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Book Chapter
Hydrogen Damage and Embrittlement
Available to PurchaseSeries: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003552
EISBN: 978-1-62708-180-1
... from intergranular fracture ( Ref 6 ). Hydrogen from Preservice Pickling and Electroplating As noted, hydrogen stress cracking can occur from hydrogen pickup from manufacturing. Properly performed pickling alone is not usually a direct cause of hydrogen damage (unless internal voids or other...
Abstract
This article provides an overview of the classification of hydrogen damage. Some specific types of the damage are hydrogen embrittlement, hydrogen-induced blistering, cracking from precipitation of internal hydrogen, hydrogen attack, and cracking from hydride formation. The article focuses on the types of hydrogen embrittlement that occur in all the major commercial metal and alloy systems, including stainless steels, nickel-base alloys, aluminum and aluminum alloys, titanium and titanium alloys, copper and copper alloys, and transition and refractory metals. The specific types of hydrogen embrittlement discussed include internal reversible hydrogen embrittlement, hydrogen environment embrittlement, and hydrogen reaction embrittlement. The article describes preservice and early-service fractures of commodity-grade steel components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also reviewed.
Book Chapter
Hydrogen Damage and Embrittlement
Available to PurchaseSeries: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006784
EISBN: 978-1-62708-295-2
... is particularly pronounced as the yield strength is decreased ( Ref 5 ). Very low-impurity-content steels do show high threshold stress-intensity values and freedom from intergranular fracture ( Ref 6 ). Hydrogen from Preservice Pickling and Electroplating As noted, HSC can occur from hydrogen pickup from...
Abstract
Hydrogen damage is a term used to designate a number of processes in metals by which the load-carrying capacity of the metal is reduced due to the presence of hydrogen. This article introduces the general forms of hydrogen damage and provides an overview of the different types of hydrogen damage in all the major commercial alloy systems. It covers the broader topic of hydrogen damage, which can be quite complex and technical in nature. The article focuses on failure analysis where hydrogen embrittlement of a steel component is suspected. It provides practical advice for the failure analysis practitioner or for someone who is contemplating procurement of a cost-effective failure analysis of commodity-grade components suspected of hydrogen embrittlement. Some prevention strategies for design and manufacturing problem-induced hydrogen embrittlement are also provided.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006283
EISBN: 978-1-62708-169-6
... hydrogen embrittlement mechanical properties quenching scaling solution heat treatment straightening stress-relief anneal titanium titanium alloys TITANIUM ALLOYS are classified into three groups with the following properties: Alpha alloys Non-heat-treatable for significant...
Abstract
This article provides a detailed discussion on heat treatment of titanium alloys such as alpha alloys, alpha-beta alloys, and beta and near-beta alloys. Common processes include stress-relief, annealing, solution treating, aging, quenching, and age hardening. It provides information on the effects of alloying elements on alpha/beta transformation. The article also discusses the heat treating procedures, and the furnaces used for heat treating titanium and titanium alloys.
Book Chapter
Corrosion of Zirconium Alloy Components in Light Water Reactors
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004148
EISBN: 978-1-62708-184-9
..., etc.). It does not impact the corrosion itself, but is involved in one by-product of the corrosion: The hydrogen pickup during corrosion leads to the precipitation of brittle hydrides upon cooling, the platelet orientations of which are controlled by this texture. Corrosion of Zirconium Alloys...
Abstract
The components used in light water reactors (LWR) often remain in contact with the primary coolant, whose typical temperatures and pressures are highly aggressive, therefore, initiating corrosion in most of the alloys. This article describes the corrosion behavior of zirconium alloys in water and heat flow conditions that causes irradiation on the zirconium alloy assemblies. It discusses the effect of irradiation on the microstructure and morphology of cladded linings. The article describes the impact of metallurgical parameters on the oxidation resistance of zirconium alloys. It concludes with a discussion on LWR coolant chemistry and corrosion of fuel rods in reactors.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001463
EISBN: 978-1-62708-173-3
... the hydrogen content Selecting the welding parameters that minimize weld pool hydrogen pickup Designing the weld for minimum stress The use of ferritic-based weld deposits will cause the rejection of large amounts of hydrogen from the weld solidification. The hydrogen will go into the fully...
Abstract
This article discusses the metallurgical aspects of underwater welds. It describes the microstructural development, which mainly includes three types of ferrite associated with low carbon steel weld metal: grain-boundary ferrite, sideplate ferrite, and acicular ferrite. The article explains the factors that affect heat-affected zone (HAZ) cracking. These include hydrogen from the weld pool, microstructures that develop in the HAZ, and stress levels that develop in the weld joint. The article describes the welding practices that can reduce residual stresses. It explains the effect of water pressure on the formation of porosity in underwater gravity welding. The article concludes with a discussion on the practical applications of underwater welding.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001440
EISBN: 978-1-62708-173-3
... the ratio of nitric acid to hydrofluoric acid at 10 to 1 strictly as a factor of safety. If the nitric acid content falls below 30 wt% and the ratio of nitric acid to hydrofluoric acid falls below 10 to 1, excessive hydrogen pickup is possible. Oxide Removal Lightly oxidized joint areas may also...
Abstract
Commercially pure titanium and most titanium alloys can be welded by procedures and equipment used in welding austenitic stainless steel and aluminum. This article describes weldability of unalloyed titanium and all alpha titanium alloys. It reviews the selection of fusion-welding processes that are used for joining titanium and titanium alloys. The processes include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), plasma arc welding (PAW), electron-beam welding (EBW), laser-beam welding (LBW), friction welding (FRW), and resistance welding (RW). The article discusses the role of filler metals and shielding gases in welding titanium and titanium alloys. It describes the equipment used for gas-tungsten arc welding and concludes with information on repair welds.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001432
EISBN: 978-1-62708-173-3
... where the use of excessive arc voltage and active fluxes results in high manganese and/or silicon pickup from the flux (see the section “Submerged Arc Welding” in this article). Fig. 1 Schematic showing location of hydrogen-induced cracks in carbon steel weldments. Source: Ref 1 Cracks...
Abstract
This article discusses the susceptibility of carbon steels to hydrogen-induced cracking, solidification cracking, lamellar tearing, weld metal porosity, and heat-affected zone (HAZ) mechanical property variations. The composition and mechanical properties of selected carbon steels used in arc welding applications are listed in a table. The article presents process selection guidelines for arc welding carbon steels. It provides information on the shielded metal arc welding, gas-metal arc welding, and flux-cored arc welding, gas-tungsten arc and plasma arc welding, submerged arc welding, electrogas welding, electroslag welding, and stud arc welding.
Book Chapter
Surface Engineering of Titanium and Titanium Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001311
EISBN: 978-1-62708-170-2
... toughens the scale and compounds descaling difficulties. An additional problem is that heat-treating furnace atmospheres are maintained on the oxidizing side to prevent hydrogen pickup. A layer of oxygen-rich metal ( Fig. 1 ) develops beneath the resulting scale formation, varying in thickness from 0.05...
Abstract
This article reviews cleaning and finishing operations that have proven to be effective on titanium, its alloys, and semi-fabricated titanium products. It explains how to remove scale, tarnish films, grease, and other soils and how to achieve required finishes and/or improve wear and oxidation resistance through the use of polishing, buffing, and wire brushing operations. The article also covers a wide range of surface modification and coating processes, including ion implantation, diffusion, chemical and physical vapor deposition, plating, anodizing, and chemical conversion coatings as well as sprayed and sol-gel coatings and laser and electron-beam treatments.
Book Chapter
Casting of Copper and Copper Alloys
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005303
EISBN: 978-1-62708-187-0
... used in copper melt treatment are hygroscopic. Damp fluxes can therefore result in hydrogen pickup in the melt from the decomposition of water. External Components Furnace tools such as rakes, puddlers, skimmers, and shovels can deliver hydrogen to the melt if they are not kept clean. Oxides...
Abstract
This article describes the casting characteristics and practices of copper and copper alloys. It discusses the melting and melt control of copper alloys, including various melt treatments to improve melt quality. These treatments include fluxing and metal refining, degassing, deoxidation, grain refining, and filtration. The article provides a discussion on these melt treatments for group I to III alloys. It describes the three categories of furnaces for melting copper casting alloys: crucible furnaces, open-flame furnaces, and induction furnaces. The article explains the important factors that influence the selection of a casting method. It discusses the production of copper alloy castings. The article concludes with information on the gating and feeding systems used in production of copper alloy castings.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004000
EISBN: 978-1-62708-185-6
... alloying elements (including other metals and gases such as oxygen, nitrogen, and hydrogen) stabilizes either the α or β phase. The temperature at which a given titanium alloy transforms completely from α to β is termed the beta transus, β t , and is a critical temperature in titanium alloy forging process...
Abstract
Titanium alloys are forged into a variety of shapes and types of forgings, with a broad range of final part forging design criteria based on the intended end-product application. This article begins with a discussion on the classes of titanium alloys, their forgeability, and factors affecting forgeability. It describes the forging techniques, equipment, and common processing elements associated with titanium alloy forging. The processing elements include the preparation of forging stock, preheating of the stock, die heating, lubrication, forging process, trimming and repair, cleaning, heat treatment, and inspection. The article presents a discussion on titanium alloy precision forgings and concludes with information on the forging of advanced titanium materials and titanium aluminides.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003634
EISBN: 978-1-62708-182-5
.... Shatter Cracks, Flakes, and Fisheyes Shatter cracks, flakes, and fisheyes are features common to hydrogen damage in forgings, weldments, and castings. They are attributed to hydrogen pickup during melting operations when the melt has a higher solubility for hydrogen than the solid alloy. During...
Abstract
Hydrogen damage is a form of environmentally assisted failure that results from the combined action of hydrogen and residual or applied tensile stress. This article classifies the various forms of hydrogen damage and summarizes the theories that seek to explain these types of degradation. It reviews hydrogen degradation in specific ferrous and nonferrous alloys, namely, iron-base alloys, nickel alloys, aluminum alloys, copper alloys, titanium alloys, zirconium alloys, and vanadium, niobium, tantalum, and their alloys. An outline of hydrogen damage in intermetallic compounds is also provided.
Book Chapter
Selection of Wrought Ferritic Stainless Steels
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001409
EISBN: 978-1-62708-173-3
... of niobium and/or titanium to match the carbon, nitrogen, and oxygen contents (intermediate-purity Group III alloys). For these reasons, every precaution must be taken and welding procedures must be selected that optimize gas shielding and cleanliness to avoid pickup of carbon, nitrogen, oxygen, and hydrogen...
Abstract
This article describes the classification of ferritic stainless steels. It reviews the metallurgical characteristics of various ferritic grades as well as the factors that influence their weldability. The article provides a discussion on various arc welding processes. These processes include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), flux-cored arc welding (FCAW), shielded metal arc welding (SMAW), and plasma arc welding (PAW). The selection criteria for welding consumables are discussed. The article also explains the welding procedures associated with the ferritic stainless steels. It concludes with information on weld properties.
Book Chapter
Electroslag Remelting
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005201
EISBN: 978-1-62708-187-0
... … … … … Electrically inefficient; use when oxides are not permissible. 70F/30 70 30 … … … Difficult starting; high conductivity; use when aluminum is not allowed; risk of hydrogen pickup 70F/20/0/10 70 20 … 10 … Good general-purpose slags; medium resistivity 70F/15/0/15 70 15 … 15 … 50F/20...
Abstract
Electroslag remelting (ESR) is commonly used to produce the highest levels of quality in plate steels, particularly in thick plates. This article provides an overview of the ESR and discusses the major components and operations of the ESR furnaces. It describes the principles of ingot solidification and the various defects of remelted ingot such as tree ring patterns, freckles, and white spots. The article explains several variations of ESR such as pressure electroslag remelting, remelting under reduced pressure, and electroslag rapid remelting. It also examines the features of steel ESR and superalloy ESR.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002170
EISBN: 978-1-62708-188-7
... affect beta phase, and thus can greatly affect hydrogen absorption. Etchant temperature and etch rate also affect the rate at which hydrogen is absorbed. Chemical milling process specifications normally specify either a maximum allowable final hydrogen content, or a maximum allowed hydrogen pickup...
Abstract
This article discusses the principal process steps, specifications, defects, applications, advantages, and disadvantages of chemical milling (CM) in aerospace industries. The process steps include precleaning, masking, scribing, etching, final cleaning, stripping, and mechanical finishing. The article describes the variables that affect undercut and surface finish obtained by CM. The mechanical properties of chemically milled parts are also discussed.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003996
EISBN: 978-1-62708-185-6
... are susceptible to hydrogen pickup during reheating operations such that reheating equipment and practices are also critical elements of forging process control. Recommended preheating temperatures vary with alloy and are contained in Table 1 . Heating Equipment Aluminum alloys are heated for forging...
Abstract
This article begins with discussion on forgeability and the factors affecting the forgeability of aluminum and aluminum alloys. It describes the types of forging methods and equipment and reviews critical elements in the overall aluminum forging process: die materials, die design, and die manufacture. The article discusses the critical aspects of various manufacturing elements of aluminum alloy forging, including the preparation of the forging stock, preheating stock, die heating, lubrication, trimming, forming and repair, cleaning, heat treatment, and inspection. It concludes with a discussion on the forging of advanced aluminum materials and aluminum alloy precision forgings.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003175
EISBN: 978-1-62708-199-3
... and damp melting tools, but the primary source of hydrogen is ambient humidity. Because little can be done to prevent hydrogen pickup during melting, hydrogen must be removed from the melt before pouring. The most common method used is bubbling dry nitrogen or argon through the melt. Rotary degassing units...
Abstract
Aluminum alloys are primarily used for nonferrous castings because of their light weight and corrosion resistance. This article discusses at length the melting and metal treatment, structure control, sand casting, permanent mold casting, and die casting of aluminum alloys. It also covers the types and melting and casting practices of copper alloys, zinc alloys, magnesium alloys, titanium alloys, and superalloys, and provides a brief account on the casting technique of metal-matrix composites.
Book Chapter
Corrosion of Zirconium and Zirconium Alloys
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003823
EISBN: 978-1-62708-183-2
...-4 has more iron but no nickel for the purpose of minimizing hydrogen pickup. Both alloys are popular in water-moderated reactors, such as boiling water and pressurized water reactors. The Zr-2.5Nb alloy is used in heavy-water-moderated reactors, such as the Canadian deuterium-uranium reactors...
Abstract
This article provides a description of the classification, industrial applications, microstructures, physical, chemical, corrosion, and mechanical properties of zirconium and its alloys. It discusses the formation of oxide films and the effects of water, temperature, and pH on zirconium. The delayed hydride cracking of zirconium is also described. The article provides information on the resistance of zirconium to various types of corrosion, including pitting corrosion, crevice corrosion, intergranular corrosion, galvanic corrosion, microbiologically induced corrosion, erosion-corrosion, and fretting corrosion. The article explains the effects of tin content in zirconium and effects of fabrication on corrosion. Corrosion control measures for all types of corrosion are also highlighted. The article concludes with information on the safety precautions associated with handling of zirconium.
Book Chapter
Well Casing External Corrosion and Cathodic Protection
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004114
EISBN: 978-1-62708-184-9
... Between differential temperature zones Between brine formations and relatively inert rock Between the well casing and the surface facilities if there is a metallic connection In addition, corrosive gases from a formation, such as carbon dioxide (CO 2 ) and hydrogen sulfide (H 2 S...
Abstract
This article describes two principal methods for detecting well casing corrosion, namely, metal-loss tools and casing current measurement, as well as their limitations and advantages. It discusses the factors to be considered in designing well casing cathodic protection systems. These include the determination of cathodic protection current by the casing polarization and CPP tests or by mathematical models; calculation of casing-to-anode separation; isolation of the casing from other facilities; consideration of stray current interference from other dc power sources; and determination of the size and the location of the anode bed for effective current output for the desired life of the anode bed. The article concludes with a discussion on the commissioning and monitoring of cathodic protection systems.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005345
EISBN: 978-1-62708-187-0
.... Postweld Heat Treatment (PWHT) The calculated CE value, potential for hydrogen pickup, and section thickness of the casting may dictate the need for postweld heat treatment to avoid or minimize the cracking potential. The need to perform this operation may be limited by the conditions under which...
Abstract
Repair welding is a necessary operation for most fabricators and can cost more than the price of the original component if performed improperly. This article provides a discussion on the repair welding of castings for ferrous and nonferrous materials. The discussion focuses on the surface preparation, weld repair process selection, joint selection, filler metal selection, weld repair considerations, deposition techniques, postweld heat treatment, and verification of weld repair quality.
Book Chapter
Titanium and Titanium Alloy Castings
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001082
EISBN: 978-1-62708-162-7
... hydrogen pickup. Hydrogen pickup is more likely the higher the β-phase content of the alloy and is also influenced by etch rate and bath temperature. Subsequent vacuum anneals may be used to remove hydrogen picked up in chemical...
Abstract
The combination of high strength-to-weight ratio, excellent mechanical properties, and corrosion resistance makes titanium the best material choice for many critical applications. This article commences with a description of the historical perspective of titanium casting technology. It discusses the various types of molding methods, namely, rammed graphite molding, and lost-wax investment molding. The article provides information on the casting design, melting, and pouring practices, and describes the microstructure, hot isostatic pressing, heat treatment, and mechanical properties of Ti-6AI-4V alloy. It also talks about the chemical milling and weld repair, and describes the product applications of titanium alloy castings. Tensile properties, standard industry specifications, and chemical compositions of various titanium alloy castings are tabulated.
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