Chemical analysis is a critical part of any failure investigation. With the right planning and proper analytical equipment, a myriad of information can be obtained from a sample. This article presents a high-level introduction to techniques often used for chemical analysis during failure analysis. It describes the general considerations for bulk and microscale chemical analysis in failure analysis, the most effective techniques to use for organic or inorganic materials, and examples of using these techniques. The article discusses the processes involved in the chemical analysis of nonmetallics. Advances in chemical analysis methods for failure analysis are also covered.

This article describes the methodology for performing a failure modes and effects analysis (FMEA). It explains the methodology with the help of a hot water heater and provides a discussion on the role of FMEA in the design process. The article presents the analysis procedures and shows how proper planning, along with functional, interface, and detailed fault analyses, makes FMEA a process that facilitates the design throughout the product development cycle. It also discusses the use of fault equivalence to reduce the amount of labor required by the analysis. The article shows how fault trees are used to unify the analysis of failure modes caused by design errors, manufacturing and maintenance processes, materials, and so on, and to assess the probability of failure mode occurrence. It concludes with information on some of the approaches to automating the FMEA.

This article reviews the analytical techniques most commonly used in plastic component failure analysis. These include the Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and dynamic mechanical analysis. The descriptions of the analytical techniques are supplemented by a series of case studies that include pertinent visual examination results and the corresponding images that aid in the characterization of the failures. The article describes the methods used for determining the molecular weight of a plastic resin. It explains the use of mechanical testing in failure analysis and also describes the considerations in the selection and use of test methods.

This article provides information on the development of finite element analysis (FEA) and describes the general-purpose applications of FEA software programs in structural and thermal, static and transient, and linear and nonlinear analyses. It discusses special-purpose finite element applications in piping and pressure vessel analysis, impact analysis, and microelectronics. The article describes the steps involved in the design process using the FEA. It concludes with two case histories that involve the use of FEA in failure analysis.

This article begins with a discussion on the criteria for evaluating computer programs for composites structural analysis, including database capabilities, types of engineering calculations supported, interface and operating systems, and technical support. It describes the capabilities of programs, such as CompositePro, ESAComp, and V-Lab that provide a graphical interface, built-in databases, and integrated modules for the different types of analyses. The article reviews the modules of other programs used for composite analysis. The programs include ASCA, CADEC, CoDA, COMPASS, ESDU, LAP, PROMAL, and SACL. The article concludes with information on on-line programs and recourses.

When complex designs, transient loadings, and nonlinear material behavior must be evaluated, computer-based techniques are used. This is where the finite-element analysis (FEA) is most applicable and provides considerable assistance in design analysis as well as failure analysis. This article provides a general view on the applicability of finite-element modeling in conducting analyses of failed components. It highlights the uses of finite-element modeling in the area of failure analysis and design, with emphasis on structural analysis. The discussion covers the general development and both general- and special-purpose applications of FEA. The special-purpose applications of FEA covered are piping and pressure vessel analysis, impact analysis, and microelectronic and microelectromechanical systems analysis. The article provides case histories that involved the use of FEA in failure analysis.

Corrosion is the deterioration of a material by a reaction of that material with its environment. The realization that corrosion control can be profitable has been acknowledged repeatedly by industry, typically following costly business interruptions. This article describes the electrochemical nature of corrosion and provides the typical analysis of environmental- and corrosion-related failures. It presents common methods of testing of laboratory corrosion and discusses the processes involved in the prevention of environmental- and corrosion-related failures of metals and nonmetals.

This article describes the historical background, uncertainties in structural parameters, classifications, and application areas of probabilistic analysis. It provides a discussion on the basic definition of random variables, some common distribution functions used in engineering, selection of a probability distribution, the failure model definition, and a definition of the probability of failure. The article also explains the solution techniques for special cases and general solution techniques, such as first-second-order reliability methods, the advanced mean value method, the response surface method, and Monte Carlo sampling. A brief introduction to importance sampling, time-variant reliability, system reliability, and risk analysis and target reliabilities is also provided. The article examines the various application problems for which probabilistic analysis is an essential element. Examples of the use of probabilistic analysis are presented. The article concludes with an overview of some of the commercially available software programs for performing probabilistic analysis.

This article provides an overview of common analytical tools used as part of the process of providing practical information regarding the causes of a coating problem or failure. The common analytical tools include Fourier transform infrared spectroscopy, differential scanning calorimetry, scanning electron microscopy-energy dispersive X-ray spectroscopy, chromatography, and electrochemical impedance spectroscopy. Test cabinets and standard test environments for laboratory analysis are reviewed. The article describes non-standard simulation testing and case studies of simulated environments for coating failure analysis.

Elastomers belong to a group of materials known as polymers that acquire their properties and strength from their molecular weight, chain entanglements, and crystalline regions. This article focuses on the use of elastomers as seals and describes its performance capabilities from the point of a sealant. The important technical concepts that define the performance capabilities of the elastomeric part include polymer architecture (molecular building blocks), compounding (the ingredients within the polymer), and vulcanization of the elastomer shape. The article discusses the aggressiveness of the chemical environment, temperature, and minor constituents in the environment and in the material itself that affect the chemical resistance of the elastomer. It provides a discussion on performance evaluation methods, namely, immersion testing and application specific testing that are determined using ISO and ASTM standards. The article concludes with information on elastomer failure modes and failure analysis.

This article discusses the conditions for collapse in center-cracked panels and describes the energy criterion for fracture. Measurement of toughness of any material by means of tensile and crack test is discussed. The procedures to be followed for linear elastic fracture mechanics cases are reviewed, along with elastic-plastic fracture mechanics and plastic fracture mechanics procedures with the aid of residual strength diagram. The article also explains the geometry factors needed to determine the toughness of materials.

This article covers the three most popular techniques used to characterize the very outermost layers of solid surfaces: Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Some of the more important attributes are listed for preliminary insight into the strengths and limitations of these techniques for chemical characterization of surfaces. The article describes the basic theory behind each of the different techniques, the types of data produced from each, and some typical applications. Also discussed are the different types of samples that can be analyzed and the special sample-handling procedures that must be implemented when preparing to do failure analysis using these surface-sensitive techniques. Data obtained from different material defects are presented for each of the techniques. The examples presented highlight the typical data sets and strengths of each technique.

This article provides guidelines for the assessment of model quality in materials science and engineering. It discusses the fundamentals of model quality assessment and the calibration of mechanistic material models. The article reviews the considerations for the model verification during software implementation planning to identify suitable programs, software components, and programming languages. It describes the validity tests used in model validation, including boundary-value tests, degenerate problem tests, sensitivity tests, and benchmarking. The article also presents an example of model calibration, verification, and validation for the prediction of martensite start temperature of steels.

This article provides information on the chemical characterization of surfaces by Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion mass spectrometry (TOF-SIMS). It describes the basic theory behind each of these techniques, the types of data produced from each, and some typical applications. The article explains the strengths of AES, XPS, and TOF-SIMS based on data obtained from the surface of a slightly corroded stainless steel sheet.

This article provides the framework for the investigation of bridge failures. It explains the types of bridge loading and presents the regulatory provisions for bridges. Some bridge failures in the U.S. that resulted in significant changes in bridge manufacturing, design, regulation, and/or maintenance are also discussed. In addition, the article provides information on traffic damage and fatigue cracking that result in bridge failures. The need for steels with better fracture toughness in bridge design is also discussed.

This article provides an overview of the electrochemical nature of corrosion and analyzes corrosion-related failures. It describes corrosion failure analysis and discusses corrective and preventive approaches to mitigate corrosion-related failures of metals. These include: change in the environment; change in the alloy or heat treatment; change in design; use of galvanic protection; use of inhibitors; use of nonmetallic coatings and liners; application of metallic coatings; use of surface treatments, thermal spray, or other surface modifications; corrosion monitoring; and preventive maintenance.

The article commences with an overview of short-term and long-term mechanical properties of polymeric materials. It discusses plasticization, solvation, and swelling in rubber products. The article further describes environmental stress cracking and degradation of polymers. It illustrates how surface degradation of a plain strain tension specimen alters the ductile brittle transition in polyethylene creep rupture. The article concludes with information on the effects of temperature on polymer performance.

Modern, solids-based computer-aided design/computer-aided manufacturing (CAD/CAM) systems provide a good share of what is needed for companies to develop products using modern methods. This article provides a brief history and an overview of CAD technology. Form features combined with constraint parameters have greatly simplified how designers work with solid modelers to design parts and assemblies. The article describes four types of constraints: numeric, geometric, algebraic, and attributes. It presents a discussion on data associativity and assembly design used in CAD system. The article provides information on the applications of CAD systems, including integrated product development, drafting and product documentation, product visualization, mechanical analysis, and numerical control programming.

This article focuses on the modes of operation, physical basis, sample requirements, properties characterized, advantages, and limitations of the characterization methods used to evaluate the physical morphology and chemical properties of component surfaces for medical devices. These methods include light microscopy, scanning electron microscopy, atomic force microscopy, energy-dispersive X-ray spectroscopy, Auger electron spectroscopy, secondary ion mass spectrometry, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy.