No-bake sand molds are based on the curing of inorganic or organic binders with either gaseous catalysts or liquid catalysts. This article reviews the major aspects of no-bake sand bonding in terms of coremaking, molding methods, and sand processing. It discusses the points to be noted in handling sand-resin mixtures for no-bake molds or cones and lists some advantages of no-bake air-set cores and molds. The article describes the process procedures, advantages, and disadvantages of gas curing and air-setting hardening of sodium silicates. It examines the members of the air-setting organic binders, namely, furan no-bake resins, phenolic no-bake resins, and urethanes. The article provides an overview of gas-cured organic binders. It also illustrates the three commercial systems for sand reclamation: wet reclamation systems, dry reclamation systems, and thermal reclamation.

This article reviews the basic types of mold aggregates and bonding methods for expendable molds and coremaking. It provides an overview of mold media and the basic types of sands and their properties. The most significant clays used in green sand operations, such as bentonites, are discussed. The article describes the methods of sand bonding with inorganic compounds. It provides a description of resin-bonded sand systems: no-bake binder systems, heat-cured binder systems, and cold box binder systems. The article concludes with a discussion on the media used for expendable molds, namely, ceramic shells and rammed graphite, for casting reactive metals such as titanium or zirconium.

Cores are separate shapes of sand that are placed in the mold to provide castings with contours, cavities, and passages that are not otherwise practical or physically obtainable by the mold. This article describes the basic principles of coremaking and the types of core sands, binders, and additives used in coremaking. It discusses the curing of compacted cores by core baking and the hot box processes. The article provides an overview of the core coatings, assembling and core setting, coring of tortuous passages, and cores in permanent mold castings and investment castings. It also discusses the design considerations in coremaking to eliminate cores and compares coring with drilling.

Modeling of gas evolution during sand mold castings is one of the most important technical and environmental issues facing the metal casting industry. This article focuses on describing the capability of numerically predicting gas evolution for the furan binder/silica sand system. It illustrates numerical modeling to study the gas evolution from furan binder/silica sand mold aggregate for aluminum, cast iron, and steel alloy cast components. The article discusses simulation results and experimental validation for aluminum alloys, cast iron castings, and steel alloys, as well as a parametric study that investigated the effects of various variables. It concludes with information on the application of 3-D modeling methodology to investigate gas emissions in furan binder/silica sand castings for steel 4140 and aluminum A356 alloys.

Aggregate molding, or sand casting, is the gravity pouring of liquid metal into a mold that is made of a mixture molded against a permanent pattern. This article summarizes the most important materials in the process of sand casting of cast iron, including different types of molding aggregates, clays, water, and additives in green sand, chemically bonded organic resins, and inorganic binders in self-setting, thermosetting, and gas-triggered systems. It discusses three main types of reclamation systems: wet, dry, and thermal. The article concludes with a description of both nonpermanent and permanent mold processes.

This article discusses classification of foundry processes based on the molding medium, such as sand molds, ceramic molds, and metallic molds. Sand molds can be briefly classified into two types: bonded sand molds, and unbonded sand molds. Bonded sand molds include green sand molds, dry sand molds, resin-bonded sand molds, and sodium silicate bonded sand. The article describes the casting processes that use these molds, including the no-bake process, cold box process, hot box process, the CO2 process, lost foam casting process and vacuum molding process. The casting processes that use ceramic molds include investment casting, and plaster casting. Metallic molds are used in permanent mold casting, die casting, semisolid casting, and centrifugal casting.

Casting is one of the most economical and efficient methods for producing metal parts. In terms of scale, it is well suited for everything from low-volume, prototype production runs to filling global orders for millions of parts. Casting also affords great flexibility in terms of design, readily accommodating a wide range of shapes, dimensional requirements, and configuration complexities. This article traces the history of metal casting from its beginnings to the current state, creating a timeline marked by discoveries, advancements, and influential events. It also lists some of the major markets where castings are used.

Sand casting processes are typically classified according to the type of binder present in the molding sand mixture. This article discusses common sand casting processes and design considerations related to shape, gating, feeding, and pattern making methods. It describes the composition of sand and binder normally used, and provides information on the aluminum casting alloys produced. The article discusses precision sand casting and sand reclamation, and includes information on health and safety considerations.

The appearance, morphology, and extent of the casting skin are the consequence of mold-metal interface interaction. This article discusses the classification of the mold-metal interaction based on severity: mild mold-metal interaction and severe mold-metal interaction. The casting surface exhibits some roughness, which depends on the molding materials used in the casting process. The article describes the effects of the casting skin in spheroidal graphite (SG) and compact graphite (CG) irons, as well as the mechanism of casting skin formation. It discusses the physics of liquid metal penetration in sand molds and concludes with information on the effect of sand additives and mold coatings.

This introductory article describes the various aspects of chemical structure that are important to an understanding of polymer properties and thus their eventual effect on the end-use performance of engineering plastics. The polymers covered include hydrocarbon polymers, carbon-chain polymers, heterochain polymers, and polymers containing aromatic rings. The article also includes some general information on the classification and naming of polymers and plastics. The most important properties of polymers, namely, thermal, mechanical, chemical, electrical, and optical properties, and the most significant influences of structure on those properties are then discussed. A variety of engineering thermoplastics, including some that are regarded as high-performance thermoplastics, are covered in this article. In addition, a few examples of commodity thermoplastics and biodegradable thermoplastics are presented for comparison. Finally, the properties and applications of six common thermosets are briefly considered.

Advanced thermoplastics are stiff, moldable plastics that compete with traditional engineering thermoplastics and thermosets owing to their good tensile, compressive, impact, and shear strength, electrical properties, and corrosion resistance. This article discusses commercial forms, family characteristics, properties and applications of the following advanced thermoplastics: homopolymer and copolymer acetals, fluoropolymers, ionomers, polyamides, polyamide-imides, polyarylates, polyketones, polyaryl sulfones, polybutylene terephthalates, polycarbonates, polyether-imides, polyether sulfones, polyethylene terephthalates, thermoplastic polyimides, liquid crystal polymers, polyphenylene ether blends, polyphenylene sulfides, and polysulfones.

This article is a compilation of definitions for terms related to engineering materials, including plastics, elastomers, polymer-matrix composites, adhesives and sealants, ceramics, ceramic-matrix composites, glasses, and carbon-carbon composites.

This article outlines the processes by which materials are selected to prevent or control localized corrosion, galvanic corrosion, and intergranular corrosion. It reviews the operating conditions and the design of candidate materials for material selection. The article discusses various corrosion-resistant materials, including ferrous and nonferrous metals and alloys, thermoplastics, reinforced thermosetting plastics, nonmetallic linings, glass, carbon and graphite, and catalyzed resin coatings. It examines an unusual form of intergranular corrosion known as exfoliation, which occurs in aluminum-copper alloys. The article also describes three types of erosion-corrosion: liquid erosion-corrosion, cavitation, and fretting. It concludes with information on the various factors to be considered for material selection, including minimum cost or economic design, minimum corrosion, minimum investment, and minimum maintenance.

This article focuses on the variety of alloys, furnaces, and associated melting equipment as well as the casting methods available for manufacturing magnesium castings. These methods include sand casting, permanent mold casting, die casting, thixomolding, and direct chill casting. The article discusses the flux process and fluxless process for the melting and pouring of magnesium alloys. It describes the advantages and disadvantages of green sand molding and tabulates typical compositions and properties of magnesium molding sands. The article provides information on the machining characteristics of magnesium and the applications of magnesium alloys.

This article explains how ceramic powders are made. It begins by briefly describing the raw materials used in structural clay products, whitewares, refractories, and advanced ceramics. It then examines various additives that promote uniformity at different stages of the process. After a description of the comminution process (wet and dry milling methods), it discusses batching and mixing operations and granulation methods. The article also deals with the effect of process variables and the steps involved in chemical synthesis, including preparation from solution and gas-phase reactions, filtration and washing, and powder recovery techniques. It concludes with a discussion on characterization, centering on size distribution analysis, specific surface area, density, porosity chemical composition, phase, and surface composition.

This article presents the primary considerations and mechanisms for corrosion and explains how they are involved in the selection of materials for process equipment in refineries and petrochemical plants. It discusses the material selection criteria for a number of ferrous and nonferrous alloys used in petroleum refining and petrochemical applications. The article reviews the mechanical properties, fabricability, and corrosion resistance of refinery steels. It describes low- and high-temperature corrosion, hydrogen embrittlement, and cracking such as stress-corrosion, sulfide stress, and stress-oriented hydrogen-induced cracking. The article considers hydrogen attack, corrosion fatigue, and liquid metal embrittlement and the methods of combating them. It explains the causes of velocity-accelerated corrosion and erosion-corrosion. The article summarizes some corrective measures that can be implemented to control corrosion. The applicable standards for materials used in corrosive service conditions in upstream and downstream petroleum service are presented in a tabular form.

The information provided in this article is intended for those individuals who want to determine why a casting component failed to perform its intended purpose. It is also intended to provide insights for potential casting applications so that the likelihood of failure to perform the intended function is decreased. The article addresses factors that may cause failures in castings for each metal type, starting with gray iron and progressing to ductile iron, steel, aluminum, and copper-base alloys. It describes the general root causes of failure attributed to the casting material, production method, and/or design. The article also addresses conditions related to the casting process but not specific to any metal group, including misruns, pour shorts, broken cores, and foundry expertise. The discussion in each casting metal group includes factors concerning defects that can occur specific to the metal group and progress from melting to solidification, casting processing, and finally how the removal of the mold material can affect performance.