This article presents the basic guidelines considered in designing a composite structure, and the basic definitions of terms that apply to composites. It describes the analysis of a composite laminate based on stress-strain relationships, stress-strain load relationships, general load displacement case, and general load case solution. Factors affecting the composite materials properties and allowables of fiber-reinforced polymers are reviewed. The article discusses the process considerations for mold design, such as master model, metal tooling, composite tooling, and tool care. It explains the resin selection in designing the composite for use in a particular application. The article illustrates the various methods that are used to process a composite component, namely, wet lay-up, autoclave, resin transfer molding, and vacuum-assisted resin transfer molding. It provides a discussion on electromagnetic interference shielding, electrostatic discharge protection, metal plating, fire resistance, and corrosion resistance on composite materials.

Testing of fiber-reinforced composite materials is performed to determine uniaxial tensile strength, Young's modulus, and Poisson's ratio relative to principal material directions, that helps in the prediction of the properties of laminates. Beginning with an overview of the fundamentals of tensile testing of fiber-reinforced composites, this article describes environmental exposures that often occur during specimen preparation and testing. These include exposures during specimen preparation, and planned exposure such as moisture, damage (impact), and thermal cycling techniques. The article also discusses the test procedures, recommended configurations, test specimen considerations, and safety requirements considered in the four major types of mechanical testing of polymer-matrix composites: tensile test, compression test, flexural test, and shear test.

Damping is the energy dissipation properties of a material or system under cyclic stress. The vibrational and damping characteristics of composites are important in many applications, including ground-based and airborne vehicles, space structures, and sporting goods. This article describes the damping characteristics of unidirectional composites, when they are subjected to longitudinal shear, longitudinal tension/compression, and transverse tension/compression. It presents equations that govern the overall damping capacity of beams that are cut from laminated plates. The article discusses the effect of temperature on damping and provides information on the relationship between damping and strength.

Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy, contact angle, work of adhesion, solid surface energy, and wetting and wicking. The article describes the change in interphase depending on the reinforcing fiber such as glass fiber, polymeric fiber, and carbon fiber. It emphasizes fiber-matrix adhesion measurements by direct methods, indirect methods, and composite laminate tests. The effects of interphase and fiber-matrix adhesion on composite mechanical properties, such as composite on-axis properties, composite off-axis properties, and composite fracture properties, are also discussed.

This article reviews the fundamental relationships between microstructure and mechanical properties for major classes of nonmetallic engineering materials: metals, ceramics and glasses, intermetallic compounds, polymers, and composites. It details the structures of inorganic crystalline solids, inorganic noncrystalline solids, and polymers. The article describes the various strengthening mechanisms of crystalline solids, namely, work hardening, solid-solution hardening, particle/precipitation hardening, and grain size hardening. Deformation and strengthening of composite materials, polymers, and glasses are reviewed. The article concludes with information on the two important aspects of the mechanical behavior of any class of engineering material: fatigue response and fracture resistance.

A unidirectional fiber composite (UDC) consists of aligned continuous fibers that are embedded in a matrix. This article describes a variety of analytical methods that are used to determine the various physical properties of the UDC. These properties include elasticity, thermal expansion coefficients, moisture swelling coefficients, static and dynamic viscoelastic properties, conductivity, and moisture diffusivity.

Knowledge of fatigue behavior at the laminate level is essential for understanding the fatigue life of a laminated composite structure. This article describes fatigue failure of composite laminates in terms of layer cracking, delamination, and fiber break and interface debonding. It discusses the fatigue behavior of composite laminates in the form of a relation between applied maximum fatigue stress and fatigue life. The article explains Weibull distribution and parameters estimation for fatigue data analysis and life prediction of composite laminates. It analyzes the fatigue properties and damage tolerance of fiber-metal laminates such as ARALL and GLARE laminates. The article concludes with a discussion on the effects of fatigue on notched and unnotched specimens.

Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.

This article begins with a review of the purposes of mechanical characterization tests and the general considerations related to the mechanical properties of anisotropic systems, specimen fabrication, equipment and fixturing, environmental conditioning, and analysis of test results. It provides information on the specimen preparation, instrumentation, and procedures for various mechanical test methods of fiber-reinforced composites. These include the compression test, flexure test, shear test, open hole tension test, and compression after impact test. The article describes three distinct fracture modes, namely, crack opening mode, shearing mode, and tearing mode. It presents an overview of fatigue testing and fatigue damage mechanisms of composite materials and reviews the types of mechanical measurements that can be made during the course of testing to assess fatigue damage. The article concludes with a discussion on the split-Hopkinson pressure bar test.

This article begins with a discussion on fiber-reinforced composite materials and describes the generic behavior and structure/property relationships of composites. The article summarizes lamina properties and presents equations that help in the calculation of lamina properties. Composite laminates are constructed from lamina with uniaxial fiber orientation and frequently from textile fabrics as well. The article explains the characteristics of symmetric in-plane and through-thickness laminates; asymmetric in-plane and symmetric through-thickness laminates; asymmetric laminates; and curved laminates. It provides information on controlled thermal expansion composites, metal-matrix composites, and ceramic-matrix composites. The article illustrates the types of bonded joints and concludes with a discussion on design for manufacturing.

One of the key attributes of continuous fiber-reinforced ceramic composites (CFCCs) is their ability to undergo inelastic straining upon mechanical loading. This article reviews the mechanics of inelastic deformation and fracture of CFCCs, as needed for the development of damage-tolerant failure prediction methodologies for use in engineering design. It outlines a general framework for the description of fracture in structural materials in the presence of notches and cracks. The article describes the common classes of fracture behavior of CFCCs and presents the constitutive laws needed to describe crack-tip inelasticity. It demonstrates the effects of inelasticity on crack-tip stress fields and addresses the environmental degradation effects on damage tolerance.

This article presents a comprehendable and comprehensive physics-based approach for characterizing the strength of fiber-reinforced polymer composites. It begins with background information on the goals and attributes of this method. The article then addresses the characterization of fiber failures in laminates, because these are at the highest strengths that can be attained and, therefore, are usually the design objective. An exception would be if the design goal is to maximize energy absorption, rather than static strength. The discussion proceeds to situations in which the matrix fails first, either by intent, by design error, or because of impact damage. The state of the modeling propagation and arrest of matrix damage follows. Comparisons of this physics-based approach are then made to empirically based failure theories.

This article explores the possibilities and limitations imposed by manufacturing processes and materials. Detailed design rules for the processes are presented. The article lists the main features of process groups in a tabular form. The physical characteristics and ratings of relative cost and production factors are also tabulated. The process groups include casting; deformation; powder processing; machining; noncutting; joining; ceramic, glass, and polymer processing; and composites manufacturing.

This article focuses on the relationships among material properties and material structure. It summarizes the fundamental characteristics of metals, ceramics, and polymers. The article provides information on the crystal structure, the atomic coordination, and crystalline defects. It discusses the relevance of the properties to design. The article describes the common means for increasing low-temperature strength and presents an example that shows structure-property relationships in nickel-base superalloys for high-temperature applications. The relationships of microstructure with low-temperature fracture, high-temperature fracture, and fatigue failure are also discussed.

This article discusses the methods of analyzing the directional dependence of the mechanical properties of composites, especially those perpendicular to the major plane of the laminate. It provides a description of the common indirect load cases and direct out-of-plane load cases. The article concludes with a discussion on composite materials that are reinforced in the z-direction (also known as three-dimensional, or 3-D composites).

This article describes methods for analyzing impact-damaged composites in the aircraft industry. These include C-scan and x-radiography methods and optical microscopy. The article reviews brittle-matrix composite and tough-matrix composite failures. It explains the different types of composite failure mechanisms such as thermoplastic-matrix composite failure mechanisms, untoughened thermoset-matrix composite failure mechanisms, toughened thermoset-matrix composite failure mechanisms, dispersed-phase and rubber-toughened thermoset-matrix composite failure mechanisms, and particle interlayer-toughened composite failure mechanisms.

This article provides a discussion on the mechanical properties of metals, ceramics, and polymers and fiber-reinforced polymer composites at low temperatures. It reviews the factors to be considered in tensile and compression testing of these materials. The article details the equipment used for low-temperature tensile and compression tests with illustrations. It concludes with a discussion on the various test methods and their ASTM standard for compression and tension testing.

Mechanical properties are often the most important properties in the design and selection of engineering plastics. Temperature, molecular structure, crystallinity, viscoelasticity, and effects of environment, fillers and reinforcements are considered as the basic factors affecting the mechanical properties of engineering plastics. The testing methods for determining mechanical properties, including stress-strain test, modulus-directed tensile test, strength test, strength-directed tensile test, impact test, and dynamic mechanical test are discussed.

Carbon-carbon composites (CCCs) are introduced in fields that require their high specific strength and stiffness, in combination with their thermoshock resistance, chemical resistance, and fracture toughness, especially at high temperatures. The use of CCCs has expanded as the price of carbon fibers has dropped and their mechanical properties have increased. This article begins with an overview of the carbon conversion processes, fiber properties and microstructures, and interfacial bonding and environmental interaction of carbon fibers, followed by a detailed discussion on the various techniques available for processing CCCs for specific applications, including preform fabrication (fiber weaving), densification, application of protective coatings, and joining. The article closes with a description of the mechanical and physical properties and applications of CCCs. The main applications of CCCs, in terms of money and mass, are in the military, space, and aircraft industries.

This article reviews the abrasive and adhesive wear failure of several types of reinforced polymers, including particulate-reinforced polymers, short-fiber reinforced polymers (SFRP), continuous unidirectional fiber reinforced polymers (FRP), particulate-filled composites, mixed composites (SFRP and particulate-filled), unidirectional FRP composites, and fabric reinforced composites. Friction and wear performance of the composites, correlation of performance with various materials properties, and studies on wear-of failure mechanisms by scanning electron microscopy are discussed for each of these types.