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epoxy vinyl ester resins

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Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003406
EISBN: 978-1-62708-195-5
... and spray-up process. Workmanship for hand lay-up and spray-up processes is reviewed. The article provides information on the matrix-resin materials used for open molding, including unsaturated polyester resins, epoxy vinyl ester resins, and reinforcements. It explains the component design and short...
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003845
EISBN: 978-1-62708-183-2
... Abstract This article describes the resin and fabrication requirements associated with fiberglass-reinforced plastic equipment. It provides a discussion on various resins and their resistance to various environments. These include polyester, epoxy, epoxy vinyl-ester, and furan and phenolic...
Image
Published: 30 September 2015
Fig. 20 Vinyl ester prepared by diglycidyl ether of bisphenol A epoxy resin and methacrylic acid More
Image
Published: 01 November 1995
Fig. 50 Vinyl ester polymerization. R , backbone of epoxy resin More
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003031
EISBN: 978-1-62708-200-6
... Abstract This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003010
EISBN: 978-1-62708-200-6
... the general and family characteristics of thermosetting resin families, including allyls, aminos (urea formaldehyde and melamine formaldehyde), cyanates, epoxies, polybenzimidazoles, unsaturated polyesters, thermoset polyimides, phenolics, and vinyl esters. It also explains processing methods, including...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006009
EISBN: 978-1-62708-172-6
... unsaturated polyesters in terms of toughness and chemical resistance ( Ref 2 ). Toughness and increased tensile elongation properties in vinyl ester resins come from the epoxy resin backbone. Depending on the epoxy backbone used, the molecular weight of the vinyl ester resin can be changed, which in turn can...
Book Chapter

By Tim Pepper
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003363
EISBN: 978-1-62708-195-5
... of the corrosion-resistant composite industry. In recent years, they have been replaced by isophthalic resins for mildly corrosive applications and bisphenol A epoxy based vinyl esters in more aggressive environments. Currently, BPA fumarates are used almost exclusively in applications requiring exceptional...
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... Thermosetting, or cross-linking, acrylics can be obtained by combining the methacrylate or acrylate esters with reactive nonacrylic polymers. The most common cross-linking agents in use are the epoxy resins, the urea or melamine-formaldehyde resins, and the vinyl resins. Generally, the nonacrylic polymer...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003036
EISBN: 978-1-62708-200-6
.... Vinyl Esters Vinyl esters shrink less and are more chemically resistant than the polyester family. They are prepared by reaction of an unsaturated acid or anhydride with an epoxy. As in the case of polyesters, this resin is too viscous to be easily handled, and the same types of reactive diluents...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003356
EISBN: 978-1-62708-195-5
... mixture will reduce the renewable resource content of the final resin, they should result in higher T g values for the end polymer. The synthesis of maleate half-esters of organic polyols, including NPG and BPA, and the cross linking of the resulting maleate half- esters with a vinyl monomer...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
...-flash aromatic naphtha Long- and short-oil alkyds Chlorinated rubber Acrylics Styrene and vinyl toluene copolymer Silicone resins Some epoxies Chlorinated hydrocarbons Methylene chloride Methyl chloroform Paint removers Terpenes Turpentine Dipentene Pine oil Oils Alkyds Epoxy esters Use...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003417
EISBN: 978-1-62708-195-5
... on fiberglass reinforced polyester resin. When better corrosion resistance is required, vinyl ester resins are used and represent the next largest product segment. Both of these resin types are also available as flame-retardant versions. When a combination of superior mechanical and electrical properties...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003038
EISBN: 978-1-62708-200-6
... in the transverse and longitudinal directions. More than 90% of all pultruded products are fiberglass-reinforced polyester. When better corrosion resistance is required, vinyl ester resins are used. When a combination of superior mechanical and electrical properties is required, epoxy resin is used. Higher...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003351
EISBN: 978-1-62708-195-5
...) market. Polyesters offer a combination of low cost, versatility in many processes, and reasonably good property performance unmatched by any other resin type. The most common orthophthalic types and the premium isophthalic types, bisphenol A fumarate, chloendic, and vinyl ester, are discussed...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006071
EISBN: 978-1-62708-172-6
... and fish oils listed previously. The drying oil can be mixed directly with the pigment (such as red or white lead, with the addition of a metallic dryer) to form the complete coating. Most commonly, however, the drying oil is combined with a resin such as an alkyd, epoxy ester, or polyurethane by heating...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003366
EISBN: 978-1-62708-195-5
... , and 13 ). These areas traditionally used other resins, such as polyesters, vinyl esters, and epoxies. These resins are being replaced with phenolics for specific applications with stringent fire resistance requirements. To participate in the growing market, phenolic resin manufacturers have responded...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006077
EISBN: 978-1-62708-172-6
..., and appliances; and the manufacturing of epoxy vinyl esters. Cycloaliphatic epoxy resins have an epoxy group appended to an aliphatic (nonaromatic) ring structure. All other epoxy resins described earlier have aromatic rings in their structure, which are susceptible to ultraviolet (UV) light radiation...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003403
EISBN: 978-1-62708-195-5
... ºC or 392 ºF) composite tool laminates. Polyester resins have the lowest cost per kilogram of any of these systems, while the vinyl esters are a close second. The costs of epoxies vary depending on the formulation, but are considerably less expensive than the BMI or polycyanate systems...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006044
EISBN: 978-1-62708-172-6
... unsaturation include styrene, vinyl acetate, vinyl versatate, acrylonitrile, and vinylidene chloride ( Fig. 2 ); they are used to widen the cost and/or performance range available with all-acrylic compositions. Vinyl acetate, for example, is copolymerized with acrylic monomers and widely used in resins...