Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. This article describes surface hardening of gray irons by flame and induction heating. It provides information on the classification of the gray irons in ASTM specification. The article presents examples that illustrate the use of stress relieving to eliminate distortion and cracking. It describes the three annealing treatments of gray iron: ferritizing annealing, medium (or full) annealing, and graphitizing annealing. The article discusses the parameters of the tensile strength and hardness of a normalized gray iron casting. These include combined carbon content, pearlite spacing, and graphite morphology. The article concludes with a discussion on the induction hardening of gray iron castings.

The term cast iron designates a group of materials that contain more than one constituent in their microstructure due to excess carbon that result in unique characteristics such as the fracture appearance and graphite morphology. This article discusses the classification of cast iron and the various metallurgical aspects, such as the composition, alloying element, solidification, and graphite morphologies, of different types of cast iron. It describes the physical properties for various cast irons and the influence of microstructure and chemical composition on each property. The article provides a detailed account on thermal properties, conductive properties, magnetic properties, and acoustic properties of cast iron. It also examines heat treatment, namely, stress relieving, annealing, normalizing, through hardening, and surface hardening. The article presents a discussion on the welding, machining and grinding, and coating of the types of cast iron.

This article discusses the chemical composition, castability, mechanical properties at room temperature and elevated temperature, and physical properties of compacted graphite (CG) cast iron. The change in graphite morphology from the flake graphite (FG) in the base iron to the CG in the final iron is achieved by liquid treatment with different minor elements. CG irons have strength properties close to those of spheroidal graphite (SG) irons, at considerably higher elongations than those of FG iron, and with intermediate thermal conductivities. The main factors affecting the mechanical properties of CG irons both at room temperatures and at elevated temperatures are composition, structure (nodularity and matrix), and section size. The article also discusses the applications of CG irons that stem from their relative intermediate position between FG and SG irons. The tables in the article list the values for tensile properties, hardness, thermal conductivity, fatigue strengths, endurance ratios, and compressive properties of CG, FG, and SG irons.

The solidification of hypoeutectic cast iron starts with the nucleation and growth of austenite dendrites, while that of hypereutectic iron starts with the crystallization of primary graphite in the stable system or cementite in the metastable system. This article begins with a discussion on the nucleation and growth of austenite dendrites. It describes the nucleation of lamellar graphite, spheroidal graphite, and austenite-iron carbide eutectic. The article reviews three main graphite morphologies crystallizing from the iron melts during solidification: lamellar (LG), compacted or vermicular (CG), and spheroidal. It discusses the metastable solidification of austenite-iron carbide eutectic and concludes with information on gray-to-white structural transition of cast iron.

Compacted graphite iron (CGI) invariably includes some nodular (spheroidal) graphite particles, giving rise to the definition of the microstructure in terms of percent nodularity. This article discusses the graphite morphology and mechanical and physical properties of CGI. The mechanical and physical properties of CGI with ferritic and pearlitic matrix structures are summarized in a table. The article describes the standards for CGI, with the definition of the grades based on the minimum tensile strength. It also provides information on the applications of compacted graphite iron castings.

Metallographic techniques for ductile irons are similar to those for other cast irons but more difficult than for steels, because graphite retention is a challenging task. This article presents recommended procedures to prepare ductile irons. It discusses three contemporary approaches for preparing ductile cast iron specimens with a wide range of phases and constituents as well as variations in graphite morphologies. A wide variety of matrix microstructures can be obtained in ductile irons. Examples are presented using a variety of etchants. Control of the nodularity of graphite in ductile irons is critical to their performance. The article presents details concerning the characterization of the graphite nodules.

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. The heat treatment of gray irons can considerably alter the matrix microstructure with little or no effect on the size and shape of the graphite achieved during casting. This article provides a detailed account of classes of gray iron, and heat treating methods of gray irons with examples. These methods include stress relieving, annealing, normalizing, transformation hardening, austenitizing, quenching, austempering, martempering, flame hardening, induction hardening, and nitriding.

This article reviews the graphite morphology, chemical composition requirements, castability, mechanical properties, and corrosion resistance of compacted graphite (CG) irons. It describes the factors affecting the mechanical properties of CG irons. The article also presents the advantages of CG irons.

This article discusses the fatigue and fracture behavior of various types of cast iron, such as gray iron, ductile iron, malleable iron, compacted graphite iron, and white iron, as a function of chemical composition, matrix microstructure, and graphite morphology.

Cast irons have been widely used by engineers in applications that require low cost, excellent castability, good damping capacity, ease of machining, and wear resistance. This article discusses the classification of wear for cast irons: adhesive wear, abrasive wear, and erosive wear. Typical wear applications for a variety of cast iron grades are listed in a table. The article reviews the general wear characteristics of gray irons, compacted graphite (CG) irons, and ductile irons. It discusses the typical compositions and properties of white and chilled iron castings. Gray cast iron is the dominant material for both brake drums and disk brake rotors. The article reviews brake lining chemistry effects, graphite morphology effects, and external abrasive effects on brake drums. It concludes with information on cast iron grinding balls.

This article discusses the graphite morphology, chemical composition, mechanical and physical properties, and applications of compacted graphite (CG) irons. It compares the selected properties of gray, ductile and CG irons, and lists their property requirements as per ASTM A 842. A listing of tensile properties of various CG irons produced by different melt treatment methods is also provided.

The International Committee of Foundry Technical Associations has identified seven basic categories of casting defects: metallic projections, cavities, discontinuities, defective surfaces, incomplete casting, incorrect dimension, and inclusions or structural anomalies. This article presents some of the common defects in each of the seven categories in a table. It discusses common defects determined during the examination of samples of ductile cast iron in Elkem's research facility in Norway. The article reviews common defects, such as shrinkage cavities, blowholes, hydrogen pinholes, nitrogen defects, and abnormal graphite morphology, found in gray iron. It concludes with a discussion on surface defects in compacted graphite iron.

This article presents typical wear applications for a variety of cast iron grades in a table. In general, wear is classified according to three major types: adhesive (frictional) wear (sliding and rolling) caused by contact of one metallic surface with another; abrasive wear caused by contact with metallic (shots, swarf) or nonmetallic abrasive materials; and erosive wear. The article discusses general wear characteristics of gray iron, compacted gray iron, and ductile iron. It provides information on the brake lining chemistry effects, graphite morphology effects, normal cast iron wear, local cast iron wear, and external abrasive effects on brake drums and disk brake rotors made of gray cast iron. The article concludes with a discussion on the application of cast iron for grinding balls.