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equilibrium potentials

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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003579
EISBN: 978-1-62708-182-5
..., reduction of dissolved oxygen, metal ion reduction, and metal deposition. The article also presents the standard equilibrium potentials measured at 25 deg C relative to a standard hydrogen electrode for various metal-ion electrodes in a tabular form. electrode potential thermodynamics kinetics...
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003604
EISBN: 978-1-62708-182-5
... Abstract Principles of metallic corrosion play a fundamental role in developing industrial processes that employ corrosion for constructive purposes. This article examines the changes in kinetics that occur with differentially small potential changes around the equilibrium electrode potentials...
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003583
EISBN: 978-1-62708-182-5
... Abstract This article provides a general introduction to the kinetics of aqueous corrosion with an emphasis on electrochemical principles. It describes the thermodynamic basis for corrosion by determining the equilibrium potentials of electrochemical reactions from the Nernst equation. A...
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003580
EISBN: 978-1-62708-182-5
... Abstract A potential pH diagram is a graphical representation of the relations, derived from the Nernst equation, between the pH and the equilibrium potentials (E) of the most probable electrochemical reactions occurring in a solution containing a specific element. This article describes three...
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006522
EISBN: 978-1-62708-207-5
... corrosion resistance and surface treatment. It describes the thermodynamics of equilibrium oxidation processes and non-equilibrium corrosion processes. The article provides a discussion on aluminum oxidation under atmospheric and dynamic conditions. It presents the potential/pH (Pourbaix) diagram for...
Book Chapter

Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0006547
EISBN: 978-1-62708-183-2
... Abstract Overpotential is the current-producing potential difference between a nonequilibrium electrode potential and its corresponding equilibrium value for an electrode reaction. This article provides information on overpotential of an electrode reaction. It contains a table that lists...
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006263
EISBN: 978-1-62708-169-6
... Abstract This article provides a detailed discussion on the heat treatment processes for titanium and titanium alloys. These processes are age hardening, solution treatment, aging, and annealing. The article illustrates the characteristics of equilibrium phase diagrams that are important for...
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001744
EISBN: 978-1-62708-178-8
... relationship between the working-electrode potential and the ratios of the concentrations of the oxidized and reduced species at equilibrium, that is, when the current is zero in the electrolysis. Table 1 Types of reactions in controlled-potential electrolysis and applicable Nernst equations Type...