This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing of the gamma aluminides with particular reference to production scaleable techniques, including vacuum arc and cold-hearth melting, isothermal forging, conventional hot forging, and extrusion. The selection and design of manufacturing methods, in the context of processing-cost trade-offs for gamma titanium aluminide alloys, are also discussed.

Alloys based on ordered intermetallic compounds constitute a unique class of metallic material that form long-range ordered crystal structures below a critical temperature. Aluminides, a unique class of ordered intermetallic materials, possesses many attributes like low densities, high melting points, and good high-temperature strength that make them an attractive material for high-temperature structural application. This article discusses the properties, chemical composition, corrosion resistance, processing, fabrication, alloying effects and crystallographic data of nickel aluminides (Ni3Al and NiAl), iron aluminides (Fe3Al and FeAl) and titanium aluminides (alpha-2 alloys, orthorhombic alloys, and gamma alloys).

This article reviews the corrosion behavior of intermetallics for the modeling of the corrosion processes and for devising a strategy to create corrosion protective systems through alloy and coating design. It discusses the high-temperature corrosion properties of intermetallics and aqueous corrosion properties. Thermodynamic principles in the context of high-temperature corrosion and information on oxidation; sulfidation; hot corrosion of NiAl-, FeAl-, and TiAl-based intermetallics; and silicides are included. The article explores the thermodynamic consideration, ordering influencing kinetics, stress-cracking corrosion, and hydrogen embrittlement of aqueous corrosion. It also explains the practical issues dealing with the corrosion problems.

This article begins with a general review of the effects of changes in stress state on processing of materials. It describes the fundamentals of hydrostatic extrusion and reviews the various issues and benefits associated with hydrostatic extrusion. The article discusses the hydrostatic extrusion of structural alloys, composites, brittle materials, and intermetallics or intermetallic compounds, with examples. It concludes with a discussion on the attempts made to extend the hydrostatic extrusion to higher temperatures.

Premanent magnet refers to solid materials that have sufficiently high resistance to demagnetizing fields and sufficiently high magnetic flux output to provide useful and stable magnetic fields. Permanent magnet materials include a variety of alloys, intermetallics, and ceramics. This article discusses the composition, properties, and applications of permanent magnetic materials, such as hysteresis alloys used in motors. It primarily focuses on the stability of magnetic fields that influences reversible and irreversible losses in magnetization with time, and the choice of magnet material, component shape and magnetic circuit arrangement.

Superconductors are materials that exhibit a complete disappearance of electrical resistivity on lowering the temperature below the critical temperature. A superconducting material must exhibit perfect diamagnetism, that is, the complete exclusion of an applied magnetic field from the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics.

Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal applications. This article discusses the mechanical properties of MMCs, namely aluminum-matrix composites, titanium-matrix composites, magnesium-matrix composites, copper-matrix composites, superalloy-matrix composites, and intermetallic-matrix composites. It describes the processing methods of discontinuous aluminum MMCs which include casting processes, liquid-metal infiltration, spray deposition and powder metallurgy. The article provides useful information on aluminum MMC designation system and also describes the types of continuous fiber aluminum MMCs, including aluminum/boron MMC, aluminum/silicon carbide MMC, aluminum/graphite MMC, and aluminum/alumina MMC.

This article is a pictorial representation of commonly observed microstructures in iron-base alloys (carbon and alloy steels, cast irons, tool steels, and stainless steels) that occur as a result of variations in chemical analysis and processing. It reviews a wide range of common and complex mixtures of constituents (single or combination of two phases) that are encountered in iron-base alloys and the complex structure that is observed in these microstructures. The single-phase constituents discussed in the article include austenite, ferrite, delta ferrite, cementite, various alloy carbides, graphite, martensite, and a variety of intermetallic phases, nitrides, and nonmetallic inclusions. The article further describes the two-phase constituents including, tempered martensite, pearlite, and bainite and nonmetallic inclusions in steel that consist of two or more phases.

Analysis of bifilms provides a simple, powerful, and elegant concept to explain many features of the metallurgy of castings. This article describes the effects of bifilms in metals. Mechanisms for the entrainment of bifilms are reviewed. The article describes the effect of furling and unfurling on mechanical properties of the solidified cast metal. It provides a discussion on the mechanisms of unfurling to determine the casting properties of the metals. These include gas precipitation, shrinkage, linear contraction, dendrite pushing, and nucleation and growth of intermetallics. The article also describes the role of bifilm defects in fracture.

This article begins with a discussion on the effects of alloying and impurity elements on the properties of aluminum cast alloys and their chemical compositions. It describes various means of structural control, namely, chemistry control, control of element ratios based on the stoichiometry of intermetallic phases, and control of solidification conditions. The article discusses the modification and grain refinement of aluminum-silicon alloys by the use of modifiers and refiners to influence eutectic and hypereutectic structures in aluminum-silicon alloys. It provides information on the foundry alloys for specific casting applications. The article concludes with a discussion on the heat treatment practices and properties of aluminum casting alloys.

This article presents a diagramatic representation of a periodic system that illustrates the fundamental alloying nature of iron for ferrous metallurgists.

This article summarizes the Sendzimir process, the Cook-Norteman process, the coating types, composition, characteristics, and typical applications of various metallic coatings, such as zinc, aluminum, zinc-aluminum alloy, and aluminum-zinc alloy coatings. It provides a discussion on aqueous corrosion and atmospheric corrosion of galvanized steel and aluminized steel, as well as the intergranular corrosion of galvanized steel.

This article provides a discussion on binary alloy phase diagrams published in this handbook. All diagrams presented are for stable equilibrium conditions, except where metastable conditions are indicated.

Homogenization, in a broad sense, refers to processes designed to achieve uniform distribution of solutes or phases in a given matrix. This article addresses the root cause for inhomogeneities in cast components. It is nearly standard industrial practice to homogenize alloys before thermomechanical processing. The article lists objectives of homogenization and benefits of homogenization treatments. The benefits include increased resistance to pitting corrosion, increased resistance to stress-corrosion cracking, improved ductility, and uniform precipitate distribution during subsequent aging. The article provides a schematic illustration of energy-dispersive x-ray spectroscope (EDS) scattered data of solute distributions across a dendrite due to microsegregation of chromium and molybdenum. It concludes with a section on computational modeling for simulation of microsegregation of chromium and molybdenum.

This article provides an overview of heat treatment processes, namely, solution heat treatment, quenching, and natural and artificial aging. It contains a table that lists various heat treatment tempers commonly practiced for nonferrous castings. The article describes microstructural changes that occur due to the heat treatment of cast alloys.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of electronic materials, including L-shaped electronic flat pack, transistor base lead, ohmic contact window, and brush/slip ring assembly. The fractographs illustrate the atomic oxygen environment exposure effect, solar cell interconnect, integrated circuit defects, and fatigue failure of these materials.

Titanium and its alloys are used in various applications owing to its high strength, stiffness, good toughness, low density, and good corrosion resistance. This article discusses the applications of titanium and titanium alloys in gas turbine engine components, aerospace pressure vessels, optic-system support structures, prosthetic devices, and applications requiring corrosion resistance and high strength. It explains the effects of alloying elements in titanium alloys as they play an important role in controlling the microstructure and properties and describes the secondary phases and martensitic transformations formed in titanium alloy systems. Information on commercial and semicommercial grades and alloys of titanium is tabulated. The article also discusses the different grades of titanium alloys such as alpha, near-alpha alloys, alpha-beta alloys, beta alloys, and advanced titanium alloys (titanium-matrix composites and titanium aluminides).

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

This article is a compilation of binary alloy phase diagrams for which rhenium (Re) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article discusses the general characteristics, primary and secondary fabrication methods, product forms, and corrosion resistance of zirconium and hafnium. It describes the physical metallurgy of zirconium and its alloys, providing details on allotropic transformation and anisotropy that profoundly influences the engineering properties of zirconium and its alloys. Tables listing the values for chemical composition and tensile properties for nuclear and nonnuclear grades of zirconium are also provided.