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high purity titanium
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Published: 01 December 2004
Fig. 31 High-purity (iodide-process) unalloyed titanium sheet, cold rolled, and annealed 1 h at 700 °C (1290 °F). Equiaxed, recrystallized grains of alpha. Etchant: Kroll's reagent (ASTM 192). 250×
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Published: 01 January 1996
Fig. 7 S - N curves ( R = −1) in unalloyed titanium. (a) Effect of grain size. (b) Effect of oxygen content. (c) Effect of cold work. HP-Ti is high-purity titanium with oxygen equivalent ( O eq ) defined in Ref 4 . Source: Ref 4 and Metals Handbook , 9th Ed., Vol 3, 1980, p 376
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Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006282
EISBN: 978-1-62708-169-6
... Table 1 Resolved shear stress for slip in titanium as a function of purity Oxygen plus nitrogen, % Slip plane Resolved shear stress MPa ksi 0.01 10 1 0 14 2 0001 62 9 0.10 10 1 0 90 13 10 1 1 97 14 0001 107 15.5 In high-purity titanium, 1010 slip...
Abstract
This article provides an in-depth treatment on the deformation and recrystallization of titanium alloys. It provides information on the predominant mode of plastic deformation that occurs in titanium in terms of the most common crystallographic planes. The article explains the relationship of the recovery process to the recrystallization, grain-growth process, and the effects of time and temperature on stress relief. It describes the factors that influence the rate of recrystallization and the conditions required for neocrystallization to occur. The article explains the mechanism of strain hardening and its effects on the mechanical properties of titanium alloys. It also discusses the factors that influence the superplasticity of titanium alloys.
Image
Published: 01 January 1986
Fig. 3 γ-ray spectrum of a neutron-irradiated high-purity nickel sample. The spectrum, recorded in the time interval 3 to 8 min after a 20-s irradiation, shows the presence of titanium, manganese, and vanadium in the sample.
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001409
EISBN: 978-1-62708-173-3
... inert gas should be used to protect the weld joint or seam (back side included) to minimize oxidation and the pickup of nitrogen. Titanium-stabilized alloys appear to be more resistant to the effects of nitrogen pickup due to poor shielding than are the high-purity alloys. This is apparently due...
Abstract
This article describes the classification of ferritic stainless steels. It reviews the metallurgical characteristics of various ferritic grades as well as the factors that influence their weldability. The article provides a discussion on various arc welding processes. These processes include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), flux-cored arc welding (FCAW), shielded metal arc welding (SMAW), and plasma arc welding (PAW). The selection criteria for welding consumables are discussed. The article also explains the welding procedures associated with the ferritic stainless steels. It concludes with information on weld properties.
Image
Published: 01 January 1993
Fig. 17 Notch toughness of a gas-tungsten arc welded high-purity ferritic stainless steel (6 mm, or 1 4 in., thick E-Brite 26-1 plate) versus a titanium-stabilized alloy (3 mm, or 1 8 in., thick 26-1 Ti plate). Source: Ref 17
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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001115
EISBN: 978-1-62708-162-7
... has been purified to the 99.9999% level using this method. This purity is required for the manufacture of semiconducting gallium arsenide, which is used in light-emitting diodes and as substrates for high-speed digital and monolithic microwave integrated circuits. Additional information is available...
Abstract
The electronic microcircuit industry has placed severe demands on metal suppliers to provide metals of the highest reproducible purity attainable as a result of the constant quest for the true values of physical and chemical properties of metals. This article describes the commonly used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio test methods used to characterize purity. Tables list the values for resistance ratios of zone-refined metals and their corresponding chemical compositions, and provide an example of the detection of impurities to concentrations in the parts per billion range, utilizing a combination of the glow discharge mass spectroscopy method and Leco combustion methods.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006136
EISBN: 978-1-62708-175-7
... production via direct powder rolling can be advantageous over the ingot based processing route. Retention of Purity Level of Powder In some cases, the powder form of the metal may have a high level of purity. The employment of direct powder rolling would offer benefits in terms of maintaining...
Abstract
Direct powder rolling (DPR) is a process by which a suitable powder or mixture of powders is compacted under the opposing forces of a pair of rolling mill rolls to form a continuous green strip that is further densified and strengthened by sintering and rerolling. This article discusses the basic principle, process considerations, and advantages of DRP, and describes the application of this process in the manufacture of powder titanium and titanium alloy components. It further illustrates the complexity of the process and describes the benefits of using DRP in terms of economics and product quality.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003141
EISBN: 978-1-62708-199-3
... affect the final properties of mill products. Melting in a vacuum reduces the hydrogen content of titanium and essentially removes other volatiles. This tends to result in high purity in the cast ingot. However, anomalous operating factors such as air leaks, water leaks, arc-outs, or even large...
Abstract
Titanium metal passes through three major steps during processing from ore to finished product: reduction of titanium ore to sponge (porous form), melting of sponge and scrap to form ingot, and remelting and casting into finished shape. This article describes primary fabrication, including all operations that convert ingot into general mill products, such as billet, bar, plate, sheet, strip, tube, and wire. The section on secondary fabrication describes processes such as die forging, extrusion, hot and cold forming, machining, chemical milling, and joining. The article presents a short note on powder metallurgy products of titanium. Casting processes and properties are covered in the final section.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005204
EISBN: 978-1-62708-187-0
... Alloying during remelting Almost no refining; costly electrode preparation; melting dangerous Good refining; economical feedstock preparation and ingot production; most often used High melting costs Zirconium, titanium … Not used Very low contamination; wide range of alloying possible; large...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003143
EISBN: 978-1-62708-199-3
... of degrading properties, but overall immunity is not ensured by using the high-purity alloy. Ti-5Al-2.5Sn should never come in contact with liquid oxygen. General Corrosion Behavior Similar to grades 2 and 3 of unalloyed titanium. The standard alloy and its high-purity modification (Ti-5Al-2.5Sn-ELI...
Abstract
This article is a comprehensive collection of properties, compositions, and applications of standard grades of titanium and selected titanium alloys. It provides data regarding the common names, Unified Number System numbers, composition limits, typical uses with service temperatures, precautions in use, and general corrosion behavior of each. The applications of titanium alloys include aerospace, gas turbine engines and prostheses. Further, the article graphically presents a comparative study of fatigue, creep and tensile properties of various titanium alloys.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006648
EISBN: 978-1-62708-213-6
... of pure titanium 57–59 Determination of impurity elements in precious metals such as platinum, palladium, silver, and gold 55, 60–63 Analysis of bulk high-purity silicon for photovoltaic applications 64, 65 Analysis of semiconductors related to specific materials such as ZnO, LiF:Mg,Cu,P, La/B...
Abstract
This article provides a brief account of glow discharge mass spectrometry (GDMS) for direct determination of trace elements in solid samples and for fast depth profiling in a great variety of innovative materials. It begins by describing the general principles of GDMS. This is followed by a discussion on the various components of a GDMS system as well as commercial GDMS instruments. A description of processes involved in specimen preparation and cleaning in GDMS is then presented. Various problems pertinent to multielemental calibrations in GDMS are discussed along with measures to overcome them. The article further provides information on the processes involved in the analytical setup of parameters in GDMS, covering the steps involved in the analysis of GDMS data. It ends with a section on the application and interpretation of GDMS in the metals industry.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001110
EISBN: 978-1-62708-162-7
... titanium sponge. The sponge is then consolidated by arc melting in a water-cooled copper crucible. Titanium cannot be effectively purified by melting because its vapor pressure is too high and its melting point too low for selective evaporation of most impurities. It is the purity of the niobium, therefore...
Abstract
Niobium-titanium alloys (NbTi) became the superconductors of choice in the early 1960s, providing a viable alternative to the A-15 compounds and less ductile alloys of niobium-zirconium. This can be attributed to the relative ease of fabrication, better electrical properties, and greater compatibility with copper stabilizing materials. This article discusses the ramifications of design requirements, selection criteria and processing methods of superconducting fibers and matrix materials. It provides information on the various steps involved in the fabrication of superconducting composites, including assembly, welding, isostatic compaction, extrusion, wire drawing, twisting, and final sizing. The article also provides a detailed account of the properties and applications of NbTi superconducting composites.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005205
EISBN: 978-1-62708-187-0
... that portions of the small liquid pool at the cathode tip are ejected into the material being melted. The high melting point of tungsten can result in inclusions in the product; such defects are not tolerable in high-strength metals such as titanium alloys and superalloys for aircraft applications...
Abstract
Plasma melting is a material-processing technique in which the heat of thermal plasma is used to melt a material. This article discusses two typical design principles of plasma torches in the transferred mode: the tungsten tip design and the hollow copper electrode design. It describes the sources of atmospheric contamination in plasma melting furnaces and their control measures. The equipment used in plasma melting furnaces are also discussed. The article provides a detailed discussion on various plasma melting processes, such as plasma consolidation, plasma arc remelting, plasma cold hearth melting, and plasma casting.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003358
EISBN: 978-1-62708-195-5
... particles are a lower-cost alternative most commonly used for casting applications. Titanium carbide is being investigated for high-temperature applications. Table 1 lists the mechanical and physical properties of various ceramic reinforcements commonly used in the manufacture of modern DRMMC materials...
Abstract
This article focuses on the production of particulate reinforcements that are used in discontinuously reinforced metal-matrix composite (DRMMC) materials systems, their physical and materials properties, and the particle shape and overall morphology. The most common DRMMC materials systems used for aerospace structural applications are silicon carbide and boron carbide particulate reinforcement in an aluminum alloy matrix. The article concludes with information on reinforcement chemistry for designing DRMMC materials systems.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005887
EISBN: 978-1-62708-167-2
... the form (cast shape or ingot). Wrought Aluminum Alloys 1<italic>xxx</italic> Series—Super- and Commercial-Purity Aluminum Non-heat-treatable alloys containing at least 99.0% Al. Other significant elements are iron and silicon. General properties: High thermal and electrical conductivities...
Abstract
This article focuses on the temperature requirements of typical nonferrous metals and their alloys of commercial importance. These include aluminum, copper, magnesium, and titanium. The article describes the thermoelectricity, photoelectricity, and capacity of aluminum alloys. In addition, it provides information on the electrical properties of copper and its alloys. The article also lists typical physical and mechanical properties of aluminum alloys at ambient temperature.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001440
EISBN: 978-1-62708-173-3
... ). For complex weld geometries, rigid or collapsible plastic bags purged and filled with inert gas (usually argon) may be used. For welds with high chemical purity requirements, the use of vacuum weld chambers is recommended. Fig. 1 Setup for inert gas shielding for GTAW of titanium alloys outside...
Abstract
Commercially pure titanium and most titanium alloys can be welded by procedures and equipment used in welding austenitic stainless steel and aluminum. This article describes weldability of unalloyed titanium and all alpha titanium alloys. It reviews the selection of fusion-welding processes that are used for joining titanium and titanium alloys. The processes include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), plasma arc welding (PAW), electron-beam welding (EBW), laser-beam welding (LBW), friction welding (FRW), and resistance welding (RW). The article discusses the role of filler metals and shielding gases in welding titanium and titanium alloys. It describes the equipment used for gas-tungsten arc welding and concludes with information on repair welds.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003155
EISBN: 978-1-62708-199-3
... phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics. A15 superconductors high-temperature superconductors niobium-titanium...
Abstract
Superconductors are materials that exhibit a complete disappearance of electrical resistivity on lowering the temperature below the critical temperature. A superconducting material must exhibit perfect diamagnetism, that is, the complete exclusion of an applied magnetic field from the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006087
EISBN: 978-1-62708-175-7
... and hydrogen) were operating temporarily in the United States for the production of high-purity copper powder. In its simplest form, copper cementation recovers copper from acidic dump leach solutions as an impure powder precipitate. Due to the presence of significant amounts of iron and silicates, low...
Abstract
This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition. Methods such as precipitation from salt solution and gas, chemical embrittlement, hydride decomposition, and thermite reactions are also discussed. The article also discusses the methods used to produce powders electrolytically and the types of metal powders produced. The physical and chemical characteristics of these powders are also reviewed.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001430
EISBN: 978-1-62708-173-3
...Abstract Abstract This article discusses the weldability characteristics of cobalt-base corrosion-resistant (CR) alloys, titanium-base CR alloys, zirconium-base CR alloys, and tantalum-base CR alloys that assist in the selection of suitable alloy and welding method for producing high-quality...