium-rich intermetallic. Etchant 1, Table 1 . 150×
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Image
Published: 01 December 2004
Fig. 9 Zn-0.025Fe alloy, hot graphite mold, slow cooling. Zeta-phase intermetallic compounds. Electrolytic polish. Electrolytic etch: etchant 6, Table 1 (short time). 200×
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Image
Published: 30 August 2021
Fig. 33 Sigma (σ) phase in cast heat-resistant alloy HH, type II. Intermetallic phases, such as σ, can greatly reduce the ductility of many high-temperature alloys in service at temperatures from 480 to 955 °C (900 to 1750 °F).
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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001102
EISBN: 978-1-62708-162-7
.... alloying effects environmental embrittlement fabrication iron aluminides intermetallic mechanical behavior metallurgical properties nickel aluminides silicides titanium aluminides ORDERED INTERMETALLIC compounds constitute a unique class of metallic materials that form long-range ordered...
Abstract
Ordered intermetallic compounds based on aluminides and silicides constitute a unique class of metallic materials that have promising physical and mechanical properties for structural applications at elevated temperatures. This article provides useful information on mechanical and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides.
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in Ordered Intermetallics
> Properties and Selection: Nonferrous Alloys and Special-Purpose Materials
Published: 01 January 1990
Fig. 1 Atomic arrangements of conventional alloys and ordered intermetallic compounds. (a) Disordered crystal structure of a conventional alloy. (b) Long-range ordered crystal structure of an ordered intermetallic compound
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Image
Published: 01 December 1998
Fig. 1 Atomic arrangements of conventional alloys and ordered intermetallic compounds. (a) Disordered crystal structure of a conventional alloy. (b) Long-range ordered crystal structure of an ordered intermetallic compound
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Published: 01 January 2003
Fig. 2 Schematic drawing of the cross section of a hot-dip coated sheet product showing the three features of all hot-dip coated sheet products—the outer coating layer, the intermetallic alloy bond zone, and the steel sheet substrate
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003164
EISBN: 978-1-62708-199-3
... Abstract Alloys based on ordered intermetallic compounds constitute a unique class of metallic material that form long-range ordered crystal structures below a critical temperature. Aluminides, a unique class of ordered intermetallic materials, possesses many attributes like low densities, high...
Abstract
Alloys based on ordered intermetallic compounds constitute a unique class of metallic material that form long-range ordered crystal structures below a critical temperature. Aluminides, a unique class of ordered intermetallic materials, possesses many attributes like low densities, high melting points, and good high-temperature strength that make them an attractive material for high-temperature structural application. This article discusses the properties, chemical composition, corrosion resistance, processing, fabrication, alloying effects and crystallographic data of nickel aluminides (Ni3Al and NiAl), iron aluminides (Fe3Al and FeAl) and titanium aluminides (alpha-2 alloys, orthorhombic alloys, and gamma alloys).
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001416
EISBN: 978-1-62708-173-3
... Abstract This article focuses on the physical metallurgy and weldability of four families of titanium-base alloys, namely, near-alpha alloy, alpha-beta alloy, near-beta, or metastable-beta alloy, and titanium based intermetallics that include alpha-2, gamma, and orthorhombic systems...
Abstract
This article focuses on the physical metallurgy and weldability of four families of titanium-base alloys, namely, near-alpha alloy, alpha-beta alloy, near-beta, or metastable-beta alloy, and titanium based intermetallics that include alpha-2, gamma, and orthorhombic systems.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003837
EISBN: 978-1-62708-183-2
... Abstract This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. Thermodynamic principles in the context of high-temperature corrosion...
Abstract
This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. Thermodynamic principles in the context of high-temperature corrosion and information on oxidation; sulfidation; hot corrosion of NiAl-, FeAl-, and TiAl-based intermetallics; and silicides are included. The article explores the thermodynamic consideration, ordering influencing kinetics, stress-cracking corrosion, and hydrogen embrittlement of aqueous corrosion. It also explains the practical issues dealing with the corrosion problems.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003728
EISBN: 978-1-62708-177-1
... the β components of α + β alloys ( Ref 1 ). In this respect, lightweight titanium-aluminum intermetallic alloys have been extensively studied as potential high-temperature materials for structural applications ( Ref 6 , 7 , 8 , and 9 ) in the gas turbine industry, aeroengines and automotive...
Abstract
This article describes the development of heat-resistant titanium-base alloys and their classification into several microstructure categories based on their strengthening mechanisms. It explains the phase transformation in titanium-aluminum-base alloys and two peritectic reactions that take place in the titanium-aluminum system. The article also describes two approaches for controlling the orientation of the high-temperature alpha phase to achieve the required lamellar orientation by directional solidification in order to improve the strength and ductility of titanium-aluminum alloys. One approach is by seeding the alpha phase in the alloys, and the other is without seeding, by controlling the solidification path of alloys through appropriate alloying. The article discusses the grain refinement technique used to improve the ductility of cast titanium-aluminum alloys to a level of above 1" at room temperature and reasonable room temperature ductility in the as-cast condition. Finally, it provides information on the microstructures produced through various near-net shape manufacturing processes.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003140
EISBN: 978-1-62708-199-3
... other transition metals. These elements have low solubility in α titanium and decrease the transformation temperature. They usually are added to alloys in combination with one or more of the β isomorphous elements to stabilize the β phase and prevent or minimize formation of intermetallic compounds...
Abstract
Titanium and its alloys are used in various applications owing to its high strength, stiffness, good toughness, low density, and good corrosion resistance. This article discusses the applications of titanium and titanium alloys in gas turbine engine components, aerospace pressure vessels, optic-system support structures, prosthetic devices, and applications requiring corrosion resistance and high strength. It explains the effects of alloying elements in titanium alloys as they play an important role in controlling the microstructure and properties and describes the secondary phases and martensitic transformations formed in titanium alloy systems. Information on commercial and semicommercial grades and alloys of titanium is tabulated. The article also discusses the different grades of titanium alloys such as alpha, near-alpha alloys, alpha-beta alloys, beta alloys, and advanced titanium alloys (titanium-matrix composites and titanium aluminides).
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003971
EISBN: 978-1-62708-185-6
... materials, such as intermetallic alloys and composites, have been developed. Furthermore, the advent of user-friendly computer codes and inexpensive computers has led to a revolution in the application of numerical methods for the design and control of a plethora of bulk-forming processes, thus leading...
Abstract
Metalworking is one of the three major technologies used to fabricate metal products. This article tabulates the classification of metal forming processes. It discusses different types of metalworking equipment, including rolling mills, ring-rolling machines, and thread-rolling and surface-rolling machines. The article outlines the significant characteristics of pressing-type machines: load and energy characteristics, time-related characteristics, and accuracy characteristics. It summarizes different specialized processes such as advanced roll-forming methods, equal-channel angular extrusion, incremental forging, and microforming. The article describes the thermomechanical processing of nickel- and titanium-base alloys and concludes with information on the advancements in process simulation.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005620
EISBN: 978-1-62708-174-0
... for rolling and postheating must take into consideration the possibility of intermetallic compound formation, eutectic melting, and/or porosity due to Kirkendall diffusion. The most common metals that are roll welded are low-carbon steels, aluminum and aluminum alloys, copper and copper alloys, d nickel. Low...
Abstract
This article describes two methods based on rolling of sheet. The first is roll welding, where two or more sheets or plates are stacked together and then passed through rolls until sufficient deformation has occurred to produce solid-state welds. The other is laser roll welding, which is a hybrid process based on a thin-melting interface for a lap joint of dissimilar-metal sheets using a roller and one-sided laser heating. The article discusses the types, advantages, and applications of roll welding and laser roll welding. It also provides a detailed discussion on the laser roll welding of dissimilar metals.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001419
EISBN: 978-1-62708-173-3
..., these alloy compositions are characterized by a wider freezing range (typically in excess of 300 °C, or 540 °F) than most aluminum alloys. Conventional I/M processing of these compositions produces equilibrium or near-equilibrium microstructures containing coarse Al 3 Fe-type primary intermetallic particles...
Abstract
Conventional high-strength aluminum alloys produced via powder metallurgy (P/M) technologies, namely, rapid solidification (RS) and mechanical alloying (mechanical attrition) have high strength at room temperature and elevated temperature. This article focuses on the metallurgy and weldability of dispersion-strengthened aluminum alloys based on the aluminum-iron system that are produced using various RS-P/M processing techniques. It describes weldability issues related to weld solidification behavior, the formation of hydrogen-induced porosity in the weld zone, and the high-temperature deformation behavior of these alloys, which affect the selection and application of fusion and solid-state welding processes. The article provides specific examples of material responses to welding conditions and highlights the microstructural development in the weld zone.
Image
Published: 01 December 1998
Fig. 18 Examples of characteristic eutectic microstructures in slowly cooled alloys. (a) 40Sn-50In alloy showing globules of tin-rich intermetallic phase (light) in a matrix of dark indium-rich intermetallic phase. 150×. (b) Al-13Si alloy showing an acicular structure consisting of short
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Image
in Physical Metallurgy Concepts in Interpretation of Microstructures
> Metallography and Microstructures
Published: 01 December 2004
Fig. 8 Examples of characteristic eutectic microstructures in slowly cooled alloys. (a) 50Sn-50In alloy showing globules of tin-rich intermetallic phase (light) in a matrix of dark indium-rich intermetallic phase. Original magnification 150×. (b) Al-13Si alloy showing an acicular structure
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0009239
EISBN: 978-1-62708-173-3
... intermetallics, and low ductility. The article reviews induction and torch brazing, infrared brazing, diffusion brazing, and brazing by heating with ion bombardment. It concludes by describing the design criteria and limitations of brazing. alpha-beta alloys brazing brittle intermetallics carbon steel...
Abstract
This article discusses the effects of brazing temperature and thermal treatment on structure and mechanical behavior of different classes of titanium base metals such as commercially pure (CP) titanium, alpha or near-alpha alloys, alpha-beta alloys, and beta alloys. The classification, properties, and potential heat treatment of titanium base alloys are presented in tables. The article provides information on brazed joints of titanium with carbon steels, as well as ceramics and graphite. It discusses the risks involved in titanium brazing, including erosion of base metal, brittle intermetallics, and low ductility. The article reviews induction and torch brazing, infrared brazing, diffusion brazing, and brazing by heating with ion bombardment. It concludes by describing the design criteria and limitations of brazing.
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