Aluminum, a commonly used base material for brazing, can be easily fabricated by most manufacturing methods, such as machining, forming, and stamping. This article outlines non-heat-treatable wrought alloys typically used as base metals for the brazing process. It highlights chloride-active and fluoride-active types of fluxes that are used for torch, furnace, or dip brazing processes. The article explains the steps to be performed, including the designing of joints, preblaze cleaning, assembling, brazing techniques (dip brazing, furnace and torch brazing, fluxless vacuum brazing), flux removal techniques, and postbraze heat treatment processes. It concludes with information on the safety precautions to be followed during the brazing process.

Aluminum fluxing is a step in obtaining clean molten metal by preventing excessive oxide formation, removing nonmetallic inclusions from the melt, and preventing and/or removing oxide buildup on furnace walls. This article discusses the solid fluxes and gas fluxes used in foundries. It reviews the classification of solid fluxes depending on their use and function at the foundry operation. These include cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article also examines the operational practices and applications of the flux injection in the foundries. It describes the applications of the aluminum fluxing such as crucible furnaces, transfer ladles, reverberatory furnaces, and holding/casting furnaces.

This article provides information about the selection of brazing processes and filler metals and describes the brazing (heating) methods, including manual torch brazing, furnace brazing, induction brazing, dip brazing, resistance brazing and specialized brazing processes such as diffusion and exothermic brazing. The article explains joint design, filler materials, fuel gases, equipment, and fluxes in the brazing methods. The article also describes the brazing of steels, stainless steels, cast irons, heat-resistant alloys, aluminum alloys, copper and copper alloys, and titanium and titanium alloys.

Copper, copper alloys, and precious metals are probably the most easily brazed metals because of their resistance to oxidation at high temperatures. This article provides a brief discussion on the metallurgy of copper, copper alloys, and precious metals and discusses the filler metals, brazing fluxes, joint clearance and design, and different brazing processes used in brazing of copper, copper alloys, and precious metals.

There are a wide variety of furnace types and designs for melting aluminum. This article discusses the various types of furnaces, including gas reverberatory furnaces, crucible furnaces, and induction melting furnaces. It describes the classification of solid fluxes: cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article reviews the basic considerations in proper flux selection and fluxing practices. It explains the basic principles of degassing and discusses the degassing of wrought aluminum alloys. The article describes filtration in wrought aluminum production and in shape casting. It also reviews grain refinement in aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article concludes with a discussion on aluminum-silicon modification.

Fluxes are added to the welding environment to improve arc stability, provide a slag, add alloying elements, and refine the weld pool. This article discusses the effect of oxygen, which is an important chemical reagent to control the weld metal composition, microstructure, and properties. It provides information on the inclusions that form as a result of reactions between metallic alloy elements and nonmetallic tramp elements, or by mechanical entrapment of nonmetallic slag or refractory particles. The article reviews the considerations of flux formulation during shielded metal arc welding and flux cored arc welding (FCAW). It describes the types of fluxes used for submerged arc welding and FCAW as well as five essential groups of flux ingredients and their interactions.

This article describes the dip brazing process and the principal types of furnaces used for molten-salt-bath dip-brazing applications. It provides information on equipment maintenance, which is divided into temperature control, control of the liquid, and maintenance of the vessel. The article presents the typical salts used for molten-salt dip brazing of carbon and low-alloy steels with selected filler metals in tabular form. It concludes with information on dip brazing of stainless steels, cast irons, and aluminum alloys and safety precautions of the process.

This article describes the factors considered in the analysis of brazeability and solderability of engineering materials. These are the wetting and spreading behavior, joint mechanical properties, corrosion resistance, metallurgical considerations, and residual stress levels. It discusses the application of brazed and soldered joints in sophisticated mechanical assemblies, such as aerospace equipment, chemical reactors, electronic packaging, nuclear applications, and heat exchangers. The article also provides a detailed discussion on the joining process characteristics of different types of engineering materials considered in the selection of a brazing process. The engineering materials include low-carbon steels, low-alloy steels, and tool steels; cast irons; aluminum alloys; copper and copper alloys; nickel-base alloys; heat-resistant alloys; titanium and titanium alloys; refractory metals; cobalt-base alloys; and ceramic materials.

Metals and ceramics exposed to high-temperature salt solutions are susceptible to a form of corrosion caused by fused salts accumulating on unprotected surfaces. This article examines the electrochemistry of such hot corrosion processes, focusing on sodium sulfate systems generated by the combustion of fossil fuels. It explains how salt chemistry, including acid/base and oxidizing properties, affects corrosion rates and mechanisms. The article also provides information on electrochemical testing and explains how Pourbaix methods, normally associated with aqueous corrosion, can be used to study fused-salt corrosion.

This article discusses two general mechanisms of corrosion in molten salts. One is the metal dissolution caused by the solubility of the metal in the melt. The second and most common mechanism is the oxidation of the metal to ions. Specific examples of the types of corrosion expected for the different metal-fused salt systems are also provided. The metal-fused salt systems include molten fluorides, chloride salts, molten nitrates, molten sulfates, hydroxide melts, and carbonate melts. The article concludes with information on prevention of molten salt corrosion.

This article focuses on the pack-cementation coatings, in particular, halide-activated pack cementation coatings on nickel alloys. It also describes the thermodynamics and kinetics of, and simultaneous deposition of various types of, pack cementation processes. These include pack aluminizing, chromizing, and siliconizing.

Soldering involves heating a joint to a suitable temperature and using a filler metal (solder) that melts below 450 deg C (840 deg F). Beginning with an overview of the specification and standards and applications, this article discusses the principal levels and effects of the most common impurity elements in tin-lead solders. It describes the various processes involved in the successful soldering of joints, including shaping the parts to fit closely together; cleaning and preparing the surfaces to be joined; applying a flux; assembling the parts; and applying the heat and solder.

Fluxes are added to the welding environment to improve arc stability, to provide a slag, to add alloying elements, and to refine the weld pool. This article describes the effect of oxygen that directly reacts with alloying elements to alter their effective role by reducing hardenability, promoting porosity, and producing inclusions. It proposes basicity index for welding as a measure of expected weld metal cleanliness and mechanical properties. The article discusses alloy modification in terms of slipping and binding agents, slag formation, and slag detachability. It reviews the types of fluxes for different arc welding processes, such as shielded metal arc welding (SMAW), flux-cored arc welding (FCAW), and submerged arc welding (SAW).

The various methods of furnace, torch, induction, resistance, dip, and laser brazing are used to produce a wide range of highly reliable brazed assemblies. However, imperfections that can lead to braze failure may result if proper attention is not paid to the physical properties of the material, joint design, prebraze cleaning, brazing procedures, postbraze cleaning, and quality control. Factors that must be considered include brazeability of the base metals; joint design and fit-up; filler-metal selection; prebraze cleaning; brazing temperature, time, atmosphere, or flux; conditions of the faying surfaces; postbraze cleaning; and service conditions. This article focuses on the advantages, limitations, sources of failure, and anomalies resulting from the brazing process. It discusses the processes involved in the testing and inspection required of the braze joint or assembly.

Brazing technology is continually advancing for a variety of metals including aluminum and its alloys and nonmetals. This article discusses the key physical phenomena in aluminum brazing and the materials for aluminum brazing, including base metals, filler metals, brazing sheet, and brazing flux. It describes various aluminum brazing methods, such as furnace, vacuum, dip, and torch brazing. Friction, flow, induction, resistance, and diffusion brazing are some alternate brazing methods discussed. The article reviews the brazing of aluminum to ferrous alloys, aluminum to copper, and aluminum to other nonferrous metals. It also discusses post-braze processes in terms of post-braze heat treatment and finishing. The article concludes with information on the safety precautions considered in brazing aluminum alloys.

Corrosion is often thought of as rusting, the process of deterioration undergone by a metal when it is exposed to air or water. This article provides the fundamentals of joints corrosion and primarily addresses the various forms of corrosion observed in brazed and soldered joints and their causes. It describes the role of proper brazing procedures in controlling corrosion. The article concludes with information on the corrosion resistance of various brazing alloy systems.

Soldering technology has been used in applications ranging from the packaging of integrated circuit chips to the fabrication of industrial heat exchangers and consequently in structural or electronic applications. This article provides information on various soldering parameters, including types of solder alloy in terms of selection process; selection of substrate base material; flux selection based on adequate wettability by the solder; solder joint assembly; combined substrate, solder, and flux properties; and manufacturing procedures. Each of these parameters is explored using examples of both structural and electronic applications. The article concludes with a discussion on the environmental, safety, and health issues to be considered during soldering.

Dross, which is the oxide-rich surface that forms on melts due to exposure to air, is a term that is usually applied to nonferrous melts, specifically the lighter alloys such as aluminum or magnesium. This article describes dross formation and ways to reduce it, the economic implications of dross, and in-plant enhancement or recovery of dross. It discusses the influence of the melter type on dross generation and the influence of charge materials and operating practices on melt loss. Fluxing is a word applied in a broad sense to a number of melt-treating methods. The article also discusses the in-furnace treatment with chemical fluxes.

Surface treatments are applied to magnesium parts primarily to improve their appearance and corrosion resistance. Mechanical and chemical cleaning methods are used singly or in combination, depending on the specific application and product involved to ensure repetitive reliability. This article focuses on mechanical finishing methods, namely, barrel tumbling, polishing, buffing, vibratory finishing, fiber brushing, and shot blasting. It provides useful information on process control and difficulties with chemical and anodic treatments of magnesium alloys. The use and applications of plating and organic finishing of magnesium alloys are also reviewed. The article concludes with a description of health and safety precautions to be followed during the surface treatment process.

This article provides a description of the classification, industrial applications, microstructures, physical, chemical, corrosion, and mechanical properties of zirconium and its alloys. It discusses the formation of oxide films and the effects of water, temperature, and pH on zirconium. The delayed hydride cracking of zirconium is also described. The article provides information on the resistance of zirconium to various types of corrosion, including pitting corrosion, crevice corrosion, intergranular corrosion, galvanic corrosion, microbiologically induced corrosion, erosion-corrosion, and fretting corrosion. The article explains the effects of tin content in zirconium and effects of fabrication on corrosion. Corrosion control measures for all types of corrosion are also highlighted. The article concludes with information on the safety precautions associated with handling of zirconium.