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Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004001
EISBN: 978-1-62708-185-6
... Abstract This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing...
Abstract
This article reviews the bulk deformation processes for various aluminide and silicide intermetallic alloys with emphasis on the gamma titanium aluminide alloys. It summarizes the understanding of microstructure evolution and fracture behavior during thermomechanical processing of the gamma aluminides with particular reference to production scaleable techniques, including vacuum arc and cold-hearth melting, isothermal forging, conventional hot forging, and extrusion. The selection and design of manufacturing methods, in the context of processing-cost trade-offs for gamma titanium aluminide alloys, are also discussed.
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in Modeling and Simulation of Cavitation during Hot Working
> Fundamentals of Modeling for Metals Processing
Published: 01 December 2009
Fig. 21 Micrographs of (a) an orthorhombic titanium aluminide alloy that failed in tension by flow localization (Source: Ref 63 ) and (b) a near-gamma titanium aluminide alloy that failed in tension by fracture (cavitation) (Source: Ref 64 )
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Published: 01 January 2005
Fig. 2 Portion of the binary titanium-aluminum phase diagram of interest in the processing of near-gamma and single-phase gamma titanium aluminide alloys. Source: Ref 46
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Published: 01 January 2005
Fig. 13 Comparison of measured and predicted equiaxed alpha grain-growth kinetics for a near-gamma titanium aluminide alloy annealed in the alpha + gamma phase field. Source: Ref 46
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in Modeling and Simulation of Cavitation during Hot Working
> Fundamentals of Modeling for Metals Processing
Published: 01 December 2009
Fig. 2 Measured cavity volume fraction (C v ) as a function of axial strain from tension testing of a gamma titanium aluminide alloy. The test temperature was 1000 °C, and the strain rate was 10 −4 s −1 . Source: Ref 18
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Published: 01 June 2024
Fig. 2 SEM fractograph of a solidification crack in a spot weld on a gamma titanium aluminide alloy. Cracking occurred in the fusion zone of the spot weld. The exposed, rounded, dendritic surfaces are indicative of fracture following an interdendritic path and occurring prior to complete
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003164
EISBN: 978-1-62708-199-3
... (Ni3Al and NiAl), iron aluminides (Fe3Al and FeAl) and titanium aluminides (alpha-2 alloys, orthorhombic alloys, and gamma alloys). alloying effects corrosion resistance crystallographic data fabrication iron aluminides mechanical properties nickel aluminides processing of aluminides...
Abstract
Alloys based on ordered intermetallic compounds constitute a unique class of metallic material that form long-range ordered crystal structures below a critical temperature. Aluminides, a unique class of ordered intermetallic materials, possesses many attributes like low densities, high melting points, and good high-temperature strength that make them an attractive material for high-temperature structural application. This article discusses the properties, chemical composition, corrosion resistance, processing, fabrication, alloying effects and crystallographic data of nickel aluminides (Ni3Al and NiAl), iron aluminides (Fe3Al and FeAl) and titanium aluminides (alpha-2 alloys, orthorhombic alloys, and gamma alloys).
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003971
EISBN: 978-1-62708-185-6
... rolling or cold drawing, however. Titanium-aluminide alloys based on the face-centered tetragonal (fct) gamma phase (TiAl) represent a second type of aluminide material for which significant progress has been made toward commercialization. The gamma-titanium aluminide alloys have a number...
Abstract
Metalworking is one of the three major technologies used to fabricate metal products. This article tabulates the classification of metal forming processes. It discusses different types of metalworking equipment, including rolling mills, ring-rolling machines, and thread-rolling and surface-rolling machines. The article outlines the significant characteristics of pressing-type machines: load and energy characteristics, time-related characteristics, and accuracy characteristics. It summarizes different specialized processes such as advanced roll-forming methods, equal-channel angular extrusion, incremental forging, and microforming. The article describes the thermomechanical processing of nickel- and titanium-base alloys and concludes with information on the advancements in process simulation.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001416
EISBN: 978-1-62708-173-3
... consist primarily of the titanium aluminides alpha-2 and gamma, as well as the orthorhombic plus beta types of alloys. The aluminides, as shown on the titanium-aluminum phase diagram of Fig. 1 , consist of two alloy families: alpha-2, which is based on the Ti 3 Al intermetallic, and gamma, which is based...
Abstract
This article focuses on the physical metallurgy and weldability of four families of titanium-base alloys, namely, near-alpha alloy, alpha-beta alloy, near-beta, or metastable-beta alloy, and titanium based intermetallics that include alpha-2, gamma, and orthorhombic systems.
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005421
EISBN: 978-1-62708-196-2
... correspond to a gamma titanium aluminide alloy tested in tension at a temperature of 1000 °C and a strain rate of 10 −4 s −1 . The slope of the fitted line equals η APP ( Ref 18 ). Simulations of cavity growth with continuous nucleation have led to the delineation of the difference between η APP and η...
Abstract
This article focuses on the modeling and simulation of cavitation phenomena. It summarizes the experimental observations of cavitation and reviews the modeling of cavity nucleation and growth. The article discusses the modeling of the cavity growth based on mesoscale and microscale under uniaxial versus multiaxial tensile-stress conditions. Mesoscale models incorporate the influence of local microstructure and texture on cavitation. The article outlines the descriptions of cavity coalescence and shrinkage. It also describes the simulation of the tension test to predict tensile ductility and to construct failure-mechanism maps.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004000
EISBN: 978-1-62708-185-6
... aluminide(s) based on the compound TiAl (or γ, gamma), an ordered tetragonal allotropic form For more discussion of the alloy design and physical metallurgy of alpha-two and gamma titanium aluminide alloys, the reader is referred to the article “Wrought Titanium and Titanium Alloys” in Properties...
Abstract
Titanium alloys are forged into a variety of shapes and types of forgings, with a broad range of final part forging design criteria based on the intended end-product application. This article begins with a discussion on the classes of titanium alloys, their forgeability, and factors affecting forgeability. It describes the forging techniques, equipment, and common processing elements associated with titanium alloy forging. The processing elements include the preparation of forging stock, preheating of the stock, die heating, lubrication, forging process, trimming and repair, cleaning, heat treatment, and inspection. The article presents a discussion on titanium alloy precision forgings and concludes with information on the forging of advanced titanium materials and titanium aluminides.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001102
EISBN: 978-1-62708-162-7
... and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides...
Abstract
Ordered intermetallic compounds based on aluminides and silicides constitute a unique class of metallic materials that have promising physical and mechanical properties for structural applications at elevated temperatures. This article provides useful information on mechanical and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides.
Book: Fractography
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.a0007037
EISBN: 978-1-62708-387-4
... of a solidification crack in a spot weld on a gamma titanium aluminide alloy. Cracking occurred in the fusion zone of the spot weld. The exposed, rounded, dendritic surfaces are indicative of fracture following an interdendritic path and occurring prior to complete solidification. Source: Ref 3 Figure 3...
Abstract
This article provides an overview of fractography as it applies to metal weldments and presents examples of various fracture surface morphologies to demonstrate how fractographic analysis can be used to determine the cause of weld failures. It identifies weld fractography principles and details several weldment-specific geometric and metallurgical considerations. The role of the weld-cracking mechanisms on the resultant fracture surfaces is described, along with example micrographs and fractographs of weldments. Common discontinuities related to welding processes and their impact on the resulting fracture behavior and surfaces are covered, as well as the common fractographic features related to fatigue failures of welds.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0009002
EISBN: 978-1-62708-185-6
... grains in the presence of stable second-phase gamma particles in a gamma titanium aluminide alloy is illustrated in Fig. 13 ( Ref 46 ). Fig. 13 Comparison of measured and predicted equiaxed alpha grain-growth kinetics for a near-gamma titanium aluminide alloy annealed in the alpha + gamma phase...
Abstract
This article reviews the general aspects of microstructure evolution during thermomechanical processing. The effect of thermomechanical processing on microstructure evolution is summarized to provide insight into the aspect of process design. The article provides information on hot working and key processes that control microstructure evolution: dynamic recovery, static recovery, recrystallization, and grain growth. Some of the key phenomenological descriptions of plastic flow and microstructure evolution are also summarized. The article concludes with a discussion on the modeling of microstructure evolution.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003140
EISBN: 978-1-62708-199-3
..., and advanced titanium alloys (titanium-matrix composites and titanium aluminides). physical metallurgy titanium alloys application titanium aluminides titanium-matrix composites TITANIUM is a low-density element (approximately 60% of the density of iron) that can be highly strengthened...
Abstract
Titanium and its alloys are used in various applications owing to its high strength, stiffness, good toughness, low density, and good corrosion resistance. This article discusses the applications of titanium and titanium alloys in gas turbine engine components, aerospace pressure vessels, optic-system support structures, prosthetic devices, and applications requiring corrosion resistance and high strength. It explains the effects of alloying elements in titanium alloys as they play an important role in controlling the microstructure and properties and describes the secondary phases and martensitic transformations formed in titanium alloy systems. Information on commercial and semicommercial grades and alloys of titanium is tabulated. The article also discusses the different grades of titanium alloys such as alpha, near-alpha alloys, alpha-beta alloys, beta alloys, and advanced titanium alloys (titanium-matrix composites and titanium aluminides).
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003728
EISBN: 978-1-62708-177-1
.... Recina V. and Nilson D. , Gamma Titanium Aluminides , Kim Y.-W. , Dimiduk D.M. , and Loretto M.H. , 1999 , TMS , 1999 , p 447 53. Christodoulou L. , International Workshop on Gamma Alloys, The Univ. of Birmingham , 1–3 May 1996 54. Larson D.E...
Abstract
This article describes the development of heat-resistant titanium-base alloys and their classification into several microstructure categories based on their strengthening mechanisms. It explains the phase transformation in titanium-aluminum-base alloys and two peritectic reactions that take place in the titanium-aluminum system. The article also describes two approaches for controlling the orientation of the high-temperature alpha phase to achieve the required lamellar orientation by directional solidification in order to improve the strength and ductility of titanium-aluminum alloys. One approach is by seeding the alpha phase in the alloys, and the other is without seeding, by controlling the solidification path of alloys through appropriate alloying. The article discusses the grain refinement technique used to improve the ductility of cast titanium-aluminum alloys to a level of above 1" at room temperature and reasonable room temperature ductility in the as-cast condition. Finally, it provides information on the microstructures produced through various near-net shape manufacturing processes.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006253
EISBN: 978-1-62708-169-6
... to this system have resulted in α 2 aluminides having useful engineering properties. In alloys with substitutional levels of aluminum content (<8%), the strength level of titanium is greatly increased by aluminum ( Fig. 4 ). The ductility is excellent up to 8% Al, where apparently a sufficient amount...
Abstract
This article introduces the different types, distinctions, and grades of commercially pure titanium and titanium alloys. It describes three types of alloying elements: alpha stabilizers, beta stabilizers, and neutral additions. The article discusses the basic categories of titanium alloys, namely, alpha and near-alpha titanium alloys, beta and near-beta titanium alloys, and alpha-beta titanium alloys. It also describes the general microstructural features of titanium alloys.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003371
EISBN: 978-1-62708-195-5
... to derive substantial strengthening and stiffening at ambient and elevated temperatures (Ref 8 , 9 , and 10 ). While Ti-6Al-4V and Ti-15V- 3Cr-3Sn-3Al have been used commonly for MMC applications, other alloys, such as titanium aluminides, were also considered with specific objectives. The alloy Ti-6Al...
Abstract
Metallic matrices are essential constituents for the fabrication of metal-matrix composites (MMCs). This article describes three different classes of aluminum alloys, namely, commercial aluminum alloys, low-density and high-modulus alloys, and high temperature alloys. It presents typical tensile properties and fracture toughness of the selected heat treatable aluminum alloys in a table. Titanium alloys are very attractive for MMC applications, due to their higher strength and temperature capability compared to aluminum alloys. The article tabulates the effect of heat treatment on room-temperature properties and tensile properties of Ti-25Al-17Nb alloy sheet.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002473
EISBN: 978-1-62708-194-8
... in providing oxidation protection. Other high-temperature materials described include nickel and titanium aluminide intermetallics, refractory metals, and ceramics. Additional information on the oxidation resistance of other structural alloys, including chromia-forming ferrous alloys for industrial...
Abstract
Alloys intended for use in high-temperature environments rely on the formation of a continuous, compact, slow-growing oxide layer for oxidation, and hot corrosion resistance. This article focuses on the issues related to high-temperature oxidation of superalloys used in gas turbine engine applications. It discusses the general methodologies used to evaluate oxidation resistance of materials. The article describes the performance characteristics of superalloys, single-crystal superalloys, and other high-temperature materials such as refractory metals and ceramics. It discusses hot corrosion of superalloys and airfoil degradation due to deposits resulting from ingested particles or sand. The article concludes with a discussion on the limitations of testing techniques and life prediction.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003517
EISBN: 978-1-62708-180-1
... are exposed to elevated temperatures for long times. Typical metallurgical instabilities for turbine blades include carbide coarsening, gamma-prime formation, and hot corrosion. For steel alloys used for tubes and piping, carbide spheroidization and coalescence, sigma-phase formation, sensitization...
Abstract
This article focuses on the life assessment methods for elevated-temperature failure mechanisms and metallurgical instabilities that reduce life or cause loss of function or operating time of high-temperature components, namely, gas turbine blade, and power plant piping and tubing. The article discusses metallurgical instabilities of steel-based alloys and nickel-base superalloys. It provides information on several life assessment methods, namely, the life fraction rule, parameter-based assessments, the thermal-mechanical fatigue, coating evaluations, hardness testing, microstructural evaluations, the creep cavitation damage assessment, the oxide-scale-based life prediction, and high-temperature crack growth methods.
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