Search Results for heavy metal impurities

This article discusses the effects of heavy metal impurities, environmental factors, the surface condition (such as as-cast, treated, and painted), and the assembly practice on the corrosion resistance of a magnesium or a magnesium alloy part. It provides information on stress-corrosion cracking and galvanic corrosion of magnesium alloys, as well as the surface protection of magnesium assemblies achieved by inorganic surface treatments.

Refractory metals are typically processed from powders into ingots that are subsequently swaged into round bars or rolled into plates. Secondary operations are required to fabricate more complex refractory metal components. This article discusses two such secondary operations, namely, machining and joining processes for tungsten, tungsten heavy alloys, molybdenum, tantalum, niobium, and rhenium components. It describes the various types of metal joining processes, including mechanical fastening, brazing, and welding.

Rare earth metals belong to Group IIIA of the periodic table that includes scandium, yttrium, and the lanthanide elements which are lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. This article classifies the rare earth metals based on their purity level, which are designated as research grades (>99.8% pure) and commercial grades (95% - 98% pure), and describes the preparation and purification, including solid-state electrolysis. It further discusses physical, mechanical, and chemical properties; electronic configurations; crystal structures, and explains the alloy forming characteristics of rare earth elements. The article concludes by describing the various applications of commercial-grade rare earth elements and commercial alloys, which incorporates rare earth elements as additives.

Gold electroplating was invented in 1840. During the first 100 years electrodeposited gold was used primarily for its aesthetic appeal as a decorative finish. This article provides a description of the gold plating process and the electrolytes used. It discusses the decorative and industrial applications of gold plating. The article reviews factors affecting the dragout of gold solution.

Zirconium and its alloys are available in two general categories: commercial grade and reactor grade. This article discusses the welding processes that can be used for welding any of the zirconium alloys. These include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), plasma arc welding (PAW), electron-beam welding (EBW), laser-beam welding (LBW), friction welding (FRW), resistance welding (RW), resistance spot welding (RSW), and resistance seam welding (RSEW). The article reviews the selection of shielding gases and filler metals for welding zirconium alloys. It concludes with a discussion on process procedures for welding zirconium alloys.

A significant amount of the worldwide demand for metals is met with recycled materials acquired by metal producers in the form of purchased scrap. This article focuses primarily on the methods and technology used to process and repurpose the vast amounts of purchased scrap that recirculate in the industrial supply chain. It describes the U.S. market for iron and steel scrap, providing information on scrap use by industry, factors influencing demand, and the purchased scrap supply. Iron and steel recycling is discussed separately from stainless steel and superalloy recycling in this article, as the scrap industry treats them differently. The scrap processing of iron involves collection, separation and sorting, size reduction and compaction, detinning, blending, and incineration. The recycling of stainless steels and superalloys follows the same process, but requires several additional steps, including secondary nickel refining, degreasing, and separation of metallurgical wastes.

Very high density materials are used for such applications as counterweights and radiation shields. This article focuses on the metallurgy, processing, properties, fabrication, design considerations, health and safety considerations, and applications of the most commonly used very high density materials: depleted uranium and tungsten and their alloys.

This article focuses on the recycling of metals including iron and steel, stainless steel, superalloys, nickel, aluminum, copper, precious metals, lead, magnesium, tin, titanium, and zinc. It provides information on the identification and sorting of scrap metals and discusses the equipment and procedures used for small-scale and large-scale scrapping operations.

This article addresses the problems of designing isolated heavy sections that are functionally essential. It describes the two most efficient solutions to these problems over which the designer has control: providing flow and feed paths and reducing the mass of the isolated sections. The article concludes with a discussion on designs that reduce the mass of a remote section.

Copper alloys are widely used as electroplated coatings. They can also be used with practically any substrate material that is suitable for electroplating. This article focuses on the solution composition and operating conditions for brass and bronze plating solutions. It describes the decorative and engineering applications of brass and bronze plating. The article also provides information on the treatment of waste water from brass and bronze plating operations.

Zirconium, hafnium, and titanium are produced from ore that generally is found in a heavy beach sand containing zircon, rutile, and ilmenite. This article discusses the processing methods of these metals, namely, liquid-liquid separation process, distillation separation process, refining, and melting. It also discusses the primary and secondary fabrication of zirconium and hafnium and its alloys. The article talks about the metallurgy of zirconium and its alloys with emphasis on allotropic transformation, cold work and recrystallization, anisotropy and preferred orientation, and the role of oxygen. It concludes by providing useful information on the applications of reactor and industrial grades of zirconium alloys.

This article discusses the methods for producing powder metallurgy (PM) nickel powders, including carbonyl process, hydrometallurgical process, hydrogen reduction process, and atomization process, as well as their applications. It describes three processes for producing nickel alloy powders: water atomization, high-pressure water atomization, and gas atomization. The article also provides information on the applications of PM hot isostatic pressing in the oil and gas industry.

This article discusses the general characteristics, primary and secondary fabrication methods, product forms, and corrosion resistance of zirconium and hafnium. It describes the physical metallurgy of zirconium and its alloys, providing details on allotropic transformation and anisotropy that profoundly influences the engineering properties of zirconium and its alloys. Tables listing the values for chemical composition and tensile properties for nuclear and nonnuclear grades of zirconium are also provided.

Commercial zinc plating is accomplished by a number of distinctively different systems: cyanide baths, alkaline noncyanide baths, and acid chloride baths. This article focuses on the composition, advantages, disadvantages, operating parameters, and applications of each of the baths. It provides information on the control of thicknesses of zinc specified for service in various indoor and outdoor atmospheres and on the similarities between cadmium and zinc plating.

Rutherford backscattering spectrometry (RBS) is a major materials characterization technique that can provide information in a short analysis time. It is used for quantitative compositional analysis of thin films, layered structures, or bulk materials and to measure surface impurities of heavy elements on substrates of lighter elements. This article focuses on RBS and its principles, such as collision kinematics, scattering cross section, and energy loss. It describes the channeling effect and the operation of the RBS equipment. The article also provides information on the applications of RBS.

This article describes the control of alloy composition and impurity levels in die casting of zinc alloys based on agitation, use of foundry scrap, and melt temperature and fluxing. It reviews the process considerations for the melt processing of the zinc alloys. The process considerations include the usage of furnaces and launder system, scrap return, inclusions in zinc alloys, fluxing of zinc alloys, and galvanizing fluxes. The article discusses the materials and lubricant selection, casting and die temperature control, and trimming process used in hot chamber die casting for zinc alloys. It also reviews other casting processes for zinc alloys, such as sand casting, permanent mold casting, plaster mold casting, squeeze casting, and semisolid casting.

Ion implantation involves the bombardment of a solid material with medium-to-high-energy ionized atoms and offers the ability to alloy virtually any elemental species into the near-surface region of any substrate. This article describes the fundamentals of the ion implantation process and discusses the advantages, limitations, and applications of ion implantation. It also reviews a typical medium current semiconductor implanter adapted for implantation of metals with the aid of illustrations.

This article briefly discusses the annealing practices for refractory metals such as tungsten, molybdenum, niobium, tantalum, and rhenium and their alloys. It also presents the applications and properties of these metals and their alloys.

This article provides a detailed account of the basic concepts of Rutherford backscattering spectrometry (RBS). It begins with a description of the principles of RBS, as well as the effect of channeling in conjunction with backscattering measurements and the effect of energy loss under this condition. This is followed by a section on equipment used in RBS analysis. Channel-energy conversion, energy-depth conversion, and separation of the dechanneling background are then discussed as the main steps of RBS data analysis. The article also discusses the applications of RBS—including composition of bulk samples, thin-film composition and layer thickness, impurity profiles, damage depth profile, and surface peak—as well as the various codes developed to simulate it.

In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article focuses on the key factors contributing to corrosion of electronic components, namely, chemicals (salts containing halides, sulfides, acids, and alkalis), temperature, air (polluted air), moisture, contact between dissimilar metals in a wet condition, applied potential differences, and stress. It discusses the chip corrosion and oxidation of tin and tin-lead alloys (solders) in SIC. The article also addresses the corrosion of the device terminations resulting in lead (termination) tarnishing that are caused by various factors, including galvanic corrosion, chemical residues, base metal migration and plating additives.