The properties of unidirectional composite (UDC) materials are quite different from those of conventional, metallic materials. This article provides information on the treatment of UDC stress-strain relations in the forms appropriate for analysis of thin plies of material. It explains the development of the relations between mid-surface strains and curvatures and membrane stress and moment resultants. The article discusses the properties, such as thermal expansion, moisture expansion, and conductivity, of symmetric laminates and unsymmetric laminates. It describes the distribution of temperature and moisture through the thickness of a laminate. Stresses caused due to mechanical loads, temperature, and moisture on the laminate are analyzed. The article concludes with information on interlaminar cracking, free-edge delamination, and transverse cracks of laminates.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of metal-matrix composites, including tungsten fiber-reinforced aluminum, tungsten fiber-reinforced carbon steel, and tungsten fiber-reinforced silver. The fractographs illustrate the ductile fracture, interlaminar failure, transgranular cleavage and fracture, tension-overload fracture, longitudinal and transverse cracking, fiber splitting, stress rupture, and low-cycle fatigue of these composites.

This article illustrates typical fractographic features for a number of different composite materials. It describes the differences in fracture characteristics due to different loading, material processing, and environmental conditions. The article presents fractographic data obtained from epoxy matrix materials. Minimal fractographic data from other brittle thermoset resin systems are also presented. The article discusses the interlaminar fracture of composites with ductile thermoplastic matrices. It also provides information on the translaminar fracture features of the composite materials.

This article begins with a review of the purposes of mechanical characterization tests and the general considerations related to the mechanical properties of anisotropic systems, specimen fabrication, equipment and fixturing, environmental conditioning, and analysis of test results. It provides information on the specimen preparation, instrumentation, and procedures for various mechanical test methods of fiber-reinforced composites. These include the compression test, flexure test, shear test, open hole tension test, and compression after impact test. The article describes three distinct fracture modes, namely, crack opening mode, shearing mode, and tearing mode. It presents an overview of fatigue testing and fatigue damage mechanisms of composite materials and reviews the types of mechanical measurements that can be made during the course of testing to assess fatigue damage. The article concludes with a discussion on the split-Hopkinson pressure bar test.

Delamination is one of the most commonly observed failure modes in composite materials. This article describes the three fundamental fracture failure modes of composite delamination, namely, opening, in-plane shearing, and tearing or scissoring shearing modes. It discusses the characterization and analysis of delamination. The article also reviews the prediction of delamination factors, such as flexbeam fatigue life, and skin/stiffener pull-off strength and life.

In the design of composite structures for durability and damage tolerance, the primary concerns are out-of-plane failures, such as delamination, material degradation associated with environment, stability under compression loading, large degree of scatter in fatigue life, and bearing failure of joints. This article presents an introductory discussion on the fatigue damage process, methodologies assessing fatigue behavior, and life prediction models. It describes the damage mechanisms introduced for a quasi-isotropic laminate under tension-compression fatigue loading. Delamination is a critical issue in fatigue and generally results from high interlaminar normal and shear stresses. The article schematically illustrates the structural elements in which high interlaminar stresses are common. It concludes with a discussion on the classification of fatigue models such as mechanistic or phenomenological, for composite materials under cyclic loading.

This article describes the failure analysis procedures for composites and the techniques to be used in these analyses. These procedures include a review of the available in-service records, materials and processing methods, print requirements, and manufacturing records; visual analysis and nondestructive part evaluation; and verification of materials and processing methods. The article discusses the determination of fiber, matrix, and void volume fractions and verification of ply lay-up and orientation. A review of composites processing parameters; fractography and surface analysis; and mechanical testing and stress analysis is also presented.

Knowledge of fatigue behavior at the laminate level is essential for understanding the fatigue life of a laminated composite structure. This article describes fatigue failure of composite laminates in terms of layer cracking, delamination, and fiber break and interface debonding. It discusses the fatigue behavior of composite laminates in the form of a relation between applied maximum fatigue stress and fatigue life. The article explains Weibull distribution and parameters estimation for fatigue data analysis and life prediction of composite laminates. It analyzes the fatigue properties and damage tolerance of fiber-metal laminates such as ARALL and GLARE laminates. The article concludes with a discussion on the effects of fatigue on notched and unnotched specimens.

As with most engineering materials, the failure of composite materials, no matter how complex, can be divided into three discrete arenas: improper design, improper manufacturing, and improper use of the end product. This article reviews the failure causes from a broad perspective, so that the composites designer, manufacturer, and user can readily see some of the more common issues associated with unique materials. It discusses the three discrete arenas of failure of composite materials: improper design, improper manufacturing, and improper use of the end product.

This article addresses the issue of the implementation of composite damage tolerance requirements as it relates to military aircraft. It presents a brief introduction on the durability impact threat, damage tolerance impact threat, and other damage tolerance damage threats. The article summarizes damage tolerance criteria and durability criteria for military aircraft. It discusses the damage tolerance design philosophy for metallic structures and composite structures of the aircraft. The article describes the implementation of a damage tolerance analysis methodology in terms of the mechanics based model, the regression algorithm, and the semi-empirical analysis.

This article begins with a discussion on fiber-reinforced composite materials and describes the generic behavior and structure/property relationships of composites. The article summarizes lamina properties and presents equations that help in the calculation of lamina properties. Composite laminates are constructed from lamina with uniaxial fiber orientation and frequently from textile fabrics as well. The article explains the characteristics of symmetric in-plane and through-thickness laminates; asymmetric in-plane and symmetric through-thickness laminates; asymmetric laminates; and curved laminates. It provides information on controlled thermal expansion composites, metal-matrix composites, and ceramic-matrix composites. The article illustrates the types of bonded joints and concludes with a discussion on design for manufacturing.

Mechanical and environmental loadings cause a variety of failure modes in composites, including matrix cracking, fiber-matrix debonding, delamination between plies, and fiber breakage. This article summarizes visual analysis and nondestructive testing methods for the failure analysis of composites. These methods include radiography, ultrasonic techniques, acoustic emission, and thermograph. The article also provides information on destructive test techniques.

This article provides the general mechanical testing guidelines for the characterization of lamina and laminate properties. Guidelines are provided for tensile property, compressive property, shear property, flexure property, fracture toughness, and fatigue property test methods. The article also tabulates selected standards for lamina and laminate mechanical testing.

Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy, contact angle, work of adhesion, solid surface energy, and wetting and wicking. The article describes the change in interphase depending on the reinforcing fiber such as glass fiber, polymeric fiber, and carbon fiber. It emphasizes fiber-matrix adhesion measurements by direct methods, indirect methods, and composite laminate tests. The effects of interphase and fiber-matrix adhesion on composite mechanical properties, such as composite on-axis properties, composite off-axis properties, and composite fracture properties, are also discussed.

This article describes the various pure forms of carbon matrices and the corresponding methods used to create them or incorporate them into a matrix of a composite. These forms include graphite, diamond, fullerenes, and nanotubes. The article discusses the three types of liquid precursors, namely, thermoplastic, thermosetting, and evaporative or solvent carriers. It provides a description of the advantages and limitations of various methods involved in chemical vapor infiltration. The article concludes with a discussion on matrix contribution to composite properties.

This article describes the most significant tests to characterize the properties of constituent materials. It discusses the chemical, physical, and mechanical tests for determining the properties of reinforcement fibers and fabrics. The article provides information on some of the basic materials used for thermoset and thermoplastic resin matrices. It reviews the identification of the individual characteristics of thermoset and thermoplastic resin along with the test methods normally used for their determination. The article contains a table that lists properties and tests for uncured and cured thermoset-matrix resins and prepregs.

This article focuses on the process methods and matrix chemistries of ceramic-matrix composites. These methods include pressure-assisted densification, chemical vapor infiltration, melt infiltration, polymer infiltration and pyrolysis, and sol-gel processing. The article discusses the use of a ceramic, preceramic, or metal phase as a fluid or vapor phase reactant to form the matrix. Emphasis is placed on microstructural features that influence ultimate composite properties.