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Book Chapter
Series: ASM Handbook
Volume: 22A
Publisher: ASM International
Published: 01 December 2009
DOI: 10.31399/asm.hb.v22a.a0005440
EISBN: 978-1-62708-196-2
... Abstract This article presents a diagramatic representation of a periodic system that illustrates the fundamental alloying nature of iron for ferrous metallurgists. periodic system ferrous metallurgists alloying iron The basic principles of alloying were applied to develop...
Abstract
This article presents a diagramatic representation of a periodic system that illustrates the fundamental alloying nature of iron for ferrous metallurgists.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001022
EISBN: 978-1-62708-161-0
... are primary considerations. However, methods must be found that achieve these benefits at lower cost. The goal of ferrous metallurgists, therefore, has been to achieve similar properties in steel forgings in the as-forged condition, that is, without subsequent heat treatment. Unfortunately...
Abstract
Two high-strength low-alloy (HSLA) families, acicular-ferrite steels and pearlite-reduced steels, contain microalloying additions of vanadium and niobium. Vanadium, niobium, and titanium combine preferentially with carbon and/or nitrogen to form a fine dispersion of precipitated particles in the steel matrix. This article summarizes the metallurgical effects of vanadium, niobium, molybdenum, and titanium. The metallurgical fundamentals were first applied to forgings in the early 1970s. The ultimate strength of first- and second-generation microalloy steels is adequate for many engineering applications, but these steels do not achieve the toughness of conventional quenched and tempered alloys under normal hot-forging conditions. Third-generation microalloy steels differ from their predecessors in that they are direct quenched from the forging temperature to produce microstructures of lath martensite with uniformly distributed temper carbides. Without subsequent heat treatment, these materials achieve properties, including toughness, similar to those of standard quenched and tempered steels.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006320
EISBN: 978-1-62708-179-5
... connection led to the belief that the metallurgist had a direct link to the divine, if not of divine origin himself. It elevated the social status of the early metallurgist in the tribal hierarchy to that of a chief or shaman. Metalworkers sometimes rose to the level of royalty. Genghis Khan was a simple...
Abstract
This article provides a short time travel of the evolution of cast iron from witchcraft to virtual cast iron, a road paralleled by the gigantic stride from a low-quality, corrupt metal to the high-tech material that it is today. It presents a chronological list of developments and use of cast iron during prehistory, antiquity, and the medieval ages in a table. The earliest successful iron founding is generally credited to the ancient Mesopotamian civilizations many centuries before Christ. The article discusses the evolution of early cast iron in Mesopotamia and China, as well as in Europe in the medieval ages. It provides information on the applications of cast iron as a high-tech, economical, and modern material.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003162
EISBN: 978-1-62708-199-3
... hardfacing materials are normally classified as steels or low-alloy ferrous materials, high-chromium white irons or high-alloy ferrous materials, carbides, nickel-base alloys, or cobalt-base alloys. A few copper-base alloys are sometimes used for hardfacing applications, but for the most part, hardfacing...
Abstract
Hardfacing is defined as the application of a wear-resistant material, in depth, to the vulnerable surfaces of a component by a weld overlay or thermal spray process Hardfacing materials include a wide variety of alloys, carbides, and combinations of these materials. Iron-base hardfacing alloys can be divided into pearlitic steels, austenitic (manganese) steels, martensitic steels, high-alloy irons, and austenitic stainless steel. The types of nonferrous hardfacing alloys include cobalt-base/carbide-type alloys, laves phase alloys, nickel-base/boride-type alloys, and bronze type alloys. Hardfacing applications for wear control vary widely, ranging from very severe abrasive wear service, such as rock crushing and pulverizing to applications to minimize metal-to-metal wear. This article discusses the types of hardfacing alloys, namely iron-base alloys, nonferrous alloys, and tungsten carbides, and their applications and advantages.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003520
EISBN: 978-1-62708-180-1
... a strong influence on the manner in which an examination is performed. For example, the civil or mechanical engineer may perform a very careful examination of the stresses and loads causing the failure but may not devote much attention to the metallurgical factors. By the same token, the metallurgist may...
Abstract
This article outlines the basic steps to be followed and the range of techniques available for failure analysis, namely, background data assembling, visual examination, microfractography, chemical analysis, metallographic examination, electron microscopy, electron microprobe analysis, X-ray techniques, and simulations. It also describes the steps for analyzing the data, preparing the report, preservation of evidence, and follow-up on recommendations.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005186
EISBN: 978-1-62708-187-0
... manufactured goods and in all capital goods machinery used in manufacturing. Some of the major market areas of castings are listed in Table 1 ( Ref 2 ). Major markets for metal castings Table 1 Major markets for metal castings Ferrous castings Gray iron Ingot molds Construction...
Abstract
Casting is one of the most economical and efficient methods for producing metal parts. In terms of scale, it is well suited for everything from low-volume, prototype production runs to filling global orders for millions of parts. Casting also affords great flexibility in terms of design, readily accommodating a wide range of shapes, dimensional requirements, and configuration complexities. This article traces the history of metal casting from its beginnings to the current state, creating a timeline marked by discoveries, advancements, and influential events. It also lists some of the major markets where castings are used.
Book: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002349
EISBN: 978-1-62708-193-1
... or quasicleavage, and intergranular failure. Certain fundamental characteristics of fracture observed in precipitation-hardening alloys, ferrous alloys, titanium alloys are also discussed. cleavage fracture crack growth cracking creep dimpled rupture ductile striation formation failure analysis...
Abstract
The cracking process occurs slowly over the service life from various crack growth mechanisms such as fatigue, stress-corrosion cracking, creep, and hydrogen-induced cracking. Each of these mechanisms has certain characteristic features that are used in failure analysis to determine the cause of cracking or crack growth. This article discusses the macroscopic and microscopic basis of understanding and modeling fracture resistance of metals. It describes the four major types of failure modes in engineering alloys, namely, dimpled rupture, ductile striation formation, cleavage or quasicleavage, and intergranular failure. Certain fundamental characteristics of fracture observed in precipitation-hardening alloys, ferrous alloys, titanium alloys are also discussed.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005192
EISBN: 978-1-62708-187-0
... Abstract This article reviews the solubilities of the common gases present in ferrous metals, such as cast irons, and nonferrous metals, such as aluminum, copper, magnesium, and their alloys. The kinetics of the relevant reactions, reactions during solidification, and possible methods...
Abstract
This article reviews the solubilities of the common gases present in ferrous metals, such as cast irons, and nonferrous metals, such as aluminum, copper, magnesium, and their alloys. The kinetics of the relevant reactions, reactions during solidification, and possible methods of control or removal of the dissolved gases are discussed. The most common method for removing hydrogen from aluminum, copper, and magnesium is inert gas flushing. The article provides information on techniques to overcome gas porosity in ferrous and nonferrous metals.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006228
EISBN: 978-1-62708-163-4
... are changed slightly, as indicated by the dashed lines in Fig. 2 In ferrous alloys, iron is the base element, but carbon and other alloying elements are frequently used. Based on carbon content, there are three types of ferrous alloys: irons, steels, and cast irons. Commercially pure iron contains less...
Abstract
Eutectoid and peritectoid transformations are classified as solid-state invariant transformations. This article focuses primarily on the structures from eutectoid transformations with emphasis on the classic iron-carbon system of steel. It reviews peritectoid phase equilibria that are very common in several binary systems. The addition of substitutional alloying elements causes the eutectoid composition and temperature to shift in the iron-carbon system. The article graphically illustrates the effect of various substitutional alloying elements on the eutectoid transformation temperature and effective carbon content. The partitioning effect of substitutional alloying elements, such as chromium, manganese, and silicon, in pearlitic steel is also illustrated.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006312
EISBN: 978-1-62708-179-5
... castings. compacted graphite iron graphite morphology microstructure tensile strength MARCH 20, 1948, IS WELL KNOWN to cast iron metallurgists as the date on which K.D. Millis, A.P. Gagnebin, and N.B. Pilling filed the first patent application for the production of ductile iron. The patent...
Abstract
Compacted graphite iron (CGI) invariably includes some nodular (spheroidal) graphite particles, giving rise to the definition of the microstructure in terms of percent nodularity. This article discusses the graphite morphology and mechanical and physical properties of CGI. The mechanical and physical properties of CGI with ferritic and pearlitic matrix structures are summarized in a table. The article describes the standards for CGI, with the definition of the grades based on the minimum tensile strength. It also provides information on the applications of compacted graphite iron castings.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001739
EISBN: 978-1-62708-178-8
... 7 2 − + 14H + + 6 e − → 2Cr 3+ + 7H 2 O F H 2 SO 3 + H 2 O → SO 4 2 − + 4H + + 2 e − In reaction A, the ferric ion (+ III oxidation state) gains an electron, reducing it to ferrous ion (+ II oxidation state). Similarly, in reaction D, iron(+ II) loses...
Abstract
This article provides information on basic chemical equilibria, wet analytical chemistry, and the appropriateness of classical wet methods. It focuses on nonoxidizing acids and oxidizing acids. The article includes information on the qualitative methods used to identify materials by wet chemical reaction. Gravimetry, in which a chemical species is weighed; titrimetry, which involves volume measurement of a liquid reactant; and a host of separation techniques, which require diverse forms of laboratory manipulation, are discussed. The article briefly describes the partitioning of oxidation states as well as those applications in surface studies and rapid material identification in which chemical techniques have proved useful.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003751
EISBN: 978-1-62708-177-1
... before they need to be replaced. Years ago many turbine rotors failed catastrophically, creating costly damage, loss of life, and a complete shutdown of the power plant. To prevent this from happening, metallurgists and metallographers were called on to predict the useful life of these components so...
Abstract
This article discusses the advantages and disadvantages of field metallography and describes the important material characteristics and other aspects to be considered before performing any metallographic procedure. It investigates the various stages of sample preparation in the metallographic laboratory: grinding, polishing, etching, preparing a replica, and obtaining a small sample. The article also illustrates the applications of field metallography with case studies.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001008
EISBN: 978-1-62708-161-0
... evolving to exploit the best features of each type of steel. The following sections in this article describe in detail several important ferrous microstructures and the steels and processing methods used to produce them. Pearlite and Bainite Pearlite is the name given to the microstructure produced...
Abstract
This article describes microstructures and microstructure-property relationships in steels. It emphasizes the correlation of microstructure and properties as a function of carbon content and processing in low-alloy steels. The article discusses the iron-carbon phase diagram and the phase transformations that change the structure and properties at varying levels of carbon content. Microstructures described include pearlite, bainite, proeutectoid ferrite and cementite, ferrite-pearlite, and martensite. The article depicts some of the primary processing steps that result in ferrite-pearlite microstructures. It shows the range of hardness levels which may be obtained by tempering at various temperatures as a function of the carbon content of the steel. To reduce the number of processing steps associated with producing quenched and tempered microstructures, new alloying approaches have been developed to produce high-strength microstructures directly during cooling after forging.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005822
EISBN: 978-1-62708-165-8
... the practices employed in the cold treatment of steel and presents some of the results of using cryogenic treatment to enhance steel properties. Cold Treatment of Steel Cold treatment of steel consists of exposing the ferrous material to subzero temperatures to either impart or enhance specific...
Abstract
Cold treating of steel can be used to enhance the transformation of austenite to martensite and improve the stress relief of castings and machined parts. Cryogenic treatment of steel is a distinct process that uses extreme cold to modify the performance of materials. This article explains the practices employed and equipment used in the cold treatment of steel. It also presents the results of using cryogenic treatment to enhance steel properties.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003803
EISBN: 978-1-62708-177-1
... produced by early Chinese metallurgists and used for many purposes, including statuary, bells, and coinage. In modern times, white cast irons are not much used, and then normally only as a precursor for malleable iron. Furthermore, this early material can have sulfur and/or phosphorus contents that are far...
Abstract
Archaeometallurgists use metallography to reveal and interpret the microstructures of objects, in conjunction with the results of their chemical analyses and microanalyses. This article describes a number of special problems that occur while performing metallographic analyses on archaeological materials. It also presents case studies, with examples that illustrate situations where metallography has contributed to archaeometallurgical studies.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006221
EISBN: 978-1-62708-163-4
... circumstances. As such, alloy phase diagrams are useful to metallurgists, materials engineers, and materials scientists in four major areas: Development of new alloys for specific applications Fabrication of these alloys into useful configurations Design and control of heat treatment procedures...
Abstract
The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can exist as a solid, liquid, and/or gas, depending on the specific combination of temperature and pressure. It describes the accomplishment of conversion between weight percentage and atomic percentage in a binary system by the use of formulas. The article analyzes the effects of alloying on melting/solidification and on solid-state transformations. It explains the construction of phase diagrams by the Gibbs phase rule and the Lever rule. The article also reviews the various types of alloy systems that involve solid-state transformations. It concludes with information on the sources of phase diagram.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003723
EISBN: 978-1-62708-177-1
... be assisted by the use of electron microscopy, which provides higher resolution than light (optical) microscopes. For example, pearlite is often unresolved when examined under a light microscope, appearing as a more or less uniform or slightly mottled gray phase ( Fig. 3a ). The experienced ferrous...
Abstract
This article introduces basic physical metallurgy concepts that may be useful for understanding and interpreting variations in metallographic features and how processing affects microstructure. It presents some basic concepts in structure-property relationships. The article describes the use of equilibrium binary phase diagrams as a tool in the interpretation of microstructures. It reviews an account of the two types of solid-state phase transformations: isothermal and athermal. The article discusses isothermal transformation and continuous cooling transformation diagrams which are useful in determining the conditions for proper heat treatment (solid-state transformation) of metals and alloys. The influence of the mechanisms of phase nucleation and growth on the morphology, size, and distribution of grains and second phases is also described.
Book Chapter
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003721
EISBN: 978-1-62708-177-1
... structures and macrostructure of metals and alloys. ferrous metals macrostructure multiphase microstructure nonferrous metals single-phase microstructure substructure FOR MORE THAN A CENTURY, dating back to the pioneering contributions of Henry Clifton Sorby, metallurgists have not been...
Abstract
This article provides information on the general structural features and origins of metals. The characteristic structural features of single-phase metals and alloys, such as grain structure and substructure, are discussed. The article also describes the major types of multiphase structures and macrostructure of metals and alloys.
Book Chapter
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006339
EISBN: 978-1-62708-179-5
... AUSTEMPERED DUCTILE IRON (ADI) results from a specialty heat treatment of ductile cast iron. Strength improvements in combination with excellent toughness can be realized by using this process. Austempering is an isothermal heat treatment that, when applied to ferrous materials, produces a structure...
Abstract
Austempered ductile iron (ADI) results from a specialty heat treatment of ductile cast iron. This article discusses the production of austempered ductile iron by heat treatment. The austempered ductile iron grades, according to ISO 17804 and EN 1564, are presented in a table. For economic reasons, or to avoid metallurgical problems, combinations of alloys are often used to achieve the desired hardenability in austempered ductile iron. The article provides information on the alloy combinations for austempered ductile iron. The mechanical properties, fracture toughness, fatigue, and abrasion resistance of the austempered ductile iron are discussed. The article concludes with information on the applications for austempered ductile iron.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002467
EISBN: 978-1-62708-194-8
... of materials and because the interdisciplinary field of materials science was not yet born, the engineer was, most likely, a metallurgist with little concern for materials other than metals. For such an individual the one-volume Metals Handbook largely filled his needs for data and tutorial reviews. How...
Abstract
This article examines material property data and the information needs at various points in the design, manufacture, and use cycle. It contains a table that lists the various sources of materials data. The article describes locating media for sources of data such as suppliers of databases and internet. It discusses the types of sources of data, including computer readable media, data centers, and print media. The article also reviews the methods for evaluation and interpretation of data and examines the processes of obtaining and reporting test data.
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