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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003693
EISBN: 978-1-62708-182-5
... Abstract This article describes the characteristics of zinc-rich coatings that can be subcategorized according to the type of binder material used. It discusses the formulations of zinc-rich coatings with organic binders. The three major groups of inorganic zinc-rich coatings categorized...
Abstract
This article describes the characteristics of zinc-rich coatings that can be subcategorized according to the type of binder material used. It discusses the formulations of zinc-rich coatings with organic binders. The three major groups of inorganic zinc-rich coatings categorized by the Society for Protective Coatings are also discussed. These include postcured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates. The article concludes with information on comparisons of inorganic with organic zinc-rich coatings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006049
EISBN: 978-1-62708-172-6
... used, namely, inorganic and organic zinc-rich coatings. Common inorganic binders such as post-cured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates, are reviewed. The article also compares inorganic and organic zinc-rich...
Abstract
The use of zinc in corrosion-protective coatings is due to its higher galvanic activity relative to that of steel. Pure zinc dust provides the best sacrificial protection to steel in a galvanic couple. Zinc-rich coatings can be subcategorized according to the type of binder material used, namely, inorganic and organic zinc-rich coatings. Common inorganic binders such as post-cured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates, are reviewed. The article also compares inorganic and organic zinc-rich coatings, and discusses the concerns regarding zinc-rich coatings.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004108
EISBN: 978-1-62708-184-9
... development in protective coatings in the last 50 years. Zinc dust is loaded into both organic and inorganic binders to form primers that are extremely effective in the prevention of corrosion, underfilm creepage, and coating system failure. Inorganic Zinc-Rich Primers Inorganic zinc-rich primers...
Abstract
Organic coatings are the principal means of corrosion control for the hulls and topsides of ships and for the splash zones on permanent offshore structures. This article describes surface preparation which is the most important consideration in determining the performance of organic coating systems. It contains a table that lists the uses and applicable standards for various surface preparation techniques. The article provides information on organic coatings in topside coating systems and reviews the importance of primers in the protection of steel substrates. It also explains the property requirements and the common types of immersion coatings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
... and moisture resistance similar to that of the organic binder. Should be topcoated in chemical environments with a pH outside the range of 5 to 10. More tolerant of surface preparation and topcoating than inorganic zinc-rich coatings Generally have lower service performance than inorganic zinc-rich coatings...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006335
EISBN: 978-1-62708-179-5
... of coatings or a coating system depends primarily on the particular structure, exposure environment, and requirements for corrosion protection. Coatings and coatings systems that typically are used, in general order of increasing performance characteristics, are alkyds, acrylics, zinc-rich primers, epoxies...
Abstract
Coating of cast irons is done to improve appearance and resistance to degradation due to corrosion, erosion, and wear. This article describes inorganic coating methods commonly applied to cast irons. The coating methods include plating, hot dip coating, conversion coating, diffusion coating, cladding, porcelain enameling, and thermal spray. Organic coatings have a wide variety of properties, but their primary use is for corrosion resistance combined with a pleasing colored appearance. The article discusses the various types of organic coatings applied to cast irons. Practically any degree of smoothness or roughness and requirement for color and gloss can be filled by organic coatings. The article describes abrasive blast cleaning, abrasive waterjet cleaning and finishing, vibratory finishing, barrel finishing, and shot peening for processing iron castings.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001304
EISBN: 978-1-62708-170-2
..., hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment. alloy steel cadmium plating carbon...
Abstract
This article discusses the classifications, compositions, properties, advantages, disadvantages, limitations, and applications of the most commonly used methods for surface engineering of carbon and alloy steels. These include cleaning methods, finishing methods, conversion coatings, hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006040
EISBN: 978-1-62708-172-6
... system, an inorganic zinc-rich primer and polyurethane/fluorourethane system, an epoxy/epoxy/aliphatic polyurethane system, and an organic zinc-rich primer/epoxy/aliphatic polyurethane system. The AWWA D102 document also describes in detail five suitable inside coating systems for water storage tanks...
Abstract
This article presents information regarding the use of protective coatings in municipal potable water systems, including raw water collection and transmission, water treatment plants, and treated water distribution. It provides useful guidance for the selection and use of protective coatings in these municipal water systems. The most commonplace corrosion-damage mechanisms are highlighted. The article describes the most common materials of construction found in municipal water systems, namely, cast iron, ductile iron, carbon steel, precast concrete cylinder pipe and reinforced concrete pipe, prestressed concrete tanks, and stainless steel. It provides information on the most common generic coating systems used for new steel tanks and water storage tanks. It concludes with a discussion of quality watch-outs when selecting or using protective coatings in municipal water systems.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006028
EISBN: 978-1-62708-172-6
.... Inorganic zinc-rich primers are offered as solvent- or water-borne systems. Inorganic zinc-rich silicates are also covered in the article “Zinc-Rich Coatings” in this Volume. Solvent-Borne Primers Solvent-borne primer compositions, based on partial hydrolyzates of tetra-ethoxy silane, are available...
Abstract
This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001012
EISBN: 978-1-62708-161-0
... of the steel. Zincrometal Zincrometal is also used for outer body panels in automobiles. First introduced in 1972, Zincrometal is a coil coated product consisting of a mixed-oxide underlayer containing metallic zinc particles and a zinc-rich organic (epoxy) topcoat. It is weldable, formable, paintable...
Abstract
Steel sheet is often coated in coil form prior to fabrication to save time, reduce production costs, and streamline operations. This article examines the most common precoating methods and provides a metallurgical understanding of how they impact the manufacturability, performance, and service life of the host material. The article covers metallic coatings, including zinc, aluminum, zinc-aluminum alloys, tin, and terne; pretreatment or phosphate coatings; and preprimed and painted finishes based on organic coatings.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003549
EISBN: 978-1-62708-180-1
... in the environment; change in the alloy or heat treatment; change in design; use of galvanic protection; use of inhibitors; use of nonmetallic coatings and liners; application of metallic coatings; use of surface treatments, thermal spray, or other surface modifications; corrosion monitoring; and preventive...
Abstract
This article provides an overview of the electrochemical nature of corrosion and analyzes corrosion-related failures. It describes corrosion failure analysis and discusses corrective and preventive approaches to mitigate corrosion-related failures of metals. These include: change in the environment; change in the alloy or heat treatment; change in design; use of galvanic protection; use of inhibitors; use of nonmetallic coatings and liners; application of metallic coatings; use of surface treatments, thermal spray, or other surface modifications; corrosion monitoring; and preventive maintenance.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006035
EISBN: 978-1-62708-172-6
... shorter molecules. Inorganic pigments are less affected by ionizing radiation than organic pigments. Inorganic zinc, which is composed of zinc particles in an inorganic matrix, is frequently used in nuclear plants. With most coatings used within a nuclear containment, such as epoxy and phenolic...
Abstract
Surface coatings are essential in all facilities that process nuclear materials or use nuclear fission for power generation. This article describes the coatings used in two basic types of Generation 3 nuclear reactor designs in the United States and their containment size. These reactors are the boiling water reactor (BWR) and pressurized water reactor (PWR). The article provides information on the loss-of-coolant accident (LOCA) identified as the design basis accident (DBA), which can rapidly de-water the core of an operating nuclear reactor. To avoid LOCA, both the BWR and the PWR include emergency core cooling systems. The article describes a DBA test and other coating performance parameters necessary for safety-related coating systems. It provides a detailed account of the selection criteria of coating types in a nuclear plant. The article concludes by highlighting protective coating strategies in Generation 3 Plants.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004220
EISBN: 978-1-62708-184-9
.... This is another factor that needs to be considered whenever the so-called benign environment within the walls of a building is considered. Inorganic Coatings Other forms of coating that are midway between the use of a metallic coating and an organic coating are the inorganic zinc-rich coatings. The life...
Abstract
This article discusses the generic situation of steel reacting with the environments found in structures. Two environments are specifically discussed: atmospheric and cementitious. The article describes the utility of different corrosion protection methods for atmospheric corrosion and cementitious systems. It presents examples of problems that have arisen in the corrosion performance of steel.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... different curing and performance properties. While all four categories can be used for heavy- duty corrosion-resistant coatings, to date, the most commonly used coatings for air-dry maintenance and marine protection are latex-based coatings based on acrylic polymers, and inorganic zinc-rich coatings based...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006072
EISBN: 978-1-62708-172-6
... and maintenance) Table 1 Coating systems for highway bridges (new construction and maintenance) Coating system Highway bridges, new Highway bridges, maintenance 1 (a) Highway bridges, maintenance 2 (b) Inorganic zinc-rich primer/polyamide epoxy/acrylic polyurethane or polyaspartic...
Abstract
This article provides a basic overview of bridge corrosion, where it occurs on steel and concrete bridge structures, and how to prevent corrosion by using coatings. It describes types of bridge designs, with illustrations, and presents information on how corrosion occurs in different bridge zones and areas, with illustrations. The article concludes with a discussion on the common methods of coating systems applications on bridge structures and key elements in coating condition assessment.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003844
EISBN: 978-1-62708-183-2
... the carbon atom, while organic materials do. Coating resins are almost exclusively organic materials. There are some exceptions, notably silicones and silicates, that form the binders for very high-temperature-resistant coatings and inorganic zinc-rich coatings, respectively. The molecular structure...
Abstract
Paints and protective coatings are the most common means of protecting materials from deterioration. This article focuses on coating degradation that results from the environmental interaction with the coatings. The major environmental influences of the degradation include energy (solar radiation, heat and temperature variation, and nuclear radiation), permeation (moisture, solvent retention, chemical, and oxygen), stress (drying and curing, vibration, and impact and abrasion), and biological influences (microbiological and macrobiological).
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003688
EISBN: 978-1-62708-182-5
... of the 55Al-Zn coating is shown in Fig. 8 . The coating has a two-phase microstructure. This is best explained by reference to the aluminum/zinc phase diagram. One phase is the primary aluminum-rich dendritic phase that begins to grow initially during solidification. The other is an interdendritic zinc-rich...
Abstract
This article describes the basic principles, processing steps, and benefits of continuous hot dip coatings. It provides useful information on the principal types of coatings applied in the hot-dip process. The types of coatings include galvanized coatings, galvannealed coatings, 55Al-Zn coating, 95Zn-Al coating, and aluminized coatings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006027
EISBN: 978-1-62708-172-6
... , Corrosion: Fundamentals, Testing, and Protection , Vol 13A , ASM Handbook , ASM International , 2003 , p 817 – 833 • Tator K.B. , Zinc-Rich Coatings , Corrosion: Fundamentals, Testing, and Protection , ASM Handbook , Vol 13A , ASM International , 2003 , p 837 – 844 ...
Abstract
This article provides a brief discussion on the common types of overlayers that can be used on a metal surface to protect it from corrosion. These overlayers include phosphate, chromate, and chromate-free conversion coatings; hot dip galvanizing; cementitious linings; glass and porcelain enamels; electroplating; thermal spray coatings; and rubber linings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006026
EISBN: 978-1-62708-172-6
...: Ref 6 Cyclic Salt Spray ASTM G85, “Standard Practice for Modified Salt Spray (Fog) Testing,” is applicable to ferrous and nonferrous metals as well as organic and inorganic coatings. The variations described in the standard are useful when a different or more corrosive environment than...
Abstract
Independent verification of coating system performance can be based on laboratory testing and/or field exposure. Qualification testing is a critical component to coating system selection. This article focuses on performance evaluations that are used to prequalify coating systems, namely, facility-specific, industry-specific, coating-type-specific, or a combination of these. It describes the standard laboratory tests used to generate performance data, namely, physical, compositional, chemical exposure, and application characteristics tests. The pros and cons of using manufacturer-generated data versus independently generated data are discussed. The article provides information on accelerated corrosion/weathering testing and nuclear level 1/level 2 service coatings qualification. It also describes the procedures for establishing minimum performance requirements and for determining when requalification testing may be required.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004107
EISBN: 978-1-62708-184-9
... of the coated pilings were driven into the bottom of the bay, exposing the column to mud, immersion, tidal, splash and spray, and atmospheric conditions) ( Ref 7 ). The 21 pilings contained coatings including zinc-rich primers with various topcoats, as-deposited flame sprayed zinc, as-deposited flame sprayed...
Abstract
A sacrificial coating applied to a steel substrate can add 20 years or more of life to the substrate, depending on its thickness and composition. Different techniques to apply sacrificial coatings offer various characteristics that contribute to corrosion resistance. This article discusses thermal spray, hotdipping, and electroplating processes used to apply coatings in steel structures. It describes the corrosion attributes of the resulting coatings and discusses the methods of protecting steel from corrosion using aluminum and zinc coatings.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003689
EISBN: 978-1-62708-182-5
... by field welding can be touched in with an organic or inorganic zinc-rich paint. Organic paint does not require a high degree of surface preparation and dries quickly. The paint must have a zinc dust content according to approved standards and should be applied in several coats to a thickness of twice...
Abstract
This article provides a discussion on the two basic steps of the batch hot dip galvanizing process: surface preparation and galvanizing. It describes the factors affecting coating thickness and coating structure. The mechanical properties of the coating and steel substrate are also discussed. The article also provides information on the various factors that should be considered before galvanizing a material. It examines the performances of galvanized coatings in corrosion service. The joining of galvanized structural members by bolting and welding is also discussed. The article describes the synergistic effects of galvanized and painted systems. It explains the applications of hot dip galvanized steel. The article concludes with information on pertinent galvanizing specifications under the authority of the American Society for Testing and Materials.
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