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Image
Published: 01 January 2001
Fig. 1 Schematic diagram of the fiber-matrix interphase and some of the factors that contribute to its formation. Source: Ref 2
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Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003374
EISBN: 978-1-62708-195-5
... Abstract Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy...
Abstract
Fiber-matrix adhesion is a variable to be optimized in order to get the best properties and performance in composite materials. This article schematically illustrates fiber matrix interphase for composite materials. It discusses thermodynamics of interphase in terms of surface energy, contact angle, work of adhesion, solid surface energy, and wetting and wicking. The article describes the change in interphase depending on the reinforcing fiber such as glass fiber, polymeric fiber, and carbon fiber. It emphasizes fiber-matrix adhesion measurements by direct methods, indirect methods, and composite laminate tests. The effects of interphase and fiber-matrix adhesion on composite mechanical properties, such as composite on-axis properties, composite off-axis properties, and composite fracture properties, are also discussed.
Image
Published: 01 January 2001
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003469
EISBN: 978-1-62708-195-5
... (CFCCs) is complicated by the complex structure of the composite material. To perform successfully (that is, to exhibit damage tolerance without undergoing catastrophic brittle failure), CFCCs often must incorporate three constituents (fiber, matrix, interphase between the fiber and matrix) for use...
Abstract
Interpretation of failures of ceramic-matrix composites, and in particular continuous fiber reinforced ceramic-matrix composites is complicated by the complex structure of the composite material. This article describes the failure characteristics and evidence of failure mechanisms of these composites, with illustrations.
Image
Published: 01 January 2001
Fig. 5 Fracture surface of A-4/epoxy [±45] 3S composites, illustrating the different nature of the failure mode and interphase properties. The fiber-matrix adhesion decreases in the order AS-4C > AS-4 > AU-4. AU-4 and AS-4 exhibit interfacial failure modes; AS-4C fails in a matrix
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Image
Published: 01 January 2001
Fig. 1 Scanning electron micrograph of a CMC with a thick interphase (Nicalon fibers, SiC-BN-SiC interphase, and ZrTiO 4 matrix). Source: Ref 1
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Image
Published: 01 January 2001
Fig. 8 Matrix microcracking due to cyclic fatigue loading of Nicalon fiber reinforced SiC-matrix composites with carbide interphase. Source: Ref 8
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Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003430
EISBN: 978-1-62708-195-5
... as the solution to high-temperature materials problems, existing CMCs may, in fact, also need protection themselves to survive particularly aggressive environments, or for other reasons. Most current CMCs are not stable for long periods in environments that attack the fiber-matrix interphase material. For example...
Abstract
Post-processing includes various processes that might be required to produce finished components from the ceramic-matrix composites (CMC) materials. The processes consist of machining or finishing operations, coating, joining, assembly operations, and nondestructive evaluation of CMCs and its components. This article discusses the specific needs for science and technology in these areas relative to the goal of employing CMCs in a variety of applications.
Image
Published: 01 January 2001
Fig. 6 Fracture mirrors on pulled-out fiber fracture surfaces of Nicalon fiber reinforced SiC-matrix composites with carbide interphase. (a) 298 K. (b) 800 K. (c) 1200 K. Source: Ref 6
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Image
Published: 01 January 2001
Fig. 7 Changes in macroscopic fracture with increasing temperatures. Fracture mirrors on pulled-out fiber fracture surfaces of Nicalon fiber reinforced Al 2 O 3 -matrix composites with boron nitride interphase. (a) 293 K. (b) 1073 K. (c) 1273 K. Source: Ref 7
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Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003839
EISBN: 978-1-62708-183-2
... Applied potential E pit Pitting potential g Gaseous state Gr Graphite Gr E Graphite electrode with fiber ends exposed HP Hot pressed i Current density i corr Corrosion current density i galv Galvanic current density l Liquid state MMC Metal-matrix...
Abstract
This article begins with the discussion on the background of metal-matrix composites (MMC) and moves into a broad description of the general parameters affecting the corrosion of MMC. It discusses the primary sources of MMC corrosion that include galvanic corrosion between MMC constituents, chemical degradation of interphases and reinforcements, microstructure-influenced corrosion, and processing-induced corrosion. The article elaborates on the corrosion behavior of specific aluminum, magnesium, titanium, copper, stainless steel, lead, depleted uranium, and zinc MMCs systems. It concludes with a description on the corrosion control of MMCs using protective coatings and inhibitors.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003351
EISBN: 978-1-62708-195-5
... are the most important with respect to composite performance, as in the properties of tensile strength and stiffness of a unidirectional composite in the fiber direction. However, other aspects of composite performance depend more strongly on matrix properties, such as the maximum upper-use temperature...
Abstract
This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009079
EISBN: 978-1-62708-177-1
... resin cure shrinkage due to less fiber constraint. However, it has also been shown that initiation of microcracking is increased when the individual fiber spacing is decreased (or clustered) and/or there is a higher modulus interphase ( Ref 14 ). These factors, along with lower fiber-matrix adhesion...
Abstract
This article describes the microcrack analysis of composite materials using bright-field illumination, polarized light, dyes, dark-field illumination, and epi-fluorescence.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009084
EISBN: 978-1-62708-177-1
... is dependent on the matrix chemistry and fiber reinforcement ( Ref 2 , 3 ). The changes in chemical composition at the fiber-matrix interface and interphase region can be more susceptible to degradation than the bulk matrix ( Ref 4 ). Also, fiber orientation is known to influence the degradation behavior...
Abstract
Polymer composite materials are subject to degradation if not appropriately protected from the environment. This article describes the effects of heat and atomic oxygen and ultraviolet-light on composite material surfaces, with illustrations.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009082
EISBN: 978-1-62708-177-1
... on the formation of spherulites in high-temperature thermoplastic-matrix carbon-fiber-reinforced composites. It also describes the microstructural analysis of a bio-based thermosetting-matrix natural fiber composite system. bio-based thermosetting-matrix natural fiber composites cooling-rate crystal growth...
Abstract
Microstructural analysis of the composite matrix is necessary to understand the performance of the part and its long-term durability. This article focuses on the microstructural analysis of engineering thermoplastic-matrix composites and the influence of cooling rate and nucleation on the formation of spherulites in high-temperature thermoplastic-matrix carbon-fiber-reinforced composites. It also describes the microstructural analysis of a bio-based thermosetting-matrix natural fiber composite system.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003372
EISBN: 978-1-62708-195-5
..., and matrices. The term CVI has been used to refer to the process for deposition of interphase and matrix in fiber-reinforced composites. Although the CVI process has been used to produce many carbides, nitrides, borides, and oxides, its use to prepare SiC is most widely known ( Ref 4 , 5 , and 6...
Abstract
This article focuses on the process methods and matrix chemistries of ceramic-matrix composites. These methods include pressure-assisted densification, chemical vapor infiltration, melt infiltration, polymer infiltration and pyrolysis, and sol-gel processing. The article discusses the use of a ceramic, preceramic, or metal phase as a fluid or vapor phase reactant to form the matrix. Emphasis is placed on microstructural features that influence ultimate composite properties.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003033
EISBN: 978-1-62708-200-6
... Abstract This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers...
Abstract
This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003381
EISBN: 978-1-62708-195-5
.... Degradation Mechanisms and Failure Modes An understanding of the degradation mechanisms and failure modes is a critical part of using accelerated aging to predict long-term behavior of the material. Effects can be seen in the fiber, in the matrix, and at the interface or interphase between. While...
Abstract
Hygrothermal behavior of cured composite materials relates to the combined and commonly synergistic effects of moisture absorption and temperature on various physical, chemical and mechanical properties. This article focuses on the influence of resins or matrices, reinforcements, processing, and diffusion on hygrothermal behavior of polymer-matrix composites and provides an outline on general considerations in assessing them. It discusses the hygrothermal testing and conditioning of polymer-matrix composites to assess fundamental hygrothermal behavior. The article provides information on the accelerated aging process for understanding the degradation mechanisms and failure modes in composites. It also describes the effect of moisture absorption on mechanical properties of polymer-matrix composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003465
EISBN: 978-1-62708-195-5
... factors, such as tensile failure (dominated by fiber properties) and fiber/resin interface or interphase problems (e.g., failures in 90° plies). Thermal analysis is of limited use for such failures. However, in failure modes sensitive to the properties of the matrix resin, thermal analysis can help...
Abstract
This article focuses on various thermal analysis techniques used to verify the cure of a polymer composite. The techniques include differential scanning calorimetry (DSC), modulated DSC, thermomechanical analysis, dynamic mechanical analysis, and dielectric analysis. The article also provides an overview of the composite failure modes affected by matrix resin and testing approach.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0009075
EISBN: 978-1-62708-177-1
... preparation stains WHEN VIEWING A POLISHED fiber-reinforced composite specimen, there are many factors to consider. The composite constituents (such as matrix and fiber type), the capability of the microscope, and the type of information that is desired will play an important role in the analysis...
Abstract
The analysis of composite materials using optical microscopy is a process that can be made easy and efficient with only a few contrast methods and preparation techniques. This article is intended to provide information that will help an investigator select the appropriate microscopy technique for the specific analysis objectives with a given composite material. The article opens with a discussion of macrophotography and microscope alignment, and then goes on to describe various illumination techniques that are useful for specific analysis requirements. These techniques include bright-field illumination, dark-field illumination, polarized-light microscopy, interference and contrast microscopy, and fluorescence microscopy. The article also provides a discussion of sample preparation materials such as dyes, etchants, and stains for the analysis of composite materials using optical microscopy.
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