This article discusses the corrosion resistance of aluminum and aluminum alloys in various environments, such as in natural atmospheres, fresh waters, seawater, and soils, and when exposed to chemicals and their solutions and foods. It describes the forms of corrosion of aluminum and aluminum alloys, including pitting corrosion, intergranular corrosion, exfoliation corrosion, galvanic corrosion, stray-current corrosion, deposition corrosion, crevice corrosion, filiform corrosion, stress-corrosion cracking, corrosion fatigue, and hydrogen embrittlement. The article also presents a short note on aluminum clad products and corrosion at joints.

The purposes and methods of fatigue modeling and simulation in high-cycle fatigue (HCF) regime are to design either failsafe components or components with a finite life and to quantify remaining life of components with pre-existing cracks using fracture mechanics, with the intent of monitoring via an inspection scheme. This article begins with a discussion on the stages of the fatigue damage process. It describes hierarchical multistage fatigue modeling and several key points regarding the physics of crack nucleation and microstructurally small crack propagation in the HCF regime. The article provides a description of the microstructure-sensitive modeling to model fatigue of several classes of advanced engineering alloys. It describes the various modeling and design processes designed against fatigue crack initiation. The article concludes with a discussion on the challenges in microstructure-sensitive fatigue modeling.

This article describes some of the mechanical/ electrochemical phenomena related to the in vivo degradation of metals used for biomedical applications. It discusses the properties and failure of these materials as they relate to stress-corrosion cracking (SCC) and corrosion fatigue (CF). The article presents the factors related to the use of surgical implants and their deterioration in the body environment, including biomedical aspects, chemical environment, and electrochemical fundamentals needed for characterizing CF and SCC. It provides a discussion on the use of metallic biomaterials in surgical implant applications, such as orthopedic, cardiovascular surgery, and dentistry. It addresses the key issues related to simulation of the in vivo environment, service conditions, and data interpretation. Theses include frequency of dynamic loading, electrolyte chemistry, applicable loading modes, cracking mode superposition, and surface area effects. The article describes the fundamentals of CF and SCC, testing methodology, and test findings from laboratory, in vivo, and retrieval studies.

Fatigue failure of engineering components and structures results from progressive fracture caused by cyclic or fluctuating loads. Fatigue is an important potential cause of mechanical failure, because most engineering components or structures are or can be subjected to cyclic loads during their lifetime. This article focuses on fractography of fatigue. It provides an abbreviated summary of fatigue processes and mechanisms: fatigue crack initiation, fatigue crack propagation, and final fracture,. Characteristic fatigue fracture features that can be discerned visually or under low magnification are then described. Typical microscopic features observed on structural metals are presented subsequently, followed by a brief discussion on fatigue in polymers and polymer-matrix composites.

Rolling-contact fatigue (RCF) is a common failure mode in components subjected to rolling or rolling-sliding contact. This article provides a basic understanding of RCF and a broad overview of materials and manufacturing techniques commonly used in industry to improve component life. A brief discussion on coatings to improve surface-initiated fatigue and wear is included, due to the similarity to RCF and the increasing criticality of this failure mode. The article presents a working knowledge of Hertzian contact theory, describes the life prediction of rolling-element bearings, and provides information on physics and testing of rolling-contact fatigue. Processes commonly used to produce bearings for demanding applications are also covered.

Fatigue failures may occur in components subjected to fluctuating (time-dependent) loading as a result of progressive localized permanent damage described by the stages of crack initiation, cyclic crack propagation, and subsequent final fracture after a given number of load fluctuations. This article begins with an overview of fatigue properties and design life. This is followed by a description of the two approaches to fatigue, namely infinite-life criterion and finite-life criterion, along with information on damage tolerance criterion. The article then discusses the characteristics of fatigue fractures followed by a discussion on the effects of loading and stress distribution, and material condition on the microstructure of the material. In addition, general prevention and characteristics of corrosion fatigue, contact fatigue, and thermal fatigue are also presented.

The overarching goal of life-prediction research is to develop models for the various types of time dependencies in the crack-tip damage accumulation that occur in materials subjected to elevated temperatures. This article focuses on describing the models based on creep, oxidation kinetics, evolution of crack-tip stress fields due to creep, oxygen ingress, and change in the microstructure. It also provides a summary of creep-fatigue modeling approaches.

Thermomechanical fatigue (TMF) is the general term given to the material damage accumulation process that occurs with simultaneous changes in temperature and mechanical loading. TMF may couple cyclic inelastic deformation accumulation, temperature-assisted diffusion within the material, temperature-assisted grain-boundary evolution, and temperature-driven surface oxidation, among other things. This article discusses some of the major aspects and challenges of dealing with TMF life prediction. It describes the damage mechanisms of TMF and covers various experimental techniques to promote TMF damage mechanisms and elucidate mechanism coupling interactions. In addition, life modeling in TMF conditions and a practical application of TMF life prediction are presented.

Electrical resistance alloys used to control or regulate electrical properties are called resistance alloys, and those used to generate heat are referred to as heating alloys. This article covers both alloy types, describing the construction and use of resistors as well as heating elements. It also discusses soldering and joining methods, sensitivity and stability factors, and various design coefficients. In addition, it provides a detailed account of the properties and applications of thermostat metals and discusses the design of resistance heaters and their operating ranges.

Copper and copper alloys are widely used because of their excellent electrical and thermal conductivities, outstanding resistance to corrosion, and ease of fabrication, together with good strength and fatigue resistance. This article provides an overview of property and fabrication characteristics, markets, and applications of copper and its alloys. It contains several tables that provide helpful information on the chemical composition, classification, designation, uses, and mechanical properties of wrought copper and copper alloys.

Wear of metals occurs by plastic displacement of surface and near-surface material, and by detachment of particles that form wear debris. This article presents a table that contains the classification of wear. It describes the testing and evaluation of wear and talks about the abrasive wear, lubrication and lubricated wear, and selection of steels for wear resistance. The article discusses the effect of alloying elements, composition, and mechanical properties of carbon and low-alloy steels at elevated temperatures. It talks about the fatigue resistance characteristics of steels, and describes the forms of embrittlement associated with carbon and low-alloy steels. The article provides information on the effect of composition, manufacturing practices, and microstructure on notch toughness of steels. Finally, it explains the effects of alloy elements, inclusion content, microstructure and heat treatment on fracture toughness of steels.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of austenitic stainless steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: fatigue-crack fracture, rock candy fracture, cleavage fracture, brittle fracture, high-cycle fatigue fracture, fatigue striations, hydrogen-embrittlement failure, creep crack propagation, fatigue crack nucleation, intergranular creep fracture, torsional overload fracture, stress-corrosion cracking, and grain-boundary damage of these steels. The austenitic stainless steel components include spring wires, preheater-reactor slurry transfer lines and gas lines of coal-liquefaction pilot plants, oil feed tubes and suction couch rolls of paper machines, cortical screws and compression hip screws of orthopedic implants, and Jewett nails.

The principal types of elevated-temperature mechanical failure are creep and stress rupture, stress relaxation, low- and high-cycle fatigue, thermal fatigue, tension overload, and combinations of these, as modified by environment. This article briefly reviews the applied aspects of creep-related failures, where the mechanical strength of a material becomes limited by creep rather than by its elastic limit. The majority of information provided is applicable to metallic materials, and only general information regarding creep-related failures of polymeric materials is given. The article also reviews various factors related to creep behavior and associated failures of materials used in high-temperature applications. The complex effects of creep-fatigue interaction, microstructural changes during classical creep, and nondestructive creep damage assessment of metallic materials are also discussed. The article describes the fracture characteristics of stress rupture. Information on various metallurgical instabilities is also provided. The article presents a description of thermal-fatigue cracks, as distinguished from creep-rupture cracks.

This article addresses dies and die materials used for hot forging in vertical presses, hammers, and horizontal forging machines (upsetters). It reviews the properties of die materials for hot forging, including good hardenability, resistance to wear, plastic deformation, thermal fatigue, and mechanical fatigue. The article describes heat treating practices commonly employed for chromium- and tungsten-base AISI hot-work tool steels. It discusses the fabrication of impression dies, and the advantages and disadvantages of cast dies. The article concludes with a discussion on the factors that affect die life and safety precautions to be considered during die construction.

Analysis of the failure of a metal structure or part usually requires identification of the type of failure. Failure can occur by one or more of several mechanisms, including surface damage (such as corrosion or wear), elastic or plastic distortion, and fracture. This leads to a wide range of failures, including fatigue failure, distortion failure, wear failure, corrosion failure, stress-corrosion cracking, liquid-metal embrittlement, hydrogen-damage failure, corrosion-fatigue failure, and elevated-temperature failure. This article describes the classification of fractures on a macroscopic scale as ductile fractures, brittle fractures, fatigue fractures, and fractures resulting from the combined effects of stress and environment.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of low-carbon steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: the intergranular fracture, bending impact fracture, brittle fracture, tensile-test fracture, transgranular fracture, cleavage fracture, delayed fracture, corrosion fatigue, inclusion morphology, fatigue crack propagation, and in-service fatigue fracture of various automotive components. These components include tie rod adjusting sleeves, automotive bolts, hydraulic jack shafts, crank handle collars, boiler tubes, drive shafts, bicycle pedal axles, lift-truck hydraulic-piston rods, and steel springs.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of AISI/SAE alloy steels (4xxx steels) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the brittle fracture, ductile fracture, impact fracture, fatigue fracture surface, reversed torsional fatigue fracture, transgranular cleavage fracture, rotating bending fatigue, tension-overload fracture, torsion-overload fracture, slip band crack, crack growth and crack initiation, crack nucleation, microstructure, hydrogen embrittlement, sulfide stress-corrosion failure, stress-corrosion cracking, and hitch post shaft failure of these steels. The components considered in the article include tail-rotor drive-pinion shafts, pinion gears, outboard-motor crankshafts, bull gears, diesel engine bearing cap bolts, splined shafts, aircraft horizontal tail-actuator shafts, bucket elevators, aircraft propellers, helicopter bolts, air flasks, tie rod ball studs, and spiral gears.

Cast stainless steels are usually specified on the basis of composition by using the alloy designation system established by the Alloy Casting Institute. This article discusses the corrosion behavior of heat-resistant alloys due to oxidation, sulfidation, and carburization. It describes the influence of the metallurgy of corrosion-resistant stainless steels on general corrosion, intergranular corrosion, localized corrosion, corrosion fatigue, and stress corrosion.

Stainless steels are used for medical implants and surgical tools due to the excellent combination of properties, such as cost, strength, corrosion resistance, and ease of cleaning. This article describes the classifications of stainless steels, such as austenitic stainless steels, martensitic stainless steels, ferritic stainless steels, precipitation-hardening stainless steels, and duplex stainless steels. It contains a table lists common medical device applications for stainless steels. The article discusses the physical metallurgy, and physical and mechanical properties of the stainless steels. Medical device considerations for stainless steels, such as fatigue strength, corrosion resistance, and passivation techniques, are reviewed. The article describes the process features of the implant-grade stainless steels, including type 316L, type 316LVM, nitrogen-strengthened, ASTM F1314, ASTM F1586, ASTM F2229, and ASTM F2581 stainless steels.

This article discusses the various tests applied to a thermal barrier coating system and to the zirconia layer to establish thermomechanical, environmental stability, and thermal design properties such as coefficient of thermal expansion, specific heat, and thermal transport properties. Thermal fatigue testing and the test for evaluating oxidation resistance of the bond coat is also discussed.