This article focuses on the various techniques for removing contaminants in the surface preparation of steel for hot-dip coatings: wet cleaning methods, including alkaline cleaning, electrolytic cleaning, chemical pickling, and electrolytic pickling; flame cleaning and furnace-atmosphere techniques, such as Sendzimir oxidation/reduction method; other specialized methods, namely, fluxes, mechanical cleaning, and ultrasonic methods; or a combination of these.

This article provides an overview of surface contaminants that may affect the heat treatment processes and end-product quality. It presents information on the chemicals used to clean different surface contaminants of steels. The article discusses three types of cleaning methods, namely, mechanical, chemical, and electrochemical and their effectiveness and applicability. The mechanical cleaning methods include grinding, brushing, steam or flame jet cleaning, abrasive blasting, and tumbling. Solvent cleaning, emulsion cleaning, alkaline cleaning, acid cleaning, pickling, and descaling are chemical cleaning methods. The electrochemical cleaning methods include electropolishing, electrolytic alkaline cleaning, and electrolytic pickling. The article provides information on cleanliness measurement methods such as qualitative tests and quantitative tests to ensure product quality. Health hazards that may be associated with each cleaning method and the general control measures to be used for each hazard are tabulated.

Passivation; pickling, that is, acid descaling; electropolishing; and mechanical cleaning are important surface treatments for the successful performance of stainless steel used for piping, pressure vessels, tanks, and machined parts in a wide variety of applications. This article provides an overview of the various types of stainless steels and describes the commonly used cleaning methods, namely, alkaline cleaning, emulsion cleaning, solvent cleaning, vapor degreasing, ultrasonic cleaning, and acid cleaning. Finishing operations of stainless steels, such as grinding, polishing, and buffing, are reviewed. The article also explains the procedures of electrocleaning, electropolishing, electroplating, painting, surface blackening, coloring, terne coatings, and thermal spraying. It includes useful information on the surface modification of stainless steels, namely, ion implantation and laser surface processing. Surface hardening techniques, namely, nitriding, carburizing, boriding, and flame hardening, performed to improve the resistance of stainless steel alloys are also reviewed.

Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal. It provides an overview of the basic design and safety considerations of the salt bath equipment and describes the environmental impact of molten salt bath cleaning.

This article reviews the steps involved in presurface-preparation inspection: substrate replacement; removal of weld spatter, rounding of sharp edges, and grinding of slivers/laminations; and removal of rust scale, grease, oil, and chemical (soluble salt) contamination. It focuses on surface preparation methods that range from simple solvent cleaning to hand and power tool cleaning, dry and wet abrasive blast cleaning, centrifugal wheel blast cleaning, chemical stripping, and waterjetting for the application of the coating system. In addition, the article provides a description of the Society for Protective Coatings' (SSPC) standards and NACE International standards as well as the International Organization for Standardization (ISO) standards and International Concrete Repair Institute (ICRI) guidelines for surface cleanliness.

Flame hardening is a heat treating process in which a thin surface shell of a steel part is heated rapidly to a temperature above the critical temperatures of the steel. The versatility of flame-hardening equipment and the wide range of heating conditions obtainable with gas burners, often permit flame hardening to be done by a variety of methods. These include the spot or stationary method, progressive method, spinning method, and the combination progressive-spinning method. This article provides information on fuel gases used in flame hardening and their selection criteria for specific applications. It also discusses operating procedures and control requirements for flame hardening of steel.

Torch soldering utilizes a fuel gas flame as the heat source in the soldering process to produce a leak-tight assembly with some degree of mechanical strength. This article describes the advantages, limitations, and applications of torch soldering. It reviews the equipment used and the basic heating techniques required for the soldering.

This article provides a brief review of the classification and characteristics of cast irons. It describes the processes used to clean iron castings, including mechanical cleaning and finishing and nonmechanical cleaning. The article discusses surface treatments used to extend casting life when resistance to corrosion, wear, and erosion is required. The common methods include electroplating, electroless plating, hardfacing, weld cladding, surface hardening, porcelain enameling, and organic coatings.

Ceramic coatings are applied to metals to protect them against oxidation and corrosion at room temperature and at elevated temperatures. This article provides a detailed account of the factors to be considered when selecting a ceramic coating and describes the characteristics of various coating materials, namely, silicate glasses, oxides, carbides, silicides, and cermets. It reviews ceramic coating methods: brushing, spraying, dipping, flow coating, combustion flame spraying, plasma-arc flame spraying, detonation gun spraying, pack cementation, fluidized-bed deposition, vapor streaming, troweling, and electrophoresis. The article also includes information on the evaluation of the quality of ceramic coatings.

This article provides a general technical description of thermal spray coatings used for corrosion protection in atmospheric and aqueous environments. It further discusses two basic coating approaches of corrosion protection, namely, the sacrificial coating of thermal spray aluminum (TSA) and thermal spray zinc (TSZ), and the barrier-type coating of corrosion-resistant materials. The emphasis is on sacrificial coatings. The article describes the steps involved in the application of TSA and TSZ: surface preparation, coating deposition, and postspray treatment. It discusses their field exposure tests and application history. The article also contains helpful information on the dense barrier coatings by high-velocity spraying processes along with their corrosion performance.

This article introduces thermal spray coatings and describes the various types of coating processes and coating devices, including the flame spray, electric-arc spray, plasma spray, transferred plasma arc, high-velocity oxyfuel, and detonation gun. It provides information on the surface preparation methods and finishing treatments of coated parts. The article also explains the tests to evaluate the coating quality and the effects of coating structures and mechanical properties on coated parts. It concludes with a discussion on the uses of thermal spray coatings.

Fracture surfaces are fragile and subject to mechanical and environmental damage that can destroy microstructural features. This article discusses the importance of care and handling of fractures and the factors that need to be considered during the preliminary visual examination. It describes the procedures for sectioning a fracture and opening secondary cracks as well as the effect of nondestructive inspection on subsequent evaluation. The article provides information on the most common techniques for cleaning fracture surfaces. These techniques are dry air blast cleaning, replica stripping, organic-solvent cleaning, water-base detergent cleaning, cathodic cleaning, and chemical-etch cleaning.

The hazards associated with thermal spray deposition processes include ultraviolet and infrared radiation; acoustical noise; and by-product production in the forms of nitrous oxides, ozone, fumes, and dust. The most important consideration in health and safety is to use the engineered controls of hazards. This article provides a brief description of the spray booth, the most commonly used engineering tool to separate the operator from the thermal spray process and confine the associated hazards. It also presents guidelines on the proper and safe handling of industrial gases and ventilation and heat exhaust. The article provides information on the personal protective equipment for eyes and skin from radiation, and ears from noise. It also discusses other potential safety hazards associated with thermal spraying, namely, magnetic fields and infrasound.

Heat treating furnaces require different control systems and integration for achieving optimum technical results and enabling safe operation. This article focuses on atmosphere furnaces, with some coverage on controls for vacuum furnaces. Heat treating operations require reliable monitoring and control of motion and position of various mechanical components with the help of mechanical limit switches, proximity sensors, and distance- and position-measuring devices. Using inputs from both flow meters and sensors, such as thermocouples and oxygen sensors, flow measurement control systems must be able to adjust the flow of gases for process optimization. The operator interface of a furnace-control system displays critical information such as the furnace temperature, atmosphere status, alarms, electronic chart recorders, recipe, and maintenance. A supervisory control and data-acquisition (SCADA) system is used to monitor, collect, and store data from multiple pieces of equipment.

This article discusses the design parameters, operation, characteristics, properties, and advantages of various types of crucible furnaces, such as stationary, tilting, and movable furnaces. It also provides information on the application of the crucible furnaces.

This article begins with a description of the advantages and disadvantages of thermal spraying. It provides a discussion on the importance of substrate processing prior to coating and the role of undercutting in repair. The article reviews the steps for substrate preparation, namely, cleaning, roughening, masking, and preheating. Information on the equipment and process variables of dry abrasive grit blasting are also provided. The article describes the roles of spray stream and the spray pattern for all thermal spray processes. It discusses the defects arising from poor temperature control and from the variables influencing the manipulation of the spray torch. The article concludes with helpful information on calculating the process efficiency of thermal spraying.

Oxyfuel gas cutting (OFC) includes a group of cutting processes that use controlled chemical reactions to remove preheated metal by rapid oxidation in a stream of pure oxygen. This article discusses the operation principles and process capabilities of the OFC. It reviews the properties and compositions of fuel types such as acetylene, natural gas, propane, propylene, and methyl-acetylene-propadiene-stabilized gas. The article describes the effects of OFC on base metal, including carbon and low-alloy steels, cast irons, and stainless steels. It provides information on light cutting, medium cutting, heavy cutting, and stack cutting. The article informs that the basic oxyfuel method can be modified to allow gas cutting of metals, such as stainless steel and most nonferrous alloys, that resist continuous oxidation.

This article discusses the operating principles, types, and applications of shearing and slitting of different forms of steel, including plates, flat sheets, bars, coiled sheet and strips. In addition, it provides a detailed account of the cutting methods such as oxyfuel gas cutting, plasma arc cutting, oxygen arc cutting, laser beam cutting, and air carbon arc cutting and gouging, describing their process capabilities, equipment used, operating principles and parameters, and factors affecting their efficiency.

This article illustrates the basic components of dry and wet hearth reverberatory furnaces. It discusses stack melters that are used for aluminum metal casting, as they are efficient in sealing the furnace and using the flue gases to preheat the charge materials. The article describes the various factors for improving and maintaining furnace efficiencies. It explains the benefits of circulating molten metal in reverberatory furnaces and circulation methods.