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Roland Warzel, III
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Peter A. dePoutiloff, Prasan K. Samal
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Peter A dePoutiloff
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Kalathur S. Narasimhan
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Prasan K. Samal
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Gerhard Leichtfried, John A. Shields, Jr., John L. Johnson
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Leander F. Pease, III, Douglas L. Pease
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Prasan K. Samal
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Animesh Bose, Rajendra Sadangi, Pankaj K. Mehrotra
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Book Chapter
High-Temperature Sintering of Ferrous Powder Metallurgy Components
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006110
EISBN: 978-1-62708-175-7
... Abstract High-temperature sintering of ferrous components continues to be important in the powder metallurgy (PM) industry. Improvements in both production rates and properties are possible as sintering temperatures increase above 1120 deg C. This article provides an overview of the different...
Abstract
High-temperature sintering of ferrous components continues to be important in the powder metallurgy (PM) industry. Improvements in both production rates and properties are possible as sintering temperatures increase above 1120 deg C. This article provides an overview of the different various stages of the sintering process and the physical, chemical, and metallurgical phenomena occur within the mass of metal powder particles. It discusses the four advantages of high-temperature sintering of various ferrous PM materials: improved mechanical properties, improved physical properties, development of liquid phase, and ability to sinter active elements in alloy steels. The article also provides information on three sources of process control requirements, namely, the powder blend, green density, and sintering conditions.
Image
Micrograph of high-temperature sintered 303L stainless steel showing fine M...
Available to PurchasePublished: 30 September 2015
Fig. 7 Micrograph of high-temperature sintered 303L stainless steel showing fine MnS globules within the grains and along the grain boundaries. Glyceregia etch. Source: MPIF
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Image
Temperature profile of sintering cycles. Profile A shows the high-temperatu...
Available to PurchasePublished: 30 September 2015
Fig. 11 Temperature profile of sintering cycles. Profile A shows the high-temperature cycle used in the study. Profile B shows the conventional sintering cycle used as a standard. Source: Ref 5
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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006111
EISBN: 978-1-62708-175-7
... of iron and iron-graphite powder, iron-copper and iron-copper graphite, and alloy steels. The effects of various sinter conditions on the amount of combined carbon formed in the steel are also discussed. The article concludes with information on high-temperature sintering and sinter hardening. alloy...
Abstract
This article provides information on the most frequently used atmospheres in commercial sintering of powder metallurgy iron and steel materials. These include endothermic, exothermic, dissociated ammonia, pure hydrogen, and nitrogen-base atmospheres. The article discusses sintering of iron and iron-graphite powder, iron-copper and iron-copper graphite, and alloy steels. The effects of various sinter conditions on the amount of combined carbon formed in the steel are also discussed. The article concludes with information on high-temperature sintering and sinter hardening.
Book Chapter
Sintering of Stainless Steels
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006118
EISBN: 978-1-62708-175-7
... interparticle bonding, and (c) preventing reoxidation and nitride formation during cooling from sintering temperature. PM stainless steels got their start with “conventional” sintering, i.e. sintering in continuous mesh belt furnaces that utilize high-temperature-grade stainless steel mesh belts, stainless...
Abstract
This article describes the sintering behavior of austenitic, ferritic, and martensitic stainless steels. It presents different sintering schedules that are selected by Metal Powder Industries Federation (MPIF). The article provides information on the equipment and atmospheres used for sintering and the steps involved in the process. It discusses the factors that influence the dimensional changes in sintering, namely, powder-related, compaction-related, and sintering-related factors.
Image
Two stainless steels fabricated by P/M, as demonstrations of the microstruc...
Available to PurchasePublished: 01 January 1996
-density microstructure useful for mechanical components, formed by injection molding and high-temperature sintering. 200×
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Image
Type 304 wrought stainless steel boss sinter brazed to a high-density (7.25...
Available to PurchasePublished: 30 September 2015
Fig. 1 Type 304 wrought stainless steel boss sinter brazed to a high-density (7.25 g/cm 3 ) high-temperature-sintered PM 409L flange. (a) 304L boss in 409L flange. (b) Braze filler paste applied to joint. (c) Braze joint. (d) Braze interface (Kalling's etch) 409L (top), 304L (bottom). Source
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Book Chapter
Secondary Operations for Powder Metallurgy Stainless Steels
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006119
EISBN: 978-1-62708-175-7
... of iron contamination from the surface difficult, because the porosity leads to entrapment of chemicals inside the part. Only the high-density (high-temperature-sintered) parts with non-interconnected surface porosity may be amenable to chemical passivation for improvement of surface corrosion resistance...
Abstract
Powder metallurgy (PM) stainless steels, as with conventional PM steels, are often used in the as-sintered condition. In addition to cost considerations, minimization of postsinter handling and secondary operations is also preferred because it reduces the potential for contamination of the parts with particulates and residues, which can result in the appearance of surface rust. This article provides information on various secondary operations, including tumbling, re-pressing, resin impregnation, annealing or heat treating, brazing, machining, and welding. It describes those aspects relating to welding of PM stainless steels, specifically, the effects of density, residual porosity, and sintered chemistry on weldability. Further, the article investigates the influence the sintering atmosphere has on machinability, as well as differences created by the presence of residual porosity.
Book Chapter
Magnetic Materials and Properties for Powder Metallurgy Part Applications
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006057
EISBN: 978-1-62708-175-7
... selected. Soft magnets should be made of single-phase compositions of high purity. Second phases affect structure-sensitive magnetic properties over time from aging. At high sintering temperatures, iron dissolves carbon and nitrogen. Structure-sensitive properties can appear to be unaffected after...
Abstract
Powder metallurgy (PM) techniques are effective in making magnetically soft components for use in magnetic part applications. This article provides an account of the factors affecting magnetism, permeability, and hysteresis losses. It includes information on the magnetic properties of PM materials that are used in the magnetic part applications, namely, pure iron, phosphorus irons, ferritic stainless steels, 50 nickel-50 iron, and silicon irons. The article describes the factors that affect and optimize magnetic properties. It contains a table that lists the magnetic properties possible in metal injection molding parts. The article also discusses ferromagnetic cores used in alternating current applications and some permanent magnets, such as rare earth-cobalt magnets and neodymium-iron-boron (neo) magnets.
Book Chapter
Mechanical Properties of Powder Metallurgy Stainless Steels
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006120
EISBN: 978-1-62708-175-7
... at temperatures in the vicinity of 1315 °C (2400 °F) leads to further enhancements in dynamic mechanical properties. With these very high sintering temperatures, it is also possible to reduce the sintering time period and realize economic benefits from higher furnace throughput. A high sintering temperature, when...
Abstract
This article describes the factors influencing the room-temperature and elevated-temperature mechanical properties of powder metallurgy (PM) stainless steels. It contains tables that list the mechanical property specifications of the Metal Powder Industries Federation (MPIF) Standard 35.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006135
EISBN: 978-1-62708-175-7
... of a neutral atmosphere is unrelated to temperature. Consequently, neutral atmospheres, unlike endothermic atmospheres, are suitable for high-temperature sintering of steel PM parts. Furthermore, parts with different carbon levels can be sintered in the same tray or in random tray sequence under neutral...
Abstract
Sintering atmosphere protects metal parts from the effects of contact with air and provides sufficient conduction and convection for uniform heat transfer to ensure even heating or cooling within various furnace sections, such as preparation, sintering, initial cooling, and final cooling sections. This article provides information on the different zones of these furnace sections. It describes the types of atmospheres used in sintering, namely, endothermic gas, exothermic gas, dissociated ammonia, hydrogen, and vacuum. The article concludes with a discussion on the furnace zoning concept and the problems that arise when these atmospheres are not controlled.
Book Chapter
Pressing and Sintering of Refractory Metal Powders
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006124
EISBN: 978-1-62708-175-7
... by the passage of a large current through the pressed ingot at temperatures as high as 3000 °C (5430 °F) is still a common technique for sintering AKS-W rods, which are used for wire production. Technically Pure Tungsten The usual sintering atmosphere for tungsten is hydrogen with a dew point lower than 0...
Abstract
This article discusses the pressing and sintering of various refractory metal powders for the production of intermediate products as well as special cases of finished products. The metal powders considered include tungsten, molybdenum, tantalum, niobium and their alloys, as well as rhenium.
Series: ASM Handbook
Volume: 4D
Publisher: ASM International
Published: 01 October 2014
DOI: 10.31399/asm.hb.v04d.a0005971
EISBN: 978-1-62708-168-9
... can occur during compaction. However, this choice causes significant inhomogeneity of composition even after sintering at high temperatures. Densities are usually reported as a pure value (such as g/cm 3 , or lb/in. 3 ) or as a percentage of the theoretical full density, where the difference...
Abstract
Powder metallurgy (PM) processes include press and sinter hardening, metal injection molding, powder forging, hot isostatic pressing, powder rolling, and spray forming. This article provides an overview of PM processing methods and general considerations of heat treatment of PM parts that are case-hardened to obtain higher hardness, wear, fatigue, and impact properties. It describes the effects of porosity on heat treatment, alloy content on PM hardenability, and starting material on homogenization of PM steels. The article describes the properties, following heat treatment, of low-alloy steels tempered at 175 ºC for one hour, and lists recommended quench and temper parameters to achieve good wear resistance and core strength based on different ranges of porosity.
Book Chapter
Pressed-and-Sintered Ferrous Powder Metallurgy Parts
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003112
EISBN: 978-1-62708-199-3
... compaction can increase density levels to 7.2 g/cm 3 to slightly more than 7.4 g/cm 3 (about 95% of theoretical density). High-temperature sintering also produces higher densities. Secondary processes, such as infiltration or double-pressing/double-sintering, can be used to increase densities to levels...
Abstract
Iron powders are the most widely used powder metallurgy (P/M) material for structural parts. This article reviews low to medium density iron and low-alloy steel parts produced by the pressing and sintering technology. It explains different powder production methods, including Hoeganaes process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals with the mechanical and physical properties of ferrous P/M materials, which may depend on certain factors, namely microstructure, porosity, density, infiltration, re-pressing, chemical composition, and heat treatment.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002486
EISBN: 978-1-62708-194-8
... 58 14 (a) Balance N 2 . Source: Ref 4 Warm compaction is used to increase the green density and green strength of P/M steel parts. When combined with high-temperature sintering, this process can provide mechanical properties equivalent to double press-double sinter processing...
Abstract
This article begins with a discussion on general powder metallurgy design considerations that assist in the selection of the appropriate processing method. It reviews powder processing techniques, conventional press-and-sinter methods, and full-density processes to understand the design restrictions of each powder processing method. The article provides comparison of powder processing methods based on their similarities, differences, advantages, and disadvantages. It concludes with a discussion on design issues for the components of powder processing technologies.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006017
EISBN: 978-1-62708-175-7
... chemical vessels commercially France 1822 Platinum powder formed into solid ingot France 1826 High-temperature sintering of platinum powder compacts on a commercial basis Russia 1829 Wollaston method of producing compact platinum from platinum sponge (basis of modern PM technique) England...
Abstract
Powder metallurgy (PM) has been called a lost art. Long before furnaces were developed that could approach the melting point of metal, PM principles were used. This article provides an overview of the major historical developments of various methods of platinum powder production. The development of production methods took place in various phases starting from prehistoric time, post-war period, to recent and commercial period. The article discusses the powder metallurgy of platinum, as well as the commercial and post-war developments of PM. Literature and trade associations are also discussed.
Book Chapter
Metallography and Microstructures of Powder Metallurgy Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003789
EISBN: 978-1-62708-177-1
... source produces high-frequency waves in the room-temperature water bath. The waves strike the beaker and force the alcohol into the pores of the specimen, removing foreign substances. Because the specimen is placed in the alcohol bath, the washing takes place in what soon becomes a contaminated solution...
Abstract
This article provides information on the microstructure of powder metal alloys and the special handling requirements of porous materials. It covers selection, sectioning, mounting, grinding, and polishing, and describes procedures, such as washing, liquid removal, and impregnation, meant to preserve pore structures and keep them open for analysis. The article compares and contrasts the microstructures of nearly 50 powder metal alloys, using them to illustrate the effect of consolidation and compaction methods as well as particle size, composition, and shape. It discusses imaging equipment and techniques and provides data on etchants and etching procedures.
Book Chapter
Corrosion Resistance of Powder Metallurgy Stainless Steels
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006113
EISBN: 978-1-62708-175-7
..., because ferrite is less noble than the austenitic matrix. High-temperature sintering can alleviate the situation to some extent by partially dissolving the contaminants in the matrix. Figure 5 shows the effects of the presence of iron and 410L stainless steel contaminations on the corrosion resistance...
Abstract
This article reviews various test methods used for evaluating the corrosion resistance of powder metallurgy stainless steels. These include immersion testing, salt spray testing, and electrochemical testing. The article discusses the factors that affect corrosion resistance of sintered stainless steels: compaction-related factors, sintering-related factors, and effects of alloy composition. Corrosion resistance data for sintered stainless steels is provided.
Book Chapter
Sintering of Hardmetals
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006069
EISBN: 978-1-62708-175-7
... of the hydrocarbons at elevated temperatures. Typically, semicontinuous furnaces have high throughput, but optimization of the delubing step in the sintering cycle and forced-cooling systems can make batch furnaces competitive. Computer numerical control (CNC) systems are commonly used to run and monitor...
Abstract
This article discusses two major sintering methods: pressureless and pressure-assisted sintering. Pressureless sintering techniques include vacuum and partial-pressure, hydrogen, and microwave sintering. Pressure-assisted consolidation techniques include overpressure sintering, sintering followed by postsinter hot isostatic pressing, hot pressing, and several rapid hot consolidation techniques. The article describes nitrogen sintering and the sintering of cermets. It reviews the furnaces used for sintering and presents the lubrication removal techniques. The article also outlines the need to control carbon and oxygen to obtain optimal properties and explains microstructure development and grain size control.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001105
EISBN: 978-1-62708-162-7
... on the plasticizer used (for example, polystyrene with an admixture of diphenyl and diphenyl-ether), extrusion requires a temperature somewhere between 160 and 175 °C (320 and 350 °F). Slow and complete debinding under vacuum prior to high sintering is critical in order to avoid distortion, cracking...
Abstract
Ceramic-metal composites, or cermets, combine the heat and wear resistance of ceramics with the formability of metals, filling an application niche that includes cutting tools, brake pads, heat shields, and turbine components. This article examines a wide range of cermets, including oxide cermets, carbide and carbonitride cermets, boride cermets, and other refractory types. It describes the powder metallurgy process by which cermets are produced, examining each step from powder preparation to post treatment. It discusses forming and compacting, injection molding, extrusion, rolling, pressing, slip casting, and sintering. It also discusses fundamental concepts such as chemical bonding, chemical composition, microstructure, and the development of physical and mechanical properties.
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