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hot salt attack
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004163
EISBN: 978-1-62708-184-9
..., hot salt attack, and thermal fatigue. The article describes the various forms of corrosion which occur at the cold end of an exhaust system. The forms of cold end exhaust corrosion, including condensate pitting corrosion, exterior salt pitting, crevice corrosion, intergranular corrosion, and galvanic...
Abstract
Steel automotive exhaust systems suffer from various forms of corrosion. This article illustrates exhaust system components with typical upper metal skin temperatures and alloys of construction. It discusses high-temperature corrosion of automotive exhaust systems, including oxidation, hot salt attack, and thermal fatigue. The article describes the various forms of corrosion which occur at the cold end of an exhaust system. The forms of cold end exhaust corrosion, including condensate pitting corrosion, exterior salt pitting, crevice corrosion, intergranular corrosion, and galvanic corrosion.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003821
EISBN: 978-1-62708-183-2
..., and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys...
Abstract
This article reviews the corrosion behavior in various environments for seven important nickel alloy families: commercially pure nickel, Ni-Cu, Ni-Mo, Ni-Cr, Ni-Cr-Mo, Ni-Cr-Fe, and Ni-Fe-Cr. It examines the behavior of nickel alloys in corrosive media found in industrial settings. The corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens, and corrosion by molten salts. Applications where the corrosion properties of nickel alloys are important factors in materials selection include the petroleum, chemical, and electrical power industries. Most nickel alloys are much more resistant than the stainless steels to reducing acids, such as hydrochloric, and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys suffer environmentally assisted cracking are highly specific and therefore avoidable by proper design of the industrial components.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003593
EISBN: 978-1-62708-182-5
...-salt interface, and site II is the salt-gas interface. Source: Ref 15 Historically, it has been demonstrated ( Ref 16 ) that a condensed fused salt film is required for severe hot corrosion attack, and that Na 2 SO 4 vapor in air is innocuous. Researchers ( Ref 17 , 18 , 19 ) showed...
Abstract
Metals and ceramics exposed to high-temperature salt solutions are susceptible to a form of corrosion caused by fused salts accumulating on unprotected surfaces. This article examines the electrochemistry of such hot corrosion processes, focusing on sodium sulfate systems generated by the combustion of fossil fuels. It explains how salt chemistry, including acid/base and oxidizing properties, affects corrosion rates and mechanisms. The article also provides information on electrochemical testing and explains how Pourbaix methods, normally associated with aqueous corrosion, can be used to study fused-salt corrosion.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003609
EISBN: 978-1-62708-182-5
... of aqueous systems. Molten salt systems operate at higher temperatures than aqueous systems, which leads to different forms of corrosion attack. Electrochemical measurements have highlighted these differences between aqueous and molten salt environments, particularly in terms of characterizing...
Abstract
This article discusses two general mechanisms of corrosion in molten salts. One is the metal dissolution caused by the solubility of the metal in the melt. The second and most common mechanism is the oxidation of the metal to ions. Specific examples of the types of corrosion expected for the different metal-fused salt systems are also provided. The metal-fused salt systems include molten fluorides, chloride salts, molten nitrates, molten sulfates, hydroxide melts, and carbonate melts. The article concludes with information on prevention of molten salt corrosion.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003142
EISBN: 978-1-62708-199-3
... Abstract This article discusses corrosion resistance of titanium and titanium alloys to different types of corrosion, including galvanic corrosion, crevice corrosion, stress-corrosion cracking (SCC), erosion-corrosion, cavitation, hot salt corrosion, accelerated crack propagation, and solid...
Abstract
This article discusses corrosion resistance of titanium and titanium alloys to different types of corrosion, including galvanic corrosion, crevice corrosion, stress-corrosion cracking (SCC), erosion-corrosion, cavitation, hot salt corrosion, accelerated crack propagation, and solid and liquid metal embrittlement. A short section discusses the addition of alloys that can improve the corrosion resistance of titanium.
Image
Published: 01 January 2006
Fig. 3 Laminated T304 heat shield where insulation became soaked with salt solution, leading to hot salt intergranular attack. At bottom, cross section. 200×
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003611
EISBN: 978-1-62708-182-5
...; most of the corrosion encountered in turbines burning liquid fuels can be described as type I hot corrosion, which occurs primarily in the metal temperature range of 850 to 950 °C (1550 to 1750 °F). This is a sulfidation-based attack on the hot gas path parts involving the formation of condensed salts...
Abstract
When metal is exposed to an oxidizing gas at elevated temperature, corrosion can occur by direct reaction with the gas, without the need for the presence of a liquid electrolyte. This type of corrosion is referred to as high-temperature gaseous corrosion. This article describes the various forms of high-temperature gaseous corrosion, namely, high-temperature oxidation, sulfidation, carburization, corrosion by hydrogen, and hot corrosion.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004158
EISBN: 978-1-62708-184-9
... and 1700 °F). High-temperature hot corrosion is caused by the formation of alkali metal salts, such as sodium sulfate (Na 2 SO 4 ) and potassium sulfate (K 2 SO 4 ), which melt and form a liquid on the surface. This molten salt attacks the oxide scale, destroying the protection normally afforded...
Abstract
The corrosion issues in the compressor, combustor and turbine sections of industrial gas turbines used in steam production generally depend on the quality of the fuel, air, and water used in the engine than on the specific industrial application. This article focuses on the forms of corrosion and their preventive measures in the compressor, combustor and turbine sections of a steam turbine. The compressor section mainly suffers from aqueous corrosion; while in case of the combustor and turbine sections, which are made of nickel-base superalloys, high-temperature environmental attack in the form of high-temperature oxidation and hot corrosion are predominant. The effect of high-temperature oxidation and hot corrosion on the mechanical properties of superalloys is also discussed.
Image
Published: 15 January 2021
Fig. 25 Effect of p SO 2 on Na 2 SO 4 -induced corrosion at 700 °C (1290 °F). 2.5 ppm atmospheric SO 2 can greatly accelerate hot corrosion over that in clean air conditions. With Na 2 SO 4 salt deposit, the catalyzed O 2 -0.1%SO 2 atmosphere causes accelerated attack at 700 °C by forming
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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003671
EISBN: 978-1-62708-182-5
... of the atmosphere, liquid, or molten salt, the temperature and thermal cycle profiles, the stress states of the materials, fatigue conditions, and the design parameters. The objective for performing a given high- temperature corrosion test should be identified during the initial phase of designing the testing...
Abstract
This article provides information on the thermodynamics and kinetics of high-temperature corrosion. The thermodynamics of high-temperature corrosion reactions reveals what reactions are possible under certain conditions and kinetics explains how fast these possible reactions will proceed. The article describes the diffusion process that plays a key role in oxidation and other gaseous reactions with metals. It discusses the development of stress in oxide layers. The article presents the sample preparation methods for high-temperature testing, and expounds the measurement methods of high-temperature degradation. It reviews a number of potential processes, which are responsible for high-temperature corrosion. The article details a wide range of coatings and coating processes for protecting components in a variety of operating conditions. It also discusses the testing methods used for materials at high temperatures, including furnace tests, burner rig testing, and thermogravimetric analysis, and the test methods conducted at high temperature and high pressure.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003825
EISBN: 978-1-62708-183-2
... Room E Fumes … E Vinegar and salt … … E Water … … E … Hot E Salt … E Sea … E Whiskey … … E (a) E, no attack: V, variable, depending on temperature and concentration; NR, not resistant Most organic salts, gases, alcohols, ketones, alkaloids...
Abstract
Tantalum is one of the most versatile corrosion-resistant metals known. The outstanding corrosion resistance and inertness of tantalum are attributed to a very thin, impervious, protective oxide film that forms on exposure of the metal to slightly anodic or oxidizing conditions. This article provides a discussion on the mechanism of corrosion resistance and on the behavior of tantalum in different corrosive environments, namely, acids; salts; organic compounds; reagents, foods, and pharmaceuticals; body fluids and tissues; and gases. It contains several tables that summarize the effects of acids, salts, and miscellaneous corrosive reagents on tantalum and applications for tantalum equipment in chemical, pharmaceutical, and other industries. Finally, the article presents a discussion on hydrogen embrittlement, the galvanic effects, and cathodic protection of tantalum and describes the corrosion resistance of different types of tantalum-base alloys.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0004050
EISBN: 978-1-62708-183-2
... (fluxing). Hot corrosion appears only at intermediate temperatures determined by the melting point and the dewpoint of the salt ( Ref 11 ). Two forms of hot corrosion are generally recognized in sulfur-containing combustion environments: type I (high temperature) and type II (low temperature). Type I...
Abstract
This article describes the specific features and mechanisms of oxidation in thermal spray coatings. It discusses the two forms of hot corrosion in sulfur-containing combustion, namely high-temperature hot corrosion and low-temperature hot corrosion. The article reviews the behavior of corrosion-resistant coatings in boilers. The effects of high-temperature corrosion in waste incinerators are detailed. The article also examines the effects of erosion-corrosion in fluidized bed combustion boilers.
Series: ASM Handbook
Volume: 11
Publisher: ASM International
Published: 15 January 2021
DOI: 10.31399/asm.hb.v11.a0006787
EISBN: 978-1-62708-295-2
... oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube...
Abstract
High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003587
EISBN: 978-1-62708-182-5
... Abstract Molten salts, or fused salts, can cause corrosion by the solution of constituents of the container material, selective attack, pitting, electrochemical reactions, mass transport due to thermal gradients, and reaction of constituents and impurities of the molten salt with the container...
Abstract
Molten salts, or fused salts, can cause corrosion by the solution of constituents of the container material, selective attack, pitting, electrochemical reactions, mass transport due to thermal gradients, and reaction of constituents and impurities of the molten salt with the container material. This article describes a test method performed using thermal convection loop for corrosion studies of molten salts. It discusses the purification of salts that are used in the Oak Ridge molten salt reactor experiment. The article also reviews the corrosion characteristics of nitrates/nitrites and fluoride salts with the aid of illustrations and equations.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003555
EISBN: 978-1-62708-180-1
... and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay...
Abstract
High temperature corrosion may occur in numerous environments and is affected by factors such as temperature, alloy or protective coating composition, time, and gas composition. This article explains a number of potential degradation processes, namely, oxidation, carburization and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay coatings, thermal barrier coatings, and ceramic coatings.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004162
EISBN: 978-1-62708-184-9
... that can deposit inside fenders and other partially enclosed areas of vehicles. The poultice can accumulate and concentrate road salts and other potentially corrosive substances. Oxygen concentration gradients under and adjacent to the poultice exacerbate attack under the poultice. Figure 3 shows...
Abstract
This article discusses the commonly encountered forms of automotive body corrosion. The corrosion forms include general or uniform corrosion, cosmetic or under-film corrosion, galvanic corrosion, crevice corrosion, poultice or under-deposit corrosion, and pitting corrosion. Corrosion-resistant sheet metals, such as electrogalvanized steel, hot dip galvanized steel, and hot dip galvannealed steel, are reviewed. The article provides information on the paint and sealant systems for corrosion control in automotive body applications.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006349
EISBN: 978-1-62708-179-5
... of 5 or lower, particularly if appreciable velocity is involved. Aeration or oxidizing conditions, such as the presence of metallic salts, result in rapid destructive attack of unalloyed cast irons, even in very dilute HCl solutions. High-nickel austenitic cast irons offer some resistance to all...
Abstract
Cast irons provide excellent resistance to a wide range of corrosion environments when properly matched with that service environment. This article presents basic parameters to be considered before selecting cast irons for corrosion services. Alloying elements can play a dominant role in the susceptibility of cast irons to corrosion attack. The article discusses the various alloying elements, such as silicon, nickel, chromium, copper, and molybdenum, that enhance the corrosion resistance of cast irons. Cast irons exhibit the same general forms of corrosion as other metals and alloys. The article reviews the various forms of corrosions, such as graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. It discusses the four general categories of coatings used on cast irons to enhance corrosion resistance: metallic, organic, conversion, and enamel coatings.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003829
EISBN: 978-1-62708-183-2
... for the bromination of organic materials, but hydrobromic acid (HBr) exposure is limited to room temperature and a maximum of 14% acid. Similarly, silver is restricted to room-temperature exposure in dilute hydroiodic acid (HI). Nitric acid (HNO 3 ) that contains traces of nitrous acid attacks silver vigorously. Hot...
Abstract
This article characterizes the corrosion resistance of precious metals, namely, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold. It provides a discussion on the general fabricability; atomic, structural, physical, and mechanical properties; oxidation and corrosion resistance; and corrosion applications of these precious metals. The article also tabulates the corrosion rates of these precious metals in corrosive environment, namely, acids, salts, and halogens.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004124
EISBN: 978-1-62708-184-9
.... Contamination of combustion fuel in diesel engines can cause high-temperature corrosion. Gas turbine engines are affected by hot corrosion. Refractory-lined incinerators and alloy-lined incinerators are discussed. The article provides case studies for each component failure. boilers diesel engines...
Abstract
High-temperature exposure of materials occurs in many applications such as power plants (coal, oil, natural gas, and nuclear), land-based gas turbine and diesel engines, gas turbine engines for aircraft, marine gas turbine engines for shipboard use, waste incineration, high-temperature fuel cells, and missile components. This article discusses high-temperature corrosion in boilers, diesel engines, gas turbines, and waste incinerators. Boilers are affected by stress rupture failures, waterside corrosion failures, fireside corrosion failures, and environmental cracking failures. Contamination of combustion fuel in diesel engines can cause high-temperature corrosion. Gas turbine engines are affected by hot corrosion. Refractory-lined incinerators and alloy-lined incinerators are discussed. The article provides case studies for each component failure.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003551
EISBN: 978-1-62708-180-1
... are susceptible to attack at low and intermediate temperatures. The normally protective SiO 2 layer that forms on SiC and Si 3 N 4 may explain why such ceramics have a poor corrosion resistance in basic salts. Corrosion resistance of structural ceramics to fused salts, alkalis, and low-melting oxides Table...
Abstract
This article provides a discussion on the structural ceramics used in gas turbine components, the automotive and aerospace industries, or as heat exchangers in various segments of the chemical and power generation industries. It covers the fundamental aspects of chemical corrosion and describes the corrosion resistance characteristics of specific classes of refractories and structural ceramics. The article also examines the prevention strategies that minimize corrosion failures of both classes of materials.
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