Search Results for indicator electrode

Molten salts, in contrast to aqueous solutions in which an electrolyte (acid, base, salt) is dissolved in a molecular solvent, are essentially completely ionic. This article begins with an overview of the thermodynamics of cells and classification of electrodes for molten salts: reference electrodes and indicator electrodes. It explains that corrosion in molten salts can be caused by the solubility of the metal in the salt, particularly if the metal dissolves in its own chloride. The article describes the factors that affect the corrosion of titanium, namely, the titanium chloride content of the magnesium chloride melt, magnesium or sodium content, and oxygen content of the product. It concludes with a discussion on the oxygen activity in the titanium metal product.

Voltammetry is the study of the current voltage relationships observed when electroactive species in solution are subject to oxidation or reduction at electrodes under carefully controlled conditions. This article describes the basic principle of voltammetry performed using the dropping mercury electrode (polarography). It discusses the various methods of voltammetry, namely, linear sweep voltammetry, cyclic voltammetry, and stripping voltammetry that are carried out with different electrode material. The article also explores the modern instrumentation and developments achieved in voltammetry, and provides an outline of additional data, such as values of the formation, or stability, and constants of complexes formed by shifting the half-wave potential, which can be obtained by voltammetry. Additionally, the article provides a brief account of the applications of voltammetry.

Electrogravimetry is a method used to separate and quantify ions of a substance, usually a metal. Quantification of these ions primarily depends on the rate of movement of charged species (ions) in an electric field. This article details the various types of electrometric titrations, namely, conductometric titration, oscillometric (high frequency) titration, potentiometric titration, amperometric titration, biamperometric titration, bipotentiometric titration, and coulometric titration. It also provides a brief outline of the applications of electrometric titrations.

This article describes various methods of electrochemical analysis, namely coulometry, electrogravimetry, voltammetry, electrometric titration, and nanometer electrochemistry. The discussion covers the general uses, sample requirements, application examples, advantages, and limitations of these methods. Some of the factors pertinent to electrochemical cells are also provided. In addition, the article provides information on various potentiometric membrane electrodes used to quantify numerous ionic and nonionic species.

Potentiometric membrane electrodes are electrochemical devices that can be used to quantify numerous ionic and nonionic species. This class of electrochemical sensors can be divided into ion-selective and gas-sensing membrane electrodes. The first half of this article mainly focuses on the subclasses, the membrane potential, electrode selectivity limitations and the methods of analysis of the ion-selective membrane electrodes. These methods of analysis include the use of calibration curves, addition techniques, subtraction techniques, and titration. The second half outlines gas sensing membrane electrodes, and discusses important elements that must be considered in addition to the potentiometric membrane electrode to ensure proper electrode response. These elements are reference electrodes, temperature controls, recording of the potential with respect to time, electrode storages, and sample pretreatment. The article also explains the applications of the potentiometric membrane electrodes with the aid of an example.

This article contains tables that list standard reduction potentials for electrochemical reactions. The first table lists reactions alphabetically by element of interest. The second table is ranked by potential value. Potential is measured versus the Standard Hydrogen Electrode which has a value of 0.0000 V. Reactions with more than one voltage indicate that results have not been reconciled. Parenthetical materials not needed to balance reactions are catalysts.

Shielded metal arc welding (SMAW), commonly called stick or covered electrode welding, is a manual welding process whereby an arc is generated between a flux-covered consumable electrode and a workpiece. This article discusses the advantages and limitations and applications of the SMAW process and describes the equipment used. It provides information on various coated electrodes used in the SMAW process, including mild and low-alloy steel-covered electrodes, stainless steel covered electrodes, and nickel and copper alloys covered electrodes. It reviews weld schedules and procedures, as well as the variations of the SMAW process. The article concludes with information on the special applications of the SMAW process and safety considerations.

Melting with induction crucible furnaces (ICFs) is a well-established and reliable technology, and their maintenance must be performed at regularly scheduled intervals to ensure safe operation. This article discusses monitoring of the refractory lining, and presents an overview of the various wear-indication methods, namely, manual checks, ground leakage indication, evaluation of electrical values of the furnace, and temperature measurement. It also presents the working principle, physical restrictions, limitations, and remarks on these methods.

This article describes the process, advantages, limitations, applications, and equipment used for shielded metal arc welding (SMAW). It provides information on the types of electrodes, weld schedules, and welding procedures. The article explains the electrodes used in the SMAW process that have different compositions of core wire and a variety of flux-covering types and weights. It includes information on gravity and firecracker welding and discusses dry and wet types of underwater welding. Finally, the article reviews the safety considerations to be followed during SMAW.

The gas-tungsten arc welding (GTAW) process is performed using a welding arc between a nonconsumable tungsten-base electrode and the workpieces to be joined. The arc discharge requires a flow of electrons from the cathode through the arc column to the anode. This article discusses two cases of electron discharge at the cathode: thermionic emission and nonthermionic emission, also called cold cathode, or field emission. It schematically illustrates relative heat transfer contributions to workpiece in the GTAW process. The article provides information on the effects of cathode tip shape and shielding gas composition in the GTAW process.

This article outlines a general approach to develop a coupled electrical-thermal-mechanical analysis for the resistance spot welding process. It provides information on the discretization of sheet-electrode geometry and distribution of contact resistivity along the sheet-sheet and electrode-sheet interfaces. The distribution can be estimated based on the discretized geometry used for the numerical modeling. The article also details the results obtained from this modeling.

Submerged arc welding (SAW) is an arc welding process in which the arc is concealed by a blanket of granular and fusible flux. This article provides a schematic illustration of a typical setup for automatic SAW and discusses the advantages and limitations and the process applications of SAW. The article discusses flux classification relative to production method, relative to effect on alloy content of weld deposit, and relative to basicity index. It describes the procedural variations and the effect of weld current, weld voltage, electrical stickout, travel speed, and flux layer depth on weld bead characteristics. The article concludes with information on weld defects, such as lack of fusion, slag entrapment, solidification cracking, hydrogen cracking, or porosity.

A variety of electrochemical techniques are used to detect and monitor material deterioration in service or in the field. This article describes the static or direct current measurements in a number of applications, including buried pipelines and storage tanks. It reviews the electrochemical impedance spectroscopy and electrochemical noise measurements in a laboratory, especially for the inspection of coatings.

In the flux-cored arc welding (FCAW) process, the heat for welding is produced by an electric arc between a continuous filler metal electrode and a workpiece. This article discusses the advantages and disadvantages and applications of the FCAW process. It schematically illustrates the semiautomatic FCAW equipment used in the gas-shielded FCAW process. The article discusses the manufacture of flux-cored electrodes and the classification of electrodes, such as carbon and low-alloy steel electrodes, stainless steel electrodes, and nickel-base electrodes. The functions of common core ingredients in FCAW electrodes are listed in a table.

This article provides a discussion on the operation of various methods and sensors that have been used or have the potential to be used for on-line, real-time monitoring of localized corrosion. These include the electrochemical noise (ECN) method, nonelectrochemical methods, the galvanically coupled differential flow cell, galvanically coupled crevice cell, coupled multielectrode sensor, and electrochemical biofilm activity sensor.