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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001113
EISBN: 978-1-62708-162-7
... Abstract This article focuses on different thin-film deposition techniques used to make superconducting films and discusses the properties and advantages of high-critical-temperature and low-critical-temperature materials in a number of applications, including signal processing and analog...
Abstract
This article focuses on different thin-film deposition techniques used to make superconducting films and discusses the properties and advantages of high-critical-temperature and low-critical-temperature materials in a number of applications, including signal processing and analog electronic devices. The article gives a brief introduction on superconducting materials, substrates and buffer layers and discusses the major deposition techniques such as, electron-beam co-evaporation, sputtering from either a composite target or multiple sources and laser ablation. The article also describes the in-situ film growth techniques for producing atomic oxygen by radio frequency excitation or microwave discharge or with ozone.
Book Chapter
Superconducting Materials
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003155
EISBN: 978-1-62708-199-3
...), ternary molybdenum chalcogenides (Chevrel phases), and high T c ceramic superconductors. Figure 3 compares the critical temperatures for metallic and ceramic superconducting materials. The advantage of the higher T c ceramics is that they can be cooled with liquid nitrogen, which is much cheaper...
Abstract
Superconductors are materials that exhibit a complete disappearance of electrical resistivity on lowering the temperature below the critical temperature. A superconducting material must exhibit perfect diamagnetism, that is, the complete exclusion of an applied magnetic field from the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics.
Book Chapter
High-Temperature Superconductors for Wires and Tapes
Available to PurchaseSeries: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001114
EISBN: 978-1-62708-162-7
... Abstract The discovery of the high-critical-temperature oxide superconductors has accelerated the interest for superconducting applications due to its higher-temperature operation at liquid nitrogen or above and thus reduces the refrigeration and liquid helium requirement. It also permits usage...
Abstract
The discovery of the high-critical-temperature oxide superconductors has accelerated the interest for superconducting applications due to its higher-temperature operation at liquid nitrogen or above and thus reduces the refrigeration and liquid helium requirement. It also permits usage of the high-critical-temperature oxides in magnets or power applications in high-current-carrying wire or tape with acceptable mechanical capability. This article discusses the powder techniques mainly based on the production of an oxide powder precursor, which is then subjected to various processing, including powder-in-tube processing, vapor deposition processing, and melt processing. It further discusses the microstructural, anisotropy and weak link influences on these processes.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001109
EISBN: 978-1-62708-162-7
...-energy balance favors the normal state. Stability of the superconducting state in magnetic fields up to the upper critical magnetic field ( H c2 ) allows type II materials to be exploited for high-magnetic-field applications. Fig. 6 The magnetic flux line lattice predicted by Abrikosov for type...
Abstract
Superconductivity has been found in a wide range of materials, including pure metals, alloys, compounds, oxides, and organic materials. Providing information on the basic principles, this article discusses the theoretical background, types of superconductors, and critical parameters of superconductivity. It discusses the magnetic properties of selected superconductors and types of stabilization, including cryogenic stability, adiabatic stability, and dynamic stability. The article also focuses on alternating current losses in superconductors, including hysteresis loss, penetration loss, eddy current loss, and radio frequency loss. Furthermore, the article describes the flux pinning phenomenon and Josephson effects.
Book Chapter
High-Temperature Sintering of Ferrous Powder Metallurgy Components
Available to PurchaseBook: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006110
EISBN: 978-1-62708-175-7
... Blend The raw material for any PM product (i.e. the starting powder blend) is subject to variations from lot to lot. These variations can be seen in particle morphology, compressibility, apparent density, and segregation of admixed constituents. The two most critical to high-temperature sintering...
Abstract
High-temperature sintering of ferrous components continues to be important in the powder metallurgy (PM) industry. Improvements in both production rates and properties are possible as sintering temperatures increase above 1120 deg C. This article provides an overview of the different various stages of the sintering process and the physical, chemical, and metallurgical phenomena occur within the mass of metal powder particles. It discusses the four advantages of high-temperature sintering of various ferrous PM materials: improved mechanical properties, improved physical properties, development of liquid phase, and ability to sinter active elements in alloy steels. The article also provides information on three sources of process control requirements, namely, the powder blend, green density, and sintering conditions.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001111
EISBN: 978-1-62708-162-7
..., superconductor. Finally, it discusses the applications of A15 superconductors in commercial magnets, power generation, power transmission, high-energy physics, and fusion. A15 superconductors applications of A15 superconductors critical current density layer growth matrix materials multifilamentary...
Abstract
This article reviews the phase diagrams, alloy with third element additions, layer growth, critical current density, and matrix materials of A15 superconductors. It describes the production methods of tape conductors (chloride deposition, and surface diffusion) and multifilamentary wires (rod process, modified jelly roll process, niobium tube process, in-situ process, powder metallurgy process, and jelly roll method). The article focuses on reaction heat treatment, which is required at the end of wire processing to convert the ductile components to the desired, but brittle, superconductor. Finally, it discusses the applications of A15 superconductors in commercial magnets, power generation, power transmission, high-energy physics, and fusion.
Book: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003431
EISBN: 978-1-62708-195-5
... on composite cure tooling that is fabricated from steel, aluminum, or high-temperature composite materials. The quality assurance for commercial applications is reviewed. The article concludes with a discussion on data fusion systems designed to provide nondestructive analysis data from fabrication...
Abstract
This article presents the importance of progressing from post-manufacturing inspection/verification to in-process inspection/verification methods. It lists the various quality assurance factors considered for typical composite laminate lay-up process. The article provides information on composite cure tooling that is fabricated from steel, aluminum, or high-temperature composite materials. The quality assurance for commercial applications is reviewed. The article concludes with a discussion on data fusion systems designed to provide nondestructive analysis data from fabrication and assembly processes for each individual composite part.
Book Chapter
Practical Aspects of Converting Ingot to Billet
Available to PurchaseSeries: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003989
EISBN: 978-1-62708-185-6
..., which is critical to produce uniform strain and prevent buckling of the billet. Some variations of this basic design use self-centering bevels or alignment fixtures to improve the uniformity of the upset. Die Material Depending on the die temperature during forging and the stiffness...
Abstract
This article describes the presses, transportation equipment, and manufacturing processes associated with cogging. It discusses the practical and metallurgical issues encountered during the conversion of ingot to billet. The article explains the use of numerical modeling as part of the continuing efforts to reduce the cost and time associated with developing new cogging sequences, increase the yield, make the processes more robust, and increase the quality of the produced product.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003996
EISBN: 978-1-62708-185-6
... forging configurations than hot-forged carbon and/or alloy steels, reflecting differences in the high-temperature oxidation behavior of aluminum alloys during forging, the forging engineering approaches used for aluminum, and the higher material costs associated with aluminum alloys in comparison...
Abstract
This article begins with discussion on forgeability and the factors affecting the forgeability of aluminum and aluminum alloys. It describes the types of forging methods and equipment and reviews critical elements in the overall aluminum forging process: die materials, die design, and die manufacture. The article discusses the critical aspects of various manufacturing elements of aluminum alloy forging, including the preparation of the forging stock, preheating stock, die heating, lubrication, trimming, forming and repair, cleaning, heat treatment, and inspection. It concludes with a discussion on the forging of advanced aluminum materials and aluminum alloy precision forgings.
Book: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003381
EISBN: 978-1-62708-195-5
... critical only with extreme deviations or specific materials. Many changes in composite performance can be attributed to changes in the final dwell time and temperature, including hygrothermal behavior such as moisture weight gain. The percent weight gain of moisture as a function of cure-cycle final...
Abstract
Hygrothermal behavior of cured composite materials relates to the combined and commonly synergistic effects of moisture absorption and temperature on various physical, chemical and mechanical properties. This article focuses on the influence of resins or matrices, reinforcements, processing, and diffusion on hygrothermal behavior of polymer-matrix composites and provides an outline on general considerations in assessing them. It discusses the hygrothermal testing and conditioning of polymer-matrix composites to assess fundamental hygrothermal behavior. The article provides information on the accelerated aging process for understanding the degradation mechanisms and failure modes in composites. It also describes the effect of moisture absorption on mechanical properties of polymer-matrix composites.
Book: Composites
Series: ASM Handbook Archive
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003478
EISBN: 978-1-62708-195-5
... are tailored to produce a dense material with the required properties. The processes typically include fabricating some type of organic composite preform, heating that preform to high temperature to decompose the organic material to carbon (referred to as carbonization), and then infiltrating the composite...
Abstract
This article presents an overview of the material properties of carbon-carbon composites. It provides information on the applications of carbon-carbon composites in electronic thermal planes, spacecraft thermal doublers, spacecraft thermal shields, spacecraft radiators, and aircraft heat exchangers.
Book Chapter
Introduction to Applications for Thermal Spray Processing
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005732
EISBN: 978-1-62708-171-9
...), and so on Economics, such as material cost, ease of repair, high throughput, and overall life improvements Reliability/robustness of process Component considerations, such as part temperature, geometry, substrate material, coating thickness, and operating environment Performance benefits...
Abstract
This article describes the process of selecting an optimum coating and material system for a specific application. It reviews critical coating functions that influence the coating selection process, and presents some application success stories. The article explores the benefits of thermal spray coatings and functions they provide. It also presents key references from various National Thermal Spray Conference, United Thermal Spray Conference, and International Thermal Spray Conference Proceedings from 2006 through 2012.
Book Chapter
Corrosion in Supercritical Water—Waste Destruction Environments
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004132
EISBN: 978-1-62708-184-9
... materials. In conjunction with the high temperatures (which increase thermal reaction rates), these properties provide a medium in which mixing is fast, organic materials dissolve well and react quickly with oxygen, and salts precipitate ( Ref 2 ). While the products of hydrocarbon oxidation are CO 2 and H...
Abstract
Supercritical water oxidation (SCWO) is an effective process for the destruction of military and industrial wastes including wastewater sludge. This article discusses the unique properties of supercritical water and lists the main technological advantages of SCWO. For many waste streams, corrosion continues to be one of the central challenges to the full development of the SCWO technology. The article presents a summary of selected materials exposed to various environments as well as the observed form of corrosion in a table. It also illustrates the necessity to adopt a synergistic approach incorporating feed chemistry control, reactor design modifications, and intelligent materials selection, for mitigating degradation of SCWO systems.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006916
EISBN: 978-1-62708-395-9
..., immediately followed by packing and holding it under pressure until the gate seal has taken place. Maintaining sufficient pressure on the melt as it cools and solidifies is extremely critical, due to the high volumetric shrinkage of plastic material. If adequate packing pressure is not maintained, the molded...
Abstract
This article focuses on manufacturing-related failures of injection-molded plastic parts, although the concepts apply to all plastic manufacturing processes It provides detailed examples of failures due to improper material handling, drying, mixing of additives, and molecular packing and orientation. It also presents examples of failures stemming from material degradation improper use of metal inserts, weak weld lines, insufficient curing of thermosets, and inadequate mixing and impregnation in the case of thermoset composites.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006255
EISBN: 978-1-62708-169-6
... desirable if the molybdenum sheet or rod will be further fabricated or machined. However, if the material is used in a high-temperature application, the recrystallized structure will be determined by the material thermomechanical history. For this reason, the amount of deformation and use of intermediate...
Abstract
This article briefly discusses the annealing practices for refractory metals such as tungsten, molybdenum, niobium, tantalum, and rhenium and their alloys. It also presents the applications and properties of these metals and their alloys.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003543
EISBN: 978-1-62708-180-1
... temperatures • Cyclic stress exceeded the endurance limit of the material• Check for proper strength, surface finish, assembly, and operation• Prior damage by mechanical or corrosion modes may have initiated cracking• Alignment, vibration, balance• High cycle low stress: large fatigue zone; low cycle high...
Abstract
Overload failures refer to the ductile or brittle fracture of a material when stresses exceed the load-bearing capacity of a material. This article reviews some mechanistic aspects of ductile and brittle crack propagation, including a discussion on mixed-mode cracking, which may also occur when an overload failure is caused by a combination of ductile and brittle cracking mechanisms. It describes the general aspects of fracture modes and mechanisms. The article discusses some of the material, mechanical, and environmental factors that may be involved in determining the root cause of an overload failure. It also presents examples of thermally and environmentally induced embrittlement effects that can alter the overload fracture behavior of metals.
Book Chapter
Fracture Toughness and Fracture Mechanics
Available to PurchaseSeries: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003305
EISBN: 978-1-62708-176-4
... behavior. By knowing the critical value of K I at failure ( K c , K Ic , or K Id ) for a given material of a particular thickness and at a specific temperature and loading rate, the designer can determine flaw sizes that can be tolerated in structural members for a given design stress level...
Abstract
The fracture-mechanics technology has significantly improved the ability to design safe and reliable structures and identify and quantify the primary parameters that affect structural integrity of materials. This article provides a discussion on fracture toughness of notched materials by explaining the ductile-to-brittle fracture transition and by correlating KId, KIc, and Charpy V-notch impact energy absorptions. It highlights the effects of constraint, temperature, and loading rate on the fracture transition. The article discusses the applications of fracture mechanism in limiting of operating stresses. It describes the mechanisms, testing methods, and effecting parameters of two main categories of fracture mechanics: linear-elastic fracture mechanics and elastic-plastic fracture mechanics. The article concludes with a discussion on the three major progressive stages of fatigue: crack initiation, crack growth, and fracture on the final cycle.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001112
EISBN: 978-1-62708-162-7
... nearly two decades ago ( Ref 1 ). This is essentially due to the originality of the materials and to the possible applications of some of them as high field superconductors (that is, >20 T, or 200 kG). For almost ten years, several research teams have been trying to fabricate high critical current...
Abstract
Ternary molybdenum chalcogenides stands for a vast class of materials, whose general formula is MxMO6X8, where, M is a cation and X is a chalcogen (sulfur, selenium, or tellurium). Possible applications of some of these are as high field superconductors (that is, >20 T, or 200 kG). This article discusses the fabrication methods of PbMo6S8 (PMS) and SnMo6S8 (SMS), including hot processing and cold processing. It provides a short note on the superconducting properties of PMS wire filaments and their applications in processes requiring high magnetic fields, such as high-energy physics, thermonuclear fusion, and nuclear magnetic resonance.
Book Chapter
Thermal Spray Technology Growth in Gas Turbine Applications
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005737
EISBN: 978-1-62708-171-9
... operating near their strength (design) limits, and material development is presently at a point of minimal return relative to the cost of research. Turbine inlet temperatures and the temperature capabilities of high-temperature alloys have increased by approximately 500 and 220 °C (900 and 400 °F...
Abstract
This article provides an overview of key thermal spray coatings used in compressors, combustors, and turbine sections of a power-generation gas turbine. It describes the critical components, including combustors, transition ducts, inlet nozzle guide vanes, and first-stage rotating airfoils. Design requirements are reviewed and compared between aerospace and power generation coatings. Application process improvement areas are also discussed as a method of reducing component cost.
Book Chapter
Thermal Spray Applications in the Steel Industry
Available to PurchaseBook: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005742
EISBN: 978-1-62708-171-9
... an important role in the production of steel. Product quality begins during raw material production and continues with shape forming and product sizing in a continuous flow. This continuous production flow requires tooling to withstand high metal melting temperatures and pressures and to have excellent...
Abstract
Thermal spray is an important surface-modification process implemented by the steel industry. This article reviews thermal spray materials and equipment used and also provides examples of where typical coated components result in improved performance. It contains a table that lists thermal spray applications in the iron-steel manufacturing industry.
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