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Published: 01 January 1993
Fig. 3 Maximum temperature versus mass of exothermic compound (characteristic curve). A particular exothermic compound will produce a single characteristic curve for a given joint mass and configuration. Source: Ref 6
More
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001391
EISBN: 978-1-62708-173-3
... of the process, and illustrates a typical arrangement for the exothermic brazing of tube. It provides information on the exothermic compounds used for brazing refractory metals and aluminum alloys. aluminum alloys exothermic brazing exothermic compounds molten filler metal refractory metals solid...
Abstract
Exothermic brazing is a process that utilizes the heat produced in a solid-state chemical reaction to melt a conventional filler metal or to produce molten filler metal as a product of the reaction. This article provides the pros and cons of exothermic brazing, describes procedure of the process, and illustrates a typical arrangement for the exothermic brazing of tube. It provides information on the exothermic compounds used for brazing refractory metals and aluminum alloys.
Image
Published: 01 January 1993
Fig. 2 Heating versus time characteristics for exothermic brazing. Larger masses require longer times to heat up and achieve lower maximum temperatures for a fixed amount of exothermic compound. Source: Ref 2 , 6
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005295
EISBN: 978-1-62708-187-0
... can be pure insulating or exothermic and are attached to the ingot mold walls or to a separate casting that sits on top of the mold. Topping compounds are generally powders placed on top of the ingots immediately after pouring. Sometimes, the topping compound can be in a preformed board much like...
Abstract
When a heat of steel is melted and refined, it is necessary to solidify it into useful forms for further processing or final use. Ingot casting remains the preferred method for certain specialty, tool, forging, and remelted steels. This article discusses the methods, equipment, and theory for pouring, solidifying, and stripping steel ingots. It describes two basic types of pouring methods, top pouring and bottom pouring, and provides information on equipment such as hot tops, ingot molds, and stools. The design of the ingot is dictated by the application and type of steel involved. The article concludes with information on the applications of solidification simulation.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005285
EISBN: 978-1-62708-187-0
... on the type and size of the melting unit. Typical fluxing compounds employed Table 1 Typical fluxing compounds employed Compound Fluidizer (F) thickener (T) Oxide surfactant Chemically active Exothermic Gas released Element added AlF 3 F … X … … … CaCl 2 F...
Abstract
Dross, which is the oxide-rich surface that forms on melts due to exposure to air, is a term that is usually applied to nonferrous melts, specifically the lighter alloys such as aluminum or magnesium. This article describes dross formation and ways to reduce it, the economic implications of dross, and in-plant enhancement or recovery of dross. It discusses the influence of the melter type on dross generation and the influence of charge materials and operating practices on melt loss. Fluxing is a word applied in a broad sense to a number of melt-treating methods. The article also discusses the in-furnace treatment with chemical fluxes.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005300
EISBN: 978-1-62708-187-0
... (1564 to 2442 °F); and the melting point of the sulfates ranges from 859 to 1450 °C (1578 to 2642 °F). Oxidizing compounds are used to promote exothermic chemical reactions. They react with the smallest molten aluminum particles that are present in the dross, yielding aluminum oxides as well...
Abstract
Aluminum fluxing is a step in obtaining clean molten metal by preventing excessive oxide formation, removing nonmetallic inclusions from the melt, and preventing and/or removing oxide buildup on furnace walls. This article discusses the solid fluxes and gas fluxes used in foundries. It reviews the classification of solid fluxes depending on their use and function at the foundry operation. These include cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article also examines the operational practices and applications of the flux injection in the foundries. It describes the applications of the aluminum fluxing such as crucible furnaces, transfer ladles, reverberatory furnaces, and holding/casting furnaces.
Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0009016
EISBN: 978-1-62708-187-0
... Thermal Properties of Materials Riser sleeves and topping compounds are classified by thermal properties as exothermic, insulating, and exothermic-insulating. The generalized thermal properties of each of these classifications are shown in Fig. 23 . Fig. 23 Heat loss from a riser...
Abstract
The role of an engineer in designing risers is to make sure that risers provide the feed metal in the right amount, at the right place, and at the right time. This article addresses feed metal volume, riser location, and duration of liquid feed metal. It discusses the three types of feeding systems used in riser design: riser sleeves, topping compounds, and breaker cores.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005848
EISBN: 978-1-62708-167-2
...). If hydrocarbons are added to an atmosphere that is rich in carbon, the surface of steels picks up carbon at elevated temperatures (carburize). Other reasons for using controlled atmosphere chambers are to control the volatilizations of surface compounds or elements, and to eliminate or enhance and extend flux...
Abstract
Controlled atmosphere chambers are used to control the surface chemistry of the metals that are being processed. This article focuses on the various types of controlled atmospheres used in induction heat treating and brazing, namely, inert gas atmospheres based on argon and helium; prepared and commercial nitrogen-base atmospheres; and brazing atmospheres. It provides detailed information on two types of controlled atmosphere chambers: atmosphere and vacuum. The article also describes the selection factors, advantages, and disadvantages of these chambers.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003199
EISBN: 978-1-62708-199-3
... and defined as follows: Class 100—Exothermic Base. Formed by partial or complete combustion of a gas-air mixture; water vapor may be removed to produce a desired dew point Class 200—Prepared Nitrogen Base. An exothermic base with carbon dioxide and water vapor removed Class 300—Endothermic...
Abstract
Control of temperature and furnace atmospheres has become increasingly critical to successful heat treating. Temperature instrumentation and control systems used in heat treating include temperature sensors, controllers, final control elements, measurement instruments, and set-point programmers. This article describes these items and discusses the classifications and control of furnace atmospheres. The article also describes the surface carbon control devices available for the wide variety of furnace atmospheres and evaluation of carbon control. Finally, the article provides a set of guidelines for safety procedures that are common to all industrial heat treating furnace installations.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006672
EISBN: 978-1-62708-213-6
... Melting temperature ( T m ) Polymorphic forms, purity, quality control Polymers T g Indicator of material properties, quality control, effect of additives T m Polymer processing, heat history Exotherm Reactions rate, curing of materials, residual care C p Energy needed...
Abstract
Differential scanning calorimetry (DSC) is the most common thermal technique for polymer characterization. This article provides a detailed account of the various factors and processes involved in DSC. The discussion covers the equipment used, specimen preparation process, calibration requirements, data analysis, and provides examples of the applications and interpretation of DSC.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003014
EISBN: 978-1-62708-200-6
... Abstract Injection molding is a process of forcing or injecting a fluid plastic material into a closed mold. The process generally has the advantages of being more readily automated and of permitting finer part details. Injection-molding compounds are thermoplastic or thermosetting materials...
Abstract
Injection molding is a process of forcing or injecting a fluid plastic material into a closed mold. The process generally has the advantages of being more readily automated and of permitting finer part details. Injection-molding compounds are thermoplastic or thermosetting materials and their composites that are specifically formulated for the injection-molding process. This article discusses the injection molding process, which includes the two basic categories of thermoplastic and thermoset injection molding, and lists the common thermoplastic and thermoset molding compounds and applications. It also describes the operation of the different types of injection molding machines as well as mold design and process controls. The article also describes the selection of injection-moldable thermosets, and provides an overview of part performance, properties, blowing agents, and aesthetic concerns related to thermoplastic structural-foam injection molding.
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005926
EISBN: 978-1-62708-166-5
... Abstract This article provides a detailed discussion on the types of furnace atmospheres required for heat treating. These include generated exothermic-based atmospheres, generated endothermic-based atmospheres, generated exothermic-endothermic-based atmospheres, generated dissociated-ammonia...
Abstract
This article provides a detailed discussion on the types of furnace atmospheres required for heat treating. These include generated exothermic-based atmospheres, generated endothermic-based atmospheres, generated exothermic-endothermic-based atmospheres, generated dissociated-ammonia-based atmospheres, industrial gas nitrogen-base atmospheres, argon atmospheres, and hydrogen atmospheres. Atmospheres for backfilling, partial pressure operation, and quenching in vacuum are also discussed. Furnace atmospheres constitute four major groups of safety hazards in heat treating: fire, explosion, toxicity, and asphyxiation. The article reviews the fundamentals of principal gases and vapors. It describes how the evaluation of the atmospheric requirements of heat treating furnaces is influenced by factors such as cost of operation and capital investment.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003019
EISBN: 978-1-62708-200-6
... Abstract The compression molding process is most commonly called the sheet molding compound (SMC) process in reference to the precursor sheet molding compound material it uses. This article discusses the types of materials used for sheet manufacture, and describes the manufacturing...
Abstract
The compression molding process is most commonly called the sheet molding compound (SMC) process in reference to the precursor sheet molding compound material it uses. This article discusses the types of materials used for sheet manufacture, and describes the manufacturing and processing parameters of SMC components, providing details on tooling and process advantages and limitations. The article provides a general overview of the types of compression molding processes, including structural compression molding and thermoplastic compression molding.
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005928
EISBN: 978-1-62708-166-5
... it is introduced into the furnace. Such control is achieved through the use of atmosphere-control devices. These various devices and instruments can effectively control endothermic, exothermic, nitrogen-methanol, nitrogen-hydrocarbon, and nitrogen-hydrogen-type atmospheres. Fundamentals of Heat Treating...
Abstract
The atmosphere within a furnace chamber is a basic factor in achieving the desired chemical reactions with metals during heat treating. This article presents the fundamentals of heat treating atmospheres, and describes two groups of atmosphere control, namely, furnace atmosphere control and supply atmosphere control. The two basic types of atmospheric supply systems are generated atmospheres and nitrogen-base atmospheres. The article provides a brief overview of the gas reactions associated with oxidation and carbon control to ensure either carburization, or to prevent decarburization. It demonstrates how the carbon potential control is achieved by controlling water vapor concentration, carbon dioxide concentration, or oxygen partial pressure. The article also describes the various devices and analyzers used to monitor sampled gas from furnace atmospheres, namely, chromatographs, oxygen probes, Orsat analyzers, infrared analyzers, dewpoint analyzers, and hot-wire analyzers. Finally, it discusses the advantages, disadvantages, and limitations of these analyzers.
Book Chapter
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003370
EISBN: 978-1-62708-195-5
... if part sections are thick, not uniform. (q) Weak knitlines may develop if compound packing pressure is low. (r) Large mold vents recommended to allow volatiles to escape. (s) Hot molds required to promote cure, crystalline growth. (t) Curing reaction may produce peak exotherm, leading...
Abstract
Molding compounds are plastic materials in varying stages of pellets or granulation that consist of resin, filler, pigments, reinforcement, plasticizers, and other ingredients ready for use in a molding operation. This article describes the material components and physical properties of sheet molding compounds (SMC). The three types of resin paste mixing techniques, such as batch, batch/continuous, and continuous, for an SMC operation are reviewed. The article discusses the design features and functional operations of the two types of SMC machines, namely, continuous-belt and beltless machines. It explains the formulation and processing of bulk molding compounds and reviews molding methods for bulk molding compounds, including compression, transfer, and injection molding. The effects of the fiber type and length and the matrix type on thermoset bulk molding compounds are discussed. It describes the four injection molding processes of injection molding compounds such as feeding, transporting, injecting, and flowing.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003362
EISBN: 978-1-62708-195-5
... resins that they commercialized were first used as casting compounds and coatings. The same resins are now commodity materials that provide the basis for most epoxy formulations (Ref 1 , 2 , and 3 ). Epoxy resins are a class of thermoset materials used extensively in structural and specialty...
Abstract
This article discusses the three basic elements of an epoxy resin formulation that must be understood when selecting a thermoset system. These include base resins, epoxy resin curatives, and modifiers. The article provides examples of epoxy resin formulations that illustrate how raw materials are combined to tailor a formulation to a specific application. It concludes with a discussion on general guidelines for the safe handling of epoxy resins and their associated products.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006137
EISBN: 978-1-62708-175-7
... and using common sintering atmosphere gases are explosion, fire, toxicity, and asphyxiation. atmosphere supply systems inspection maintenance safety and environmental concerns sintering atmosphere generators sintering atmospheres SINTERING ATMOSPHERES (endothermic gas, exothermic gas...
Abstract
This article discusses the requirements for safe design, installation, operation, inspection, testing, and maintenance of sintering atmosphere generators and atmosphere supply systems for both personal and environment safety. The four intrinsic dangers associated with producing and using common sintering atmosphere gases are explosion, fire, toxicity, and asphyxiation.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006535
EISBN: 978-1-62708-207-5
... and/or double fluorides, and oxidizing compounds. Therefore, drossing fluxes are able to react exothermically, generating heat and improving flux wettability. The wetting action of the flux promotes coalescence, which brings the fine aluminum drops tighter to form larger drops that are much easier to recover...
Abstract
There are a wide variety of furnace types and designs for melting aluminum. This article discusses the various types of furnaces, including gas reverberatory furnaces, crucible furnaces, and induction melting furnaces. It describes the classification of solid fluxes: cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article reviews the basic considerations in proper flux selection and fluxing practices. It explains the basic principles of degassing and discusses the degassing of wrought aluminum alloys. The article describes filtration in wrought aluminum production and in shape casting. It also reviews grain refinement in aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article concludes with a discussion on aluminum-silicon modification.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003831
EISBN: 978-1-62708-183-2
... solutions, molten salts, molten metals, and in air, oxygen, or other gaseous compounds at ambient or elevated temperatures. The effects of diffusion and alloying with the base metal during brazing/soldering/welding (and during service) also influence compatibility. For this reason, each brazing filler...
Abstract
Corrosion is often thought of as rusting, the process of deterioration undergone by a metal when it is exposed to air or water. This article provides the fundamentals of joints corrosion and primarily addresses the various forms of corrosion observed in brazed and soldered joints and their causes. It describes the role of proper brazing procedures in controlling corrosion. The article concludes with information on the corrosion resistance of various brazing alloy systems.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006931
EISBN: 978-1-62708-395-9
... Analysis ” in this volume. Figure 1 identifies the interrelationships among composition, structure properties, and morphology. These factors can affect processing, which in turn can strongly affect the ultimate properties or end-use performance of a polymer. Although the compounding step introduces...
Abstract
This article presents tools, techniques, and procedures that engineers and material scientists can use to investigate plastic part failures. It also provides a brief survey of polymer systems and the key properties that need to be measured during failure analysis. It describes the characterization of plastics by infrared and nuclear magnetic resonance spectroscopy, differential scanning calorimetry, differential thermal analysis, thermogravimetric analysis, thermomechanical analysis, and dynamic mechanical analysis. The article also discusses the use of X-ray diffraction for analyzing crystal phases and structures in solid materials.
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