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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001242
EISBN: 978-1-62708-170-2
... pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used. acid plating...
Abstract
This article provides a detailed account of the various alkaline and acid plating baths used for electrolytic copper plating. Dilute cyanide and Rochelle cyanide baths, high-efficiency sodium and potassium cyanide baths, alkaline noncyanide copper plating baths, and alkaline copper pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001251
EISBN: 978-1-62708-170-2
... Abstract Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements...
Abstract
Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements, and applications of lead plating.
Book Chapter
Electrodeposition Processes
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
... Abstract Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating...
Abstract
Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also discusses selective plating, electroforming, and other processes and where they are typically used.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001256
EISBN: 978-1-62708-170-2
...-speed fluoborate baths operating at from 500 to 1000 A/ft 2 . Time required to plate 2.54 μm (100 μin) of 80Sn-20Pb from high-speed methane sulfonic acid (MSA) solution Table 1 Time required to plate 2.54 μm (100 μin) of 80Sn-20Pb from high-speed methane sulfonic acid (MSA) solution Total...
Abstract
Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001263
EISBN: 978-1-62708-170-2
..., is plated from Watts, fluoborate, and sulfamate solutions. The last is the most widely used due to lower stresses in the deposits and ease of operation. Nickel is deposited from most baths with moderate to high tensile stress. If uncontrolled, this stress can make removal of the mandrel difficult, can...
Abstract
Electroforming is the process by which articles or shapes can be exactly reproduced by electrodeposition on a mandrel or form that is later removed, leaving a precise duplicate of the original. This article discusses electroforming applications, and explains electroforming of nickel, cobalt, iron, and copper, providing information on mandrel design and selection, electroforming solutions and operating variables. It discusses the significant aspects of electroforming that demand special considerations, such as metal distribution, internal deposit stress, roughness, and treeing. The article concludes with an overview of alloy electroforming.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001247
EISBN: 978-1-62708-170-2
... . Noncyanide baths generate little hydrogen embrittlement and are used to electroplate hardened, high-strength steels. Both the sulfate and the fluoborate baths have been used for some time as a substitute for cyanide baths, and working data are available. The fluoborate bath is characterized by high cathode...
Abstract
Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature of cadmium plating with attention to the materials of construction and equipment used. The article provides a description of the selection of plating method with examples, applications, and several postplating processes of cadmium plating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001249
EISBN: 978-1-62708-170-2
... overcome by adding gelatin or glue to the bath to increase its viscosity. Plating Baths The four most commonly used indium plating baths are indium cyanide, indium fluoborate, indium sulfamate, and indium sulfate. Table 1 compares these processes. The details of the processes are shown in Tables...
Abstract
This article focuses on the electrodeposition of indium and its alloys, such as indium-antimony, indium-gallium, and indium-bismuth, in nonaqueous indium plating baths. It also provides information on the stripping of indium plate from plated components and presents an overview of the specifications, standards, and hazards of indium plating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001250
EISBN: 978-1-62708-170-2
.... The supplier of the proprietary bath should be consulted for directions on controlling this problem. To retard the oxidation of the stannous tin ions to the stannic form, either phenolsulfonic or cresolsulfonic acid is added to a sulfate-base system, and hydroquinone is added to a fluoboric acid-base...
Abstract
A tin deposit provides sacrificial protection to copper, nickel, and many other nonferrous metals and alloys. Tin also provides good protection to steel. Tin can be deposited from either alkaline or acid electrolytes. This article explains the compositions and operating conditions of these electrolytes.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001246
EISBN: 978-1-62708-170-2
... Abstract Iron has been electroplated from a variety of electrolytes, whose bath parameters result in coatings that have widely divergent characteristics according to the specific characteristics desired in the finished product. This article provides an overview of the process description...
Abstract
Iron has been electroplated from a variety of electrolytes, whose bath parameters result in coatings that have widely divergent characteristics according to the specific characteristics desired in the finished product. This article provides an overview of the process description and processing equipment and discusses the properties, advantages, limitations, and principal applications of iron plating. It also describes the environmental, health, and safety considerations of iron plating.
Book Chapter
Chemical and Electrolytic Brightening
Available to PurchaseSeries: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006511
EISBN: 978-1-62708-207-5
... acid electrobrightening of aluminum and aluminum alloys Constituent or condition Amount or value Electrobrightening (a) Fluoboric acid 2.5 wt% Temperature of bath 30 °C (85 °F) Current density 1–2 A/dm 2 (10–20 A/ft 2 ) Voltage 15–30 V Immersion time 5–10 min...
Abstract
Chemical brightening (bright dipping) and electrolytic brightening (electropolishing) are essentially selective-dissolution processes, in which the high points of a rough surface of aluminum are attacked more rapidly than the depressions, and the peaks and valleys are smoothed to produce a bright and beautiful finish. This article discusses the metallurgical factors, optical factors, and applications of the chemical and electrolytic brightening. It compares the chemical brightening and electrolytic brightening, and presents the advantages of the chemical and electrolytic brightening processes in terms of performance and economy. The article describes the phosphoric-nitric acid baths and phosphoric-sulfuric acid baths used for chemical brightening. Solution compositions and operating conditions for three commercial electropolishing processes, as well as for suitable post-treatments, are presented in a table.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001245
EISBN: 978-1-62708-170-2
... bath are similar to those from Watts solutions. The nickel fluoborate solution has been used primarily for high-speed deposition of thick nickel. Hard Nickel Developed especially for engineering applications, this solution is applied where controlled hardness, improved abrasion resistance...
Abstract
This article discusses the process considerations and deposit properties of nickel plating. It describes the Watts solution and the anode materials used. The article focuses on the nickel plating processes used for decorative, engineering, and electroforming purposes. It provides information on the quality control of nickel plating. It concludes with a review of the environmental, health, and safety considerations associated with nickel plating.
Book Chapter
Nonelectrolytic Deposition Processes
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003216
EISBN: 978-1-62708-199-3
... are more Copper electroforming solutions include acid are pieces for which electroforming can be used stringent because the process consumes much sulfate and fluoborate baths. Sulfate, fluoborate, advantageously. Optical memory disc mold cavi- more time and the product must be mechanically and sulfamate...
Abstract
This article describes the steps, bath composition and characteristics, equipment, plating rate, deposit thickness, and applications for different types of nonelectrolytic deposition processes, including electroless nickel plating, electroless copper plating and mechanical plating.
Book Chapter
Cleaning and Coating of Cast Irons
Available to PurchaseSeries: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006335
EISBN: 978-1-62708-179-5
... and reduction of fatigue strength are not dissipated as heat treating temperature approaches stress-relieving temperature. Nonmechanical Cleaning Nonmechanical cleaning methods applicable to cast irons include molten salt bath cleaning, pickling, and chemical cleaning, with the latter method including...
Abstract
Coating of cast irons is done to improve appearance and resistance to degradation due to corrosion, erosion, and wear. This article describes inorganic coating methods commonly applied to cast irons. The coating methods include plating, hot dip coating, conversion coating, diffusion coating, cladding, porcelain enameling, and thermal spray. Organic coatings have a wide variety of properties, but their primary use is for corrosion resistance combined with a pleasing colored appearance. The article discusses the various types of organic coatings applied to cast irons. Practically any degree of smoothness or roughness and requirement for color and gloss can be filled by organic coatings. The article describes abrasive blast cleaning, abrasive waterjet cleaning and finishing, vibratory finishing, barrel finishing, and shot peening for processing iron castings.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001248
EISBN: 978-1-62708-170-2
... plating incorporating metals such as nickel and cobalt, to improve corrosion for specific applications and possibly eliminate standard chromate treating. A number of zinc baths based on zinc sulfate and zinc fluoborate have been developed, but these have very limited applications. They are used...
Abstract
Commercial zinc plating is accomplished by a number of distinctively different systems: cyanide baths, alkaline noncyanide baths, and acid chloride baths. This article focuses on the composition, advantages, disadvantages, operating parameters, and applications of each of the baths. It provides information on the control of thicknesses of zinc specified for service in various indoor and outdoor atmospheres and on the similarities between cadmium and zinc plating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001252
EISBN: 978-1-62708-170-2
... be used. (A strike is a low-concentration bath operated at high cathode current density.) The following gives a typical silver strike solution formulation. Component/Parameter Value Silver, as KAg(CN) 2 , g/L (oz/gal) 1.0–2.0 (0.13–0.27) Potassium cyanide (free), g/L (oz/gal) 80–100 (10...
Abstract
Electroplated silver is used in both decorative and functional applications, such as engineering and electrical/electronic applications. This article explains the solution formulations and specifications of electrolytes used in silver plating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001259
EISBN: 978-1-62708-170-2
... alloys Table 1 Technology options for the deposition of chromium-base alloys Type of bath Aqueous Acid Alkaline Nonaqueous Organic Molten salt Applied current None (electroless) Conventional direct current Pulsed direct current Periodic reversed direct...
Abstract
Chromium alloys yield alloy coatings with properties that range from completely satisfactory to marginally acceptable, depending on the end use. This article provides a detailed description of plating solutions and deposition conditions and rates of chromium-iron, chromium-nickel, and chromium-iron-nickel alloys.
Book Chapter
Finishing Methods
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003214
EISBN: 978-1-62708-199-3
... of electropolishing bath. Cathodes are individual rods, flat strips, or expanded metal in strips, which can be suspended from the cathode bar in a pattern for good current distribution. Applications This process is primarily used for obtaining mirror-like surfaces from highly smooth initial surfaces. A final...
Abstract
Finishing refers to a wide variety of processes that generally involve material removal in one form or another to generate surfaces with specific geometries, tolerances, and functional or decorative characteristics. This article discusses four major finishing methods, namely, abrasive machining, electropolishing, mass finishing, and shot peening. In each case, it describes subtypes, process variations, and the associated equipment.
Book Chapter
Surface Engineering of Aluminum and Aluminum Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
... to avoid the hazards that attend the use of hydrofluoric acid. Fluoboric and fluosilicic acids may also be used as alternates to hydrofluoric acid. An alkaline bath, such as Alupol, can also be used for chemical etching. This bath consists of 20 kg (44 lb) sodium nitrate, 15 kg (33 lb) sodium nitrite, 25...
Abstract
Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.
Book Chapter
Surface Engineering of Zirconium and Hafnium
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001312
EISBN: 978-1-62708-170-2
... contamination and cold-worked layer and to produce a smooth, bright finish. Chemical Descaling Some scale, as well as forming lubricants, can be removed by proprietary water solutions of strong caustic compounds, or by the use of molten alkaline-based salt baths. The salt baths operate at temperatures...
Abstract
Zirconium and hafnium surfaces require cleaning and finishing for reasons such as preparation for joining, heat treatment, plating, forming, and producing final surface finishes. This article provides information on various surface treatment processes, surface soil removal, blast cleaning, chemical descaling, pickling or etching, anodizing, autoclaving, polishing, buffing, vapor phase nitriding, and electroplating. Applications of these surface treatment processes are also reviewed.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004218
EISBN: 978-1-62708-184-9
... is normally used for tempering and quenching. An alkali chloride carbonate mixture is used for annealing ferrous and nonferrous metals. Neutral salt baths containing mixed chlorides are used for hardening steel parts. Carbon steels, alloy steels, stainless steels, and Fe-Ni-Cr alloys have been used...
Abstract
The high-temperature corrosion processes that are most frequently responsible for the degradation of furnace accessories are oxidation, carburization, decarburization, sulfidation, molten-salt corrosion, and molten-metal corrosion. This article discusses each corrosion process, along with the corrosion behavior of important engineering alloys. It describes the corrosion of plating, anodizing, and parts of pickling equipment such as tanks, wirings and bus bars, racks, anode splines, pumps, and heaters.
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