Electroless, or autocatalytic, metal plating is a nonelectrolytic method of deposition from solution that can be plated uniformly over all surfaces, regardless of size and shape. The plating's ability to plate onto nonconductors is an advantage that contributes to the choice of electroless copper in various applications. This article provides information on the bath chemistry and deposit properties of electroless copper and discusses the applications of electroless copper plating, such as printed wiring boards, decorative plating-on-plastic, electromagnetic interference shielding, and hybrid and other advanced applications. It describes two commercial processes, pretreatment and post-treatment. The article reviews the solutions used, controls and control equipment, and performance criteria of electroless copper plating. It concludes with information on the environmental and safety issues associated with electroless copper plating.

This article discusses the occupational health hazards related to industrial protective coating application and removal. It explains the health hazards associated with coating constituents such as lead, cadmium, chromium, arsenic, silica, and asbestos. The article also discusses hazard evaluation, hazard controls, Occupational Safety and Health Administration standards, and industry consensus standards. It concludes with a description of containment systems to prevent environmental exposures from industrial paint removal projects.

Analysis of the failure of a metal structure or part usually requires identification of the type of failure. Failure can occur by one or more of several mechanisms, including surface damage (such as corrosion or wear), elastic or plastic distortion, and fracture. This leads to a wide range of failures, including fatigue failure, distortion failure, wear failure, corrosion failure, stress-corrosion cracking, liquid-metal embrittlement, hydrogen-damage failure, corrosion-fatigue failure, and elevated-temperature failure. This article describes the classification of fractures on a macroscopic scale as ductile fractures, brittle fractures, fatigue fractures, and fractures resulting from the combined effects of stress and environment.

This article describes selected U.S. environmental statutes and regulations that are pertinent to material surface finishers. It provides information on the applicability, requirements, and permitting conditions of the Clean Air Act, the Resources Conservation and Recovery Act, the Superfund Amendments and Reauthorization Act, and the Clean Water Act.

Grinding is an extremely complex process that requires the consideration of a number of elements in order to make a reasonably adroit initial selection of a fluid or fluids for a manufacturing plant. In addition, the disposal of grinding wastes must meet the minimum requirements as recommended by the federal Environmental Protection Agency (EPA) and Resource Conservation and Recovery Act (RCRA) regulations. This article explains the selection considerations of such fluids, as well as the applications and environmental issues related to the grinding processes.

Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.

Alkaline cleaning is a commonly used method for removing a wide variety of soils from the surface of metals. This article focuses on the composition, operating conditions, and test and control of alkaline cleaners, as well as equipment used and their application methods. It describes the mechanisms of alkaline cleaning, such as saponification, displacement, emulsification and dispersion, and metal oxide dissolution. The article concludes with information of the safety and environmental considerations in the usage of alkaline cleaners.

Engineering design should result in a product that performs its function efficiently and economically within the prevailing legal, social, safety, and reliability requirements. This introductory article discusses some key considerations in design, material selection, and manufacturing that a materials engineer should take into account to satisfy such requirements. It includes a brief section on concurrent engineering, which companies use to ensure that all needed input is obtained and addressed concurrently throughout the product lifecycle, including material selection and processing, product design, cost analysis, manufacturing, recyclability, and performance.

This article provides a detailed discussion on the types of furnace atmospheres required for heat treating. These include generated exothermic-based atmospheres, generated endothermic-based atmospheres, generated exothermic-endothermic-based atmospheres, generated dissociated-ammonia-based atmospheres, industrial gas nitrogen-base atmospheres, argon atmospheres, and hydrogen atmospheres. Atmospheres for backfilling, partial pressure operation, and quenching in vacuum are also discussed. Furnace atmospheres constitute four major groups of safety hazards in heat treating: fire, explosion, toxicity, and asphyxiation. The article reviews the fundamentals of principal gases and vapors. It describes how the evaluation of the atmospheric requirements of heat treating furnaces is influenced by factors such as cost of operation and capital investment.

Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals for corrosion and decorative areas, and some plastics. This article discusses the formulation basics of polyurea technology and compares the technology to that of polyurethane and polyurethane/polyurea systems. It addresses performance issues and describes application processing considerations and safety practices of polyurea coating/lining systems.

Solvent cleaning is a surface preparation process that can be accomplished in room temperature baths (cold cleaning ) or by condensing vapors of a solvent on a workpiece (vapor degreasing). This article provides a detailed discussion on solvents, equipment, process limitations and applications, and safety and health hazards of cold cleaning and vapor degreasing. It also includes information on control of contamination, conservation and recovery of solvent, and disposal of solvent wastes.

This article provides a description of the classification, industrial applications, microstructures, physical, chemical, corrosion, and mechanical properties of zirconium and its alloys. It discusses the formation of oxide films and the effects of water, temperature, and pH on zirconium. The delayed hydride cracking of zirconium is also described. The article provides information on the resistance of zirconium to various types of corrosion, including pitting corrosion, crevice corrosion, intergranular corrosion, galvanic corrosion, microbiologically induced corrosion, erosion-corrosion, and fretting corrosion. The article explains the effects of tin content in zirconium and effects of fabrication on corrosion. Corrosion control measures for all types of corrosion are also highlighted. The article concludes with information on the safety precautions associated with handling of zirconium.

Product design greatly influences the recycling and reuse of manufacturing materials. This article presents a design for recycling strategy based on ease of disassembly, minimizing process scrap, using readily recyclable materials, and labelling or otherwise identifying parts. It also discusses the concept of life-cycle analysis (LCA), a quantitative accounting of the environmental and economic costs of using a given material and the energy required to make, distribute, operate, and eventually dispose of the host product and its constituent materials. An important but often overlooked step in the LCA process is to identify potential improvement pathways.

This article begins with a discussion on the environmental factors that induce corrosion in magnesium alloys. It reviews the factors that determine the severity of different forms of localized corrosion, namely, galvanic corrosion, corrosion fatigue, and stress-corrosion. The article discusses the corrosion protection in magnesium assemblies and the protective coating systems used in corrosion protection practices. The protection schemes for specific applications and production of novel magnesium alloys with improved corrosion resistance are also described. The article concludes with a discussion on corrosion of bulk vapor-deposited alloys and magnesium-matrix composites.

Environmental and worker health regulations have increased the costs associated with cadmium coating application and cadmium-beating waste disposal, thus creating economic incentives for industrial users to seek cadmium plating replacements. This article presents a cadmium replacement identification matrix that includes information on the specifications, corrosion control performance, environment-assisted cracking, coating lubricity, environmental and worker health regulations, and cost and performance factors for various replacement processes.

Maintenance coating is an important part of any meaningful asset-preservation strategy in facilities producing pulp and paper and other chemicals. This article discusses maintenance coating for carbon steel structures and process equipment exposed to normal external pulp and paper mill atmospheric conditions. The important requirements and standards for surface preparation are emphasized and common issues encountered in maintenance coating projects are described.

This article focuses on the types, composition, and applications of phosphate coatings and describes the characteristics of phosphate-coated ferrous and nonferrous materials, including steel and aluminum. It addresses five successive process fundamentals: cleaning, rinsing, phosphating, rinsing after phosphating, and chromic acid rinsing. The article describes the techniques for controlling the chemical composition of various phosphating solutions. It discusses the equipment and factors that influence equipment requirements in immersion and spray systems. The article also describes the controlling procedures of coating weight and crystal size. It provides guidelines for choosing phosphate coatings based on application, coating weight requirements, and recommended process parameters. The article concludes with a discussion on safety precautions and the treatment of effluents from phosphating plants.

Autoclave molding is a process used to impart a controlled heat and pressure cycle cure to a layup. This article describes the materials used for preparing a layup, including peel ply, separator, bleeder, barrier, breather, dam, and vacuum bag. It describes the major elements and functions of an autoclave system, including pressure vessel, gas stream heating and circulation sources, gas stream pressurizing systems, vacuum systems, control systems, and loading systems. The article includes information about modified autoclaves for specialized applications and safety practices in autoclave molding. It also describes the tooling configuration and type of tooling which includes aluminum and steel tooling, electroformed nickel tooling, graphite-epoxy tooling, and elastomeric tooling.

Very high density materials are used for such applications as counterweights and radiation shields. This article focuses on the metallurgy, processing, properties, fabrication, design considerations, health and safety considerations, and applications of the most commonly used very high density materials: depleted uranium and tungsten and their alloys.

This article describes various quenchants, namely, water and inorganic salt solutions, polymers (polyvinyl alcohol, polyalkylene glycol, polyethyl oxazoline, polyvinyl pyrrolidone and sodium polyacrylates), quench oils, and molten salts, which are used for heat treatment of ferrous alloys. It also provides information on the steps for controlling quenching performance for polymer quenchants and oils with an emphasis on measuring quenchant performance, safety measures, and oxidation.