Porcelain enamels are glass coatings applied primarily to products or parts made of sheet steel, cast iron, and aluminum to improve appearance and to protect the metal surface. This article describes the types of porcelain enamels, and details enamel frits for these materials. It provides a list of steels suitable for porcelain enameling and discusses the most important factors considered in the selection of steel for porcelain enameling. The article briefly presents the preparation methods of these materials for porcelain enameling and covers the methods, and furnaces of porcelain enameling. It examines the role of coating thickness, firing time and temperature, metal substrate, and color on the performance of enameled surfaces. The article concludes with a discussion on the properties of enameled surfaces, factors considered in process control, and test procedures for evaluating the quality of enameled surfaces.

Quenching and partitioning (Q&P) steel is a term used to describe a series of C-Si-Mn, C-Si-Mn-Al, or other steels subjected to the quenching and partitioning heat treatment process. This article discusses the Q&P steel's chemical compositions and mechanical properties, and provides an overview of the important background and product characteristics with a focus on the automotive sheet steel application. It schematically represents the continuous annealing process, consequent phase-transformation behaviors, and forming-limit curves of Q&P steels. The article describes the parameters associated with resistance spot welding, laser welding, and metal active gas welding. It also provides useful information of retained austenite volume fraction measured by x-ray diffraction and electron backscatter diffraction. The article also examines microstructure evolution during tensile testing at different strain levels using electron backscatter diffraction.

This article discusses the characteristics, composition limits, and classification of wrought tool steels, namely high-speed steels, hot-work steels, cold-work steels, shock-resisting steels, low-alloy special-purpose steels, mold steels, water-hardening steels, powder metallurgy tool steels, and precision-cast tool steels. It describes the effects of surface treatments on the basic properties of tool steels, including hardness, resistance to wear, deformation, and toughness. The article provides information on fabrication characteristics of tool steels, including machinability, grindability, weldability, and hardenability, and presents a short note on machining allowances.

Ultrahigh-strength steels are designed to be used in structural applications where very high loads are applied and often high strength-to-weight ratios are required. This article discusses the composition, mechanical properties, processing, product forms, and applications of commercial structural steels capable of a minimum yield strength of 1380 MPa (200 ksi). These include medium-carbon low-alloy steels, such as 4340, 300M, D-6a and D-6ac steels; medium-alloy air-hardening steels, such as HI1 modified steel and H13 steel; high fracture toughness steels, such as HP-9-4-30, AF1410, and AerMet 100 steels; and maraging steels.

Intensive quenching (IQ) is an alternative method of hardening steel parts, providing extremely high cooling rates within the martensite-phase formation temperature range. This article begins with the description on the general correlation between steel mechanical properties and cooling rate during IQ. It presents a review of batch intensive quenching (IQ-2) methods and single-part intensive quenching (IQ-3) methods as well as practical applications of these methods. The article provides useful information on the effect of heat flow on cooling in these methods, and discusses the improvements achieved in part microstructure, mechanical properties, and stress conditions of steel, after intensive quenching. It also describes the reasons for part distortion in IQ, and reviews the types of quench systems used in IQ-2 and IQ-3 processes.

Austenitization refers to heating into the austenite phase field, during which the austenite structure is formed. This article highlights the purpose of austenitization, and reviews the mechanism and importance of thermodynamics and kinetics of austenite structure using an iron-carbon binary phase diagram. It also describes the effects of austenite grain size, and provides useful information on controlling the austenite grain size using the thermomechanical process.

The properties of irons and steels are linked to the chemical composition, processing path, and resulting microstructure of the material. For a particular iron and steel composition, most properties depend on microstructure. Processing is a means to develop and control microstructure, for example, hot rolling, quenching, and so forth. This article describes the role of these factors in both theoretical and practical terms, with particular focus on the role of microstructure. It lists the mechanical properties of selected steels in various heat-treated or cold-worked conditions. In steels and cast irons, the microstructural constituents have the names ferrite, pearlite, bainite, martensite, cementite, and austenite. The article presents four examples that have very different microstructures: the structural steel has a ferrite plus pearlite microstructure; the rail steel has a fully pearlitic microstructure; the machine housing has a ferrite plus pearlite matrix with graphite flakes; and the jaw crusher microstructure contains martensite and cementite.

This article discusses the processes involved in continuous hotdip coating of steel sheets, namely, hot and cold line processing, surface preparation, and post treatment. It outlines the properties and microstructures of metals and their alloys used in this process. The coatings considered in this article include metal coatings, such as zinc coatings, and alloy coatings, such as zinc-iron, types 1 and 2 aluminum, Zn-5AI, Zn-55AI, and lead-tin coatings.

Proper sectioning of the surface to be examined is a very important step in preparing steel specimens. The first step in preventing damage to the metallurgical structure is to minimize the amount of sectioning that is done. This article discusses the various metallographic techniques, namely mounting, grinding, polishing, and etching involved in the microstructural analysis of carbon and alloy steels, case hardening steels, cast iron, ferrous powder metallurgy alloys, wrought and cast stainless steels, tool materials, steel castings, iron-chromium-nickel heat-resistant casting alloys and different product forms of steels.

Thread rolling is a cold-forming process for producing threads or other helical or annular forms by rolling the impression of hardened steel dies into the surface of a cylindrical or conical blank. Methods that use cylindrical dies are classified as radial infeed, tangential feed, through feed, planetary, and internal. This article focuses on the capabilities, limitations, and machines used for these methods. It describes the three characteristics, such as rollability, flaking, and seaming, used in evaluating and selecting metals for thread rolling. The article explores the factors affecting die life and explains the effect of thread form on processing. It provides information on various fluids used in thread rolling to cool the dies and the work and to improve the finish on the rolled products. The article provides a comparison between thread rolling and cutting, as well as between thread rolling and grinding.

Hardenability is usually the single most important factor in the selection of steel for heat-treated parts. The hardenability of steel is best assessed by studying the hardening response of the steel to cooling in a standardized configuration in which a variety of cooling rates can be easily and consistently reproduced from one test to another. These include the Jominy end-quench test, the carburized hardenability test, and the surface-area-center hardenability test. This article discusses the effects of varying carbon content as well as the influence of different alloying elements on hardenability of steels. The basic information needed before a steel with adequate hardenability can be specified as the as-quenched hardness required prior to tempering to final hardness that will produce the best stress-resisting microstructure; the depth below the surface to which this hardness must extend; and the quenching medium that should be used in hardening.

Hardenability is a composition-dependent property of steel and depends on carbon content and other alloying elements as well as the grain size of the austenite phase. This article provides an overview of a wide range of testing procedures used to determine and quantify hardenability of shallow-hardening, low-carbon, plain carbon, and low-alloy medium-carbon steels ranging from classical fracture and etching, Grossmann hardenability, and Jominy end-quench testing to manual and computerized computational methods. The article then uses this as a backdrop for the implementation of the core concepts of hardenability in a variety of predictive tools for calculating hardenability. The Caterpillar 1E0024 Hardenability Calculator, a personal computer-based program, calculates the Jominy curve based on the steel composition. The article also describes the method for boron and nonboron steels, with calculation examples for 8645 steel and 86B45 steel.

Case hardening is defined as a process by which a ferrous material is hardened in such a manner that the surface layer, known as the case, becomes substantially harder than the remaining material, known as the core. This article discusses the equipment required, process variables, carbon and hardness gradients, and process procedures of different types of case hardening methods: carburizing (gas, pack, liquid, vacuum, and plasma), nitriding (gas, liquid, plasma), carbonitriding, cyaniding and ferritic nitrocarburizing. An accurate and repeatable method of measuring case depth is essential for quality control of the case hardening process and for evaluation of workpieces for conformance with specifications. The article also discusses various case depth measurement methods, including chemical, mechanical, visual, and nondestructive methods.

All tool steels are heat treated to develop specific combinations of wear resistance, resistance to deformation or breaking under loads, and resistance to softening at elevated temperature. This article describes recommended heat treating practices, such as normalizing, annealing, austenitizing, quenching, preheating, and tempering commonly employed in certain steels. These are water-hardening tool steels, shock-resisting tool steels, oil-hardening cold-work tool steels, medium-alloy air-hardening cold-work tool steels, high-carbon high-chromium cold-work tool steels, hot-work tool steels, high-speed tool steels, low-alloy special-purpose tool steels, and mold steels. The article presents tables that list the temperature ranges, holding time, and hardness values for all of these heat treating processes.

Hardenability of steel depends on carbon content and other alloying elements as well as on the grain size of the austenite phase. This article provides information on the calculation of high-carbon (carburized) steel hardenability. It contains tables that list multiplying factors that are used for the calculation of case hardenability of carburizing steels and the hardenability of high-carbon steels hardened after a prior normalize or quench treatment. The article reviews the derivation and limitations of multiplying factors.

Inverse hardening a steel of adequate hardenability requires a workpiece of sufficiently large cross section, an appropriate cooling medium, and the right quenching conditions. This article explains the Temperature Gradient Quenching Analysis System (TGQAS), which can measure, record, and evaluate all quenching processes in common use, describing their heat extraction dynamics by corresponding thermodynamic functions. It discusses the metallurgical aspects of steels with an emphasis on two different processes, namely, heat extraction (a thermodynamic process) and microstructural transformation (a metallurgical process) that are initiated at the moment when the austenitized workpiece is immersed in the quenchant. The article describes the uses of polyalkylene glycol copolymer and the effect of hardness and fatigue resistance on AISI 4140 type steel.

Flame hardening is a heat treating process in which a thin surface shell of a steel part is heated rapidly to a temperature above the critical temperatures of the steel. The versatility of flame-hardening equipment and the wide range of heating conditions obtainable with gas burners, often permit flame hardening to be done by a variety of methods. These include the spot or stationary method, progressive method, spinning method, and the combination progressive-spinning method. This article provides information on fuel gases used in flame hardening and their selection criteria for specific applications. It also discusses operating procedures and control requirements for flame hardening of steel.

Successful hardening depends on the hardenability of steel composition, the geometry of parts, the quenching system, and on the heat treating process used. This article provides a brief overview of the computation and use of quench factor analysis (QFA) to quantify as-quenched hardness for carbon and low-alloy steels. As a single-value parameter alternative to Grossmann H-values, QFA is a potential method to qualify a quenching medium or process or to effectively monitor variation of quench severity due to either the quenchant or the system. The article describes the procedures for experimentally determining the quench factors by using a type 304 austenitic stainless steel probe. Typical examples of the utilization of QFA for quenchant characterization are provided. The article also describes the methods for experimentally generating time-temperature-property curves.