Search Results for flame emission

This article discusses the general principles, optical systems, and emission sources of optical emission spectroscopy for elemental analysis. Changes in the energy of the valence or outer shell electrons result in the atomic lines used in emission spectroscopy. Each possible combination of electron configurations produces a spectroscopic term that describes the state of the atom. Atomic emission is analytically useful only to the extent that the emission from one atomic species can be measured and its intensity recorded independent of emission from other sources. Emission sources are often designed to minimize molecular emission. Each of the four types of emission sources; arcs, high-voltage sparks, glow discharges, and flames; has a set of physical characteristics with accompanying analytical assets and liabilities. The article also discusses the applications of each type of emission source.

Atomic absorption spectrometry (AAS) is generally used for measuring relatively low concentrations of approximately 70 metallic or semimetallic elements in solution samples. This article describes several features that are common to three techniques, namely, AAS, atomic emission spectrometry (AES), and atomic fluorescence spectrometry (AFS). It discusses the reasons for the extreme differences in AAS sensitivities that affect AFS and AES. The article provides information on the advantages and disadvantages of the Smith/Hieftje system and two types of background correction systems, namely, the continuum-source background correction and Zeeman background correction. It also provides a list of applications of conventional AAS equipment, which includes most of the types of samples brought to laboratories for elemental analyses.

The raw materials used in thermal spray processes are a critical parameter in the finished coating because the variations in their size, morphology, chemistry, and phase composition can significantly impact coating properties. Therefore, it is important to test and characterize the raw materials. This article discusses various characterization methods for powders. Topics discussed include: methods for determining particle size and/or size distribution; powder and coating stoichiometry; particle chemistry; and phase analysis by x-ray diffraction. This article discusses the characterization of thermal spray powders which involves the determination of particle size and/or size distribution and phase analysis by x-ray diffraction. It provides information on preferential volatilization and rapid solidification that influence compositional differences. Wet chemical methods, spectographic analysis, and atomic absorption spectrometry are also discussed.

This article is a detailed account of optical emission spectroscopy (OES) for elemental analysis. It begins with a discussion on the historical background of OES and development trends in OES methods. This is followed by a description of the general principles and optical systems of OES, along with various types of emission sources commonly used for OES. Some of the processes involved in calibration and quantification of OES for direct solids analysis by the ratio method are then described. The article ends with a discussion on the applications of each type of emission sources.

This article focuses on some of the factors pertinent to atomic absorption spectroscopy (AAS). It begins by describing the working principle, critical components, and construction of flame atomic absorption instrumentation. This is followed by sections discussing various types of interferences in AAS, namely vaporization, ionization, matrix interferences, and background correction. Some of the methods for the analysis of microliter-sized samples and methods of standard additions to the sample solution for generating calibration standards are then reviewed. The article concludes with a section on processes involved in matrix matching.

This article provides an overview of the various types of unsaturated polyester resins and low-profile additives. The resins include general-purpose resins, isophthalic resins, bisphenol A fumarate resins, chlorendic resins, and vinyl ester resin. The article describes the mechanical and electrical properties, thermal and oxidative stability, and chemical and ultraviolet (UV) resistance of polyester resins. It concludes with a discussion on the flame-retardant polyester resins.

This article discusses the capabilities and limitations of various material characterization methods that assist in the selection of a proper analytical tool for analyzing particulate materials. Commonly used methods are microanalysis, surface analysis, and bulk analysis. The techniques used for performing microanalysis include scanning electron microscopy and electron probe X-ray microanalysis. The article describes surface analysis techniques, including Auger electron spectroscopy, X-ray photoelectron spectroscopy, and ion-scattering spectroscopy. Bulk analysis techniques, such as X-ray powder diffraction, inductively coupled plasma atomic emission spectroscopy, atomic absorption spectroscopy, and atomic fluorescence spectrometry, are also discussed.

This article provides a clear but nonexhaustive description of the general principle of atomic emission, with a particular focus on instrumentation, and summarizes the main characteristics of the inductively coupled plasma optical emission spectrometer technique. Basic atomic theory as well as the instrument characteristics and their influence on the instrument performances are presented. The advantages, drawbacks, and developments of this technique are discussed, and, finally, alternative techniques and examples of applications are provided.

Inductively coupled plasma atomic emission spectroscopy (ICP-AES) is an analytical technique for elemental determinations in the concentration range of major to trace based on the principles of atomic spectroscopy. This article provides a description of the basic atomic theory, and explains the analytical procedures and various interference effects of ICP, namely, spectral, vaporization-atomization, and ionization. It provides a detailed discussion on the principal components of an analytical ICP system, namely, the sample introduction system; ICP torch and argon gas supplies; radio-frequency generator and associated electronics; spectrometers, such as polychromators and monochromators; detection electronics and interface; and the system computer with appropriate hardware and software. The article also describes the uses of direct-current plasma, and provides examples of the applications of ICP-AES.

This article is a compilation of definitions of terms related to materials characterization techniques.

Temperature control in heat treating is of paramount importance in maintaining the quality and achieving the desired metallurgical results. This article provides a detailed account of the factors affecting temperature control in heat treating furnaces, with information on temperature control systems, including contact sensors, noncontact sensors, controllers, energy-flow regulators, measurement instruments, and set-point programmers. Common contact sensors include temperature scales, thermocouples, and resistance temperature detectors, whereas optical pyrometers and on-line radiation thermometers fall under the noncontact type. The article describes two types of instrumentation used in heat treating: field test instruments for temperature-uniformity surveys and system-accuracy tests; and controlling, monitoring, and recording instruments for digital instrumentation.

The overall chemical composition of metals and alloys is most commonly determined by X-ray fluorescence (XRF) and optical emission spectroscopy (OES), and combustion and inert gas fusion analysis. This article provides information on the capabilities, uses, detection threshold and precision methods, and sample requirements. The amount of material that needs to be sampled, operating principles, and limitations of the stated methods are also discussed.

Ceramic and glass manufacturers take environmental regulations into consideration during all stages of the product cycle, from research and development to purchasing, processing, end use, and disposal. Ceramic and glass products are finding application in the construction industry and as raw materials for other processes. This article describes the recycling of in-process scrap and industrial wastes (fly ash, red mud, metallurgical waste, and other waste products), and applications of these recycled products. It focuses on environmental regulations such as Resource Conservation and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide.

The hazards associated with thermal spray deposition processes include ultraviolet and infrared radiation; acoustical noise; and by-product production in the forms of nitrous oxides, ozone, fumes, and dust. The most important consideration in health and safety is to use the engineered controls of hazards. This article provides a brief description of the spray booth, the most commonly used engineering tool to separate the operator from the thermal spray process and confine the associated hazards. It also presents guidelines on the proper and safe handling of industrial gases and ventilation and heat exhaust. The article provides information on the personal protective equipment for eyes and skin from radiation, and ears from noise. It also discusses other potential safety hazards associated with thermal spraying, namely, magnetic fields and infrasound.

This article discusses the operating principles, types, and applications of shearing and slitting of different forms of steel, including plates, flat sheets, bars, coiled sheet and strips. In addition, it provides a detailed account of the cutting methods such as oxyfuel gas cutting, plasma arc cutting, oxygen arc cutting, laser beam cutting, and air carbon arc cutting and gouging, describing their process capabilities, equipment used, operating principles and parameters, and factors affecting their efficiency.

This article begins with a discussion on the energy sources used for thermal forming. These include electric induction coil, gas flame, plasma torch, and laser beam. The article discusses the mechanisms of forming and different modes of deformation. It describes the effect of process and material parameters on forming and the effect of metallurgical changes on mechanical property and microstructure of stainless steel. The article concludes with information on the applications of thermal forming.