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George F. Vander Voort
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George Krauss
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Debbie Aliya, Steve Lampman
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Bruce L. Bramfitt, Samuel J. Lawrence
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George F. Vander Voort, Gabriel M. Lucas, Elena P. Manilova
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ferritic structural alloys
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Book Chapter
Solid-State Transformations
Available to PurchaseBook: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006228
EISBN: 978-1-62708-163-4
.... Below 910 °C (1673 °F), it again has a bcc crystal structure called ferrite, designated as α. The fact that steel can be hardened is a direct result of the eutectoid reaction in iron-carbon alloys. Just as a eutectic reaction involves the decomposition of a liquid solution, a eutectoid reaction...
Abstract
Eutectoid and peritectoid transformations are classified as solid-state invariant transformations. This article focuses primarily on the structures from eutectoid transformations with emphasis on the classic iron-carbon system of steel. It reviews peritectoid phase equilibria that are very common in several binary systems. The addition of substitutional alloying elements causes the eutectoid composition and temperature to shift in the iron-carbon system. The article graphically illustrates the effect of various substitutional alloying elements on the eutectoid transformation temperature and effective carbon content. The partitioning effect of substitutional alloying elements, such as chromium, manganese, and silicon, in pearlitic steel is also illustrated.
Book Chapter
Microstructure and Machinability
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003191
EISBN: 978-1-62708-199-3
...; 263 HB. (h) White iron. Pearlite + carbide; 550 HB Figures 3 and 4 illustrate typical microstructures of ductile and malleable irons. The annealed structures of both types have a matrix of practically all ferrite and can be machined at relatively high speeds comparable to those used...
Abstract
An understanding of the influence of microstructure on machinability can provide an insight into more efficient machining and the correct solution to problems. Providing numerous microstructures to depict examples, this article describes the relationship between the microstructure and machinability of cast irons, steels, and aluminum alloys. It presents data on hardness values and the effect of the matrix microstructure of cast iron on tool life. It also explains how a higher inclusion count improves the machinability of steels and why aluminum alloys can be machined at very high speeds.
Book Chapter
Typical Microstructures of Iron-Base Alloys
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003246
EISBN: 978-1-62708-199-3
... and complex mixtures of constituents (single or combination of two phases) that are encountered in iron-base alloys and the complex structure that is observed in these microstructures. The single-phase constituents discussed in the article include austenite, ferrite, delta ferrite, cementite, various alloy...
Abstract
This article is a pictorial representation of commonly observed microstructures in iron-base alloys (carbon and alloy steels, cast irons, tool steels, and stainless steels) that occur as a result of variations in chemical analysis and processing. It reviews a wide range of common and complex mixtures of constituents (single or combination of two phases) that are encountered in iron-base alloys and the complex structure that is observed in these microstructures. The single-phase constituents discussed in the article include austenite, ferrite, delta ferrite, cementite, various alloy carbides, graphite, martensite, and a variety of intermetallic phases, nitrides, and nonmetallic inclusions. The article further describes the two-phase constituents including, tempered martensite, pearlite, and bainite and nonmetallic inclusions in steel that consist of two or more phases.
Book Chapter
Microstructures, Processing, and Properties of Steels
Available to PurchaseSeries: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001008
EISBN: 978-1-62708-161-0
... been developed to produce high-strength microstructures directly during cooling after forging. bainite carbon steels cementite ferrite iron-carbon phase diagram low-alloy steels martensite pearlite quenched and tempered microstructures structure-property relationships...
Abstract
This article describes microstructures and microstructure-property relationships in steels. It emphasizes the correlation of microstructure and properties as a function of carbon content and processing in low-alloy steels. The article discusses the iron-carbon phase diagram and the phase transformations that change the structure and properties at varying levels of carbon content. Microstructures described include pearlite, bainite, proeutectoid ferrite and cementite, ferrite-pearlite, and martensite. The article depicts some of the primary processing steps that result in ferrite-pearlite microstructures. It shows the range of hardness levels which may be obtained by tempering at various temperatures as a function of the carbon content of the steel. To reduce the number of processing steps associated with producing quenched and tempered microstructures, new alloying approaches have been developed to produce high-strength microstructures directly during cooling after forging.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001341
EISBN: 978-1-62708-173-3
... by the weld thermal cycles and by the welding environment. The article provides information on welds in other alloy systems such as stainless steels and aluminum-base, nickel-base, and titanium-base alloys. aluminum alloys ferritic steel weldments fusion welding heat treatment nickel alloys solid...
Abstract
Solid-state transformations occurring in a weld are highly nonequilibrium in nature and differ distinctly from those experienced during casting, thermomechanical processing, and heat treatment. This article focuses on welding metallurgy of fusion welding of steels and highlights the fundamental principles that form the basis of many of the developments in steels and consumables for welding. Examples in the article are largely drawn from the well-known and relatively well-studied case of ferritic steel weldments to illustrate the special physical metallurgical considerations brought about by the weld thermal cycles and by the welding environment. The article provides information on welds in other alloy systems such as stainless steels and aluminum-base, nickel-base, and titanium-base alloys.
Book Chapter
Metallography and Microstructures of Weldments
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003785
EISBN: 978-1-62708-177-1
... by discontinuities in the transformation structure. Ferrous Alloys In low-alloy steels, the solidification packet or austenite grain size may be marked by continuous veins of proeutectoid ferrite ( Fig. 13 ). The solidification mode is often difficult to determine because of solid-state phase transformations...
Abstract
This article provides a review of metallographic procedures and techniques for analyzing the microstructure of fusion welded joints. It discusses sample preparation, the use of backing plates, and common sectioning methods. It identifies the various types of defects that can occur in arc welded metals, organizing them according to the sectioning method by which they are observed. It describes the relationship between weld bead morphology and sectioning direction and its effect on measurement error. The article examines micrographs from stainless steel, aluminum, and titanium alloy joints, highlighting important details such as solidification and solid-state transformation structures and what they reveal about the welding process. Besides arc welding, it also discusses laser and electron beam welding methods, resistance and spot welding, and the welding of dissimilar metals.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006067
EISBN: 978-1-62708-175-7
... , duplex , and precipitation-hardening . Because each family of alloys is based on a distinct crystal structure, the physical and mechanical characteristics of each family of alloys are to a large extent similar. At room temperature, unalloyed iron exists in a body-centered cubic (bcc) ferritic...
Abstract
Stainless steels are primarily alloys of iron and chromium. They are grouped into five families, primarily based on their microstructure: ferritic, austenitic, martensitic, duplex, and precipitation hardening. Three out of the five families of stainless steels, namely, austenitic, ferritic, and martensitic, are well suited for manufacture via conventional powder metallurgy (PM) processes. This article presents the iron-chromium partial phase diagram to illustrate the changes in the temperature range when pure iron is alloyed with chromium. It describes AISI and UNS numbering systems, which are used as an identification system for stainless steels. The article tabulates the material designations of stainless steels in accordance with the Metal Powder Industries Federation. It also details the characteristics and chemical composition of wrought and PM stainless steels.
Book Chapter
Introduction to Steel Heat Treatment
Available to PurchaseSeries: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005819
EISBN: 978-1-62708-165-8
... a face-centered (fcc) crystal structure—called austenite or gamma (γ) iron. The existence of these two phases, along with carbon alloying, are fundamental in the heat treatment of steel. One important difference between iron ferrite and austenite is the spacing of iron atoms. The iron atoms...
Abstract
The heat treatment of steel is based on the physical metallurgical principles that relate to its processing, properties, and structure. The microstructures that result from the heat treatment of steel are composed of one or more phases in which the atoms of iron, carbon, and other elements in steel are associated. This article describes the phases of heat treated steel, and provides information on effect of temperature change and the size of carbon atoms relative to that of iron atoms during the heat treatment.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003739
EISBN: 978-1-62708-177-1
... in a lathlike ferritic structure with the transformation morphology and kinetics identical to the formation of upper bainite ( Ref 4 ). This same phenomenon is also observed in nonferrous alloys, either as a nonlamellar aggregate or with only one lathlike product transforming from the parent, although some...
Abstract
This article provides a discussion on the transformations of various categories of bainite in ferrous systems. These include upper bainite, lower bainite, inverse bainite, granular bainite, and columnar bainite. The article also provides information on the bainite transformations in nonferrous systems.
Book Chapter
Physical Metallurgy Concepts in Interpretation of Microstructures
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003723
EISBN: 978-1-62708-177-1
... element is below its solubility limits, it is completely “dissolved” in the host metal and thus forms a solid solution. In contrast, if the concentration of an alloying element exceeds its solubility limit, a new phase forms with a different crystal structure that is more able to cope with the additional...
Abstract
This article introduces basic physical metallurgy concepts that may be useful for understanding and interpreting variations in metallographic features and how processing affects microstructure. It presents some basic concepts in structure-property relationships. The article describes the use of equilibrium binary phase diagrams as a tool in the interpretation of microstructures. It reviews an account of the two types of solid-state phase transformations: isothermal and athermal. The article discusses isothermal transformation and continuous cooling transformation diagrams which are useful in determining the conditions for proper heat treatment (solid-state transformation) of metals and alloys. The influence of the mechanisms of phase nucleation and growth on the morphology, size, and distribution of grains and second phases is also described.
Image
Examples of two-phase stainless steels with various microstructural combina...
Available to PurchasePublished: 01 December 1998
) Austenitic AISI 304, welded. Structure: delta ferrite and austenite (dark). Heat tinted; 500×. (d) Duplex alloy, as cast and annealed. Structure: austenite and ferrite (dark). Tint etched; 200×
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Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001047
EISBN: 978-1-62708-161-0
.... There is usually a small amount of ferrite present in austenitic stainless steel castings, in contrast to the single-phase austenitic structure of the wrought alloys. The presence of ferrite in the castings is desirable for facilitating weld repair, but ferrite also increases resistance to stress-corrosion...
Abstract
This article reviews the properties of cast steels that are specified for liquid corrosion service at temperatures above and below 650 deg C. Stainless steel castings are usually classified based on their resistance to corrosion and heat and generally fall into one category or the other. The article describes alternate methods for classifying cast stainless steels, one is based on grade designations, the other on microstructural analysis. It also addresses heat treatment, pointing out its similarities with the thermal processing of wrought materials, and establishes the importance of mechanical properties in material selection. The article presents information on the selection process and provides a detailed list of heat-resistant cast steels and alloys. It also includes key manufacturing characteristics to aid in foundry and welding-related decisions.
Image
Effect of sintering atmosphere on the phase structures produced in low- and...
Available to PurchasePublished: 30 September 2015
Fig. 1 Effect of sintering atmosphere on the phase structures produced in low- and medium-chromium ferritic stainless steels during sintering. (a) Hydrogen sintering produces ferritic structure for both alloys. (b) Dissociated ammonia sintering leads to extensive martensite formation in low
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Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005613
EISBN: 978-1-62708-174-0
... by the CCT curves, the amount of each transformation product, and the hardness of the final structure are shown. Ac 3 , 788 °C (1450 °F); Ac 1 , 716 °C (1321 °F). F, ferrite; P, pearlite; B, bainite; M, martensite. Source: Ref 1 Special Factors Affecting Transformation Behavior in a Weldment...
Abstract
Solid-state transformations occurring in a weld are highly nonequilibrium in nature and differ distinctly from those experienced during casting, thermomechanical processing, and heat treatment. This article provides a description of the special factors affecting transformation behavior in a weldment. It reviews the heat-affected and fusion zones of single-pass and multi-pass weldments. The article also includes a discussion on the welds in alloy systems, such as stainless steels and aluminum-base, nickel-base, and titanium-base alloys.
Book Chapter
Metallography and Microstructures of Carbon and Low-Alloy Steels
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003763
EISBN: 978-1-62708-177-1
..., the elevated temperature phase of steel is austenite. It is also called gamma (γ) iron and has a face-centered cubic crystal structure. Iron-carbon alloys exist as 100% austenite above the “V”-shaped lines labeled A 3 and A cm and exist as mixtures of austenite and ferrite or austenite and cementite...
Abstract
This article describes the microstructure and metallographic practices used for medium- to high-carbon steels as well as for low-alloy steels. It explains the microstructural constituents of plain carbon and low-alloy steels, including ferrite, pearlite, and cementite. The article provides information on how to reveal the various constituents using proven metallographic procedures for both macrostructural and microstructural examination. Emphasis is placed on the specimen preparation procedures such as sectioning, mounting, grinding, and polishing. The article illustrates the use of proven etching techniques for plain carbon and low-alloy steels.
Book Chapter
Metallography and Microstructures of Stainless Steels and Maraging Steels
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003767
EISBN: 978-1-62708-177-1
... structures vary according to the type of steel, such as ferritic, austenitic, martensitic, precipitation hardenable, or duplex. electropolishing procedures etching techniques grinding devices macroscopic examination maraging steels metallography maraging steel microstructures microscopic...
Abstract
This article describes metallographic preparation and examination techniques for stainless steels and maraging steels. It presents a series of micrographs demonstrating microstructural features of these alloys. Procedures used to prepare stainless steels for macroscopic and microscopic examination are similar to those used for carbon, alloy, and tool steels. Cutting and grinding must be carefully executed to minimize deformation because the austenitic grades work harden readily. The high-hardness martensitic grades that contain substantial undissolved chromium carbide are difficult to polish while fully retaining the carbides. Unlike carbon, alloy, and tool steels, etching techniques are more difficult due to the high corrosion resistance of stainless steels and the various second phases that may be encountered. The microstructures of stainless steels can be quite complex. Matrix structures vary according to the type of steel, such as ferritic, austenitic, martensitic, precipitation hardenable, or duplex.
Book Chapter
Metallurgical Fundamentals of Quenching
Available to PurchaseSeries: ASM Handbook
Volume: 4F
Publisher: ASM International
Published: 01 February 2024
DOI: 10.31399/asm.hb.v4F.a0006995
EISBN: 978-1-62708-450-5
... crystal structures (phases) in the solid state ( Ref 7 ). Depending on temperature, the basic phases of pure iron include alpha-iron (α-Fe), known as ferrite, delta-iron (δ), and gamma-iron (γ), known as austenite ( Fig. 4 ). Alloying with carbon adds another degree of freedom in this thermodynamic system...
Abstract
Steels are among the most versatile materials in modifying their microstructure and properties by heat treatment. This article outlines the basic concepts of physical metallurgy relating to the heat treatment of steel. It considers the phases and microstructures of steel together with the transformations observed and critical temperatures during heat treatment. Additionally, the different types of steels, heat treatments, and their purposes are also discussed.
Book Chapter
Selection of Wrought Austenitic Stainless Steels
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001410
EISBN: 978-1-62708-173-3
... austenite structure is shown on the right side of Fig. 9(a) , where a carbon dioxide laser-beam weld was made over a gas-tungsten arc weld in an alloy of 23Cr-12Ni-balance Fe with a Cr eq /Ni eq ratio of 1.9 ( Ref 26 ). These welds solidify as single-phase ferrite, but subsequently transform...
Abstract
Austenitic stainless steels exhibit a single-phase, face-centered cubic structure that is maintained over a wide range of temperatures. This article reviews the compositions of standard and nonstandard austenitic stainless steels. It summarizes the important aspects of solidification behavior and microstructural evolution that dictate weld-metal ferrite content and morphology. The article describes weld defect formation, namely, solidification cracking, heat-affected zone liquation cracking, weld-metal liquation cracking, copper contamination cracking, ductility dip cracking, and weld porosity. It discusses four general types of corrosive attack: intergranular attack, stress-corrosion cracking, pitting and crevice corrosion, and microbiologically influenced corrosion. The article concludes with information on weld thermal treatments such as preheat and interpass heat treatments and postweld heat treatment.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005790
EISBN: 978-1-62708-165-8
...). Transformation of a cold-worked structure to a stress-relieved, recovered, and recrystallized structure of ferrite and carbide Transformation of a structure of ferrite and carbide to a structure involving globular carbides, of increased coarseness In response “a” from subcritical annealing...
Abstract
This article describes the metallurgy and process specifics of subcritical annealing, which involves heating below the lower critical temperature such that austenite does not form during subcritical annealing. It provides information on the nominal subcritical annealing temperatures of plain carbon, low-alloy and high-alloy steels and temperature-time relations of subcritical annealing. Practical implications for induction annealing and induction normalizing are included. The article concludes by describing induction softening, which softens the threaded area on carburized components such as hypoid pinion gears, to prevent the occurrence of delayed fractures from occurring.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001411
EISBN: 978-1-62708-173-3
... poor toughness, especially in the welded condition. A duplex microstructure with high ferrite content can therefore have poor low-temperature notch toughness, whereas a structure with high austenite content can possess low strength and reduced resistance to Cl SCC ( Ref 5 ). The high alloy content...
Abstract
This article provides information on the base material properties of wrought duplex stainless steels (DSS). These properties include microstructure, alloy grades, mechanical and physical properties, and corrosion resistance. The article reviews the applications and microstructural development of DSS. It describes the factors influencing welding and weldability of the DSS. These factors include preheating, postweld heat treatment, interpass temperature control, welding practices, welding procedure qualification, filler metal requirements, cracking behavior, and loss of properties. The article examines the applicable welding processes such as fusion welding and solid-state welding processes.
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