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Book Chapter

By L.M. Weisenberger, B.J. Durkin
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001242
EISBN: 978-1-62708-170-2
... pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used. acid plating...
Book Chapter

By George B. Rynne
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001251
EISBN: 978-1-62708-170-2
... Abstract Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
... Abstract Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating...
Book Chapter

By Reginald K. Asher, Sr.
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001256
EISBN: 978-1-62708-170-2
...-speed fluoborate baths operating at from 500 to 1000 A/ft 2 . Time required to plate 2.54 μm (100 μin) of 80Sn-20Pb from high-speed methane sulfonic acid (MSA) solution Table 1 Time required to plate 2.54 μm (100 μin) of 80Sn-20Pb from high-speed methane sulfonic acid (MSA) solution Total...
Book Chapter

By Glenn Malone, Myron E. Browning
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001263
EISBN: 978-1-62708-170-2
..., is plated from Watts, fluoborate, and sulfamate solutions. The last is the most widely used due to lower stresses in the deposits and ease of operation. Nickel is deposited from most baths with moderate to high tensile stress. If uncontrolled, this stress can make removal of the mandrel difficult, can...
Book Chapter

By Milton F. Stevenson, Sr.
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001247
EISBN: 978-1-62708-170-2
... . Noncyanide baths generate little hydrogen embrittlement and are used to electroplate hardened, high-strength steels. Both the sulfate and the fluoborate baths have been used for some time as a substitute for cyanide baths, and working data are available. The fluoborate bath is characterized by high cathode...
Book Chapter

By Allen W. Grobin, Jr.
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001249
EISBN: 978-1-62708-170-2
... overcome by adding gelatin or glue to the bath to increase its viscosity. Plating Baths The four most commonly used indium plating baths are indium cyanide, indium fluoborate, indium sulfamate, and indium sulfate. Table 1 compares these processes. The details of the processes are shown in Tables...
Book Chapter

By Arthur J. Killmeyer
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001250
EISBN: 978-1-62708-170-2
.... The supplier of the proprietary bath should be consulted for directions on controlling this problem. To retard the oxidation of the stannous tin ions to the stannic form, either phenolsulfonic or cresolsulfonic acid is added to a sulfate-base system, and hydroquinone is added to a fluoboric acid-base...
Book Chapter

By Sue Troup-Packman
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001246
EISBN: 978-1-62708-170-2
... Abstract Iron has been electroplated from a variety of electrolytes, whose bath parameters result in coatings that have widely divergent characteristics according to the specific characteristics desired in the finished product. This article provides an overview of the process description...
Book Chapter

By Mary Oakley, Wayne Chandler
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006511
EISBN: 978-1-62708-207-5
... acid electrobrightening of aluminum and aluminum alloys Constituent or condition Amount or value Electrobrightening (a) Fluoboric acid 2.5 wt% Temperature of bath 30 °C (85 °F) Current density 1–2 A/dm 2 (10–20 A/ft 2 ) Voltage 15–30 V Immersion time 5–10 min...
Book Chapter

By George A. Di Bari
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001245
EISBN: 978-1-62708-170-2
... bath are similar to those from Watts solutions. The nickel fluoborate solution has been used primarily for high-speed deposition of thick nickel. Hard Nickel Developed especially for engineering applications, this solution is applied where controlled hardness, improved abrasion resistance...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003216
EISBN: 978-1-62708-199-3
... are more Copper electroforming solutions include acid are pieces for which electroforming can be used stringent because the process consumes much sulfate and fluoborate baths. Sulfate, fluoborate, advantageously. Optical memory disc mold cavi- more time and the product must be mechanically and sulfamate...
Book Chapter

Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006335
EISBN: 978-1-62708-179-5
... and reduction of fatigue strength are not dissipated as heat treating temperature approaches stress-relieving temperature. Nonmechanical Cleaning Nonmechanical cleaning methods applicable to cast irons include molten salt bath cleaning, pickling, and chemical cleaning, with the latter method including...
Book Chapter

By A. Sato
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001248
EISBN: 978-1-62708-170-2
... plating incorporating metals such as nickel and cobalt, to improve corrosion for specific applications and possibly eliminate standard chromate treating. A number of zinc baths based on zinc sulfate and zinc fluoborate have been developed, but these have very limited applications. They are used...
Book Chapter

By Alan Blair
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001252
EISBN: 978-1-62708-170-2
... be used. (A strike is a low-concentration bath operated at high cathode current density.) The following gives a typical silver strike solution formulation. Component/Parameter Value Silver, as KAg(CN) 2 , g/L (oz/gal) 1.0–2.0 (0.13–0.27) Potassium cyanide (free), g/L (oz/gal) 80–100 (10...
Book Chapter

By Eric W. Brooman
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001259
EISBN: 978-1-62708-170-2
... alloys Table 1 Technology options for the deposition of chromium-base alloys Type of bath Aqueous Acid Alkaline Nonaqueous Organic Molten salt Applied current None (electroless) Conventional direct current Pulsed direct current Periodic reversed direct...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003214
EISBN: 978-1-62708-199-3
... of electropolishing bath. Cathodes are individual rods, flat strips, or expanded metal in strips, which can be suspended from the cathode bar in a pattern for good current distribution. Applications This process is primarily used for obtaining mirror-like surfaces from highly smooth initial surfaces. A final...
Book Chapter

Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
... to avoid the hazards that attend the use of hydrofluoric acid. Fluoboric and fluosilicic acids may also be used as alternates to hydrofluoric acid. An alkaline bath, such as Alupol, can also be used for chemical etching. This bath consists of 20 kg (44 lb) sodium nitrate, 15 kg (33 lb) sodium nitrite, 25...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001312
EISBN: 978-1-62708-170-2
... contamination and cold-worked layer and to produce a smooth, bright finish. Chemical Descaling Some scale, as well as forming lubricants, can be removed by proprietary water solutions of strong caustic compounds, or by the use of molten alkaline-based salt baths. The salt baths operate at temperatures...
Book Chapter

By B. Mishra
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004218
EISBN: 978-1-62708-184-9
... is normally used for tempering and quenching. An alkali chloride carbonate mixture is used for annealing ferrous and nonferrous metals. Neutral salt baths containing mixed chlorides are used for hardening steel parts. Carbon steels, alloy steels, stainless steels, and Fe-Ni-Cr alloys have been used...