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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001332
EISBN: 978-1-62708-173-3
... Abstract Welding and joining processes are essential for the development of virtually every manufactured product. This article discusses the fundamentals of fusion welding processes, with an emphasis on the underlying scientific principles. It reviews the role of energy-source intensity...
Abstract
Welding and joining processes are essential for the development of virtually every manufactured product. This article discusses the fundamentals of fusion welding processes, with an emphasis on the underlying scientific principles. It reviews the role of energy-source intensity and the width of the heat-affected zone in fusion welding processes. The article contains figures from which the properties of any heat source can be estimated readily.
Book Chapter
Radial Distribution Function Analysis
Available to PurchaseSeries: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001762
EISBN: 978-1-62708-178-8
..., in principle, a data set can be obtained by using a fixed wavelength and scanning θ (angle dispersive) or by fixing θ and scanning the wavelength (energy dispersive). Most instruments scan θ; however, new radiation sources for x-rays and neutrons composed of a broad spectrum of high-intensity wavelengths...
Abstract
The diffraction pattern of any material contains structural and chemical property information that can be extracted using radial distribution function analysis. This article provides an introduction to the technique and presents several examples highlighting various ways in which it can be used. It begins with a discussion on the principles of diffraction and scattering and the effectiveness of x-ray, neutron, and electron energy sources for different types of measurements. It provides information on data collection and reduction and explains how to create atomic distribution plots from intensity and scattering angle data. The article also presents application parameters for defining short distances and background intensity and describes a procedure for generating pair distribution functions.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001728
EISBN: 978-1-62708-178-8
... Abstract This article discusses the general principles, optical systems, and emission sources of optical emission spectroscopy for elemental analysis. Changes in the energy of the valence or outer shell electrons result in the atomic lines used in emission spectroscopy. Each possible...
Abstract
This article discusses the general principles, optical systems, and emission sources of optical emission spectroscopy for elemental analysis. Changes in the energy of the valence or outer shell electrons result in the atomic lines used in emission spectroscopy. Each possible combination of electron configurations produces a spectroscopic term that describes the state of the atom. Atomic emission is analytically useful only to the extent that the emission from one atomic species can be measured and its intensity recorded independent of emission from other sources. Emission sources are often designed to minimize molecular emission. Each of the four types of emission sources; arcs, high-voltage sparks, glow discharges, and flames; has a set of physical characteristics with accompanying analytical assets and liabilities. The article also discusses the applications of each type of emission source.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005577
EISBN: 978-1-62708-174-0
... of practical heat intensities used for fusion welding. It contains tables that present information on the thermal diffusivities of common elements and alloys from 20 to 100 °C. energy-source intensity fusion welding steel surface power density thermal diffusivity WELDING AND JOINING processes...
Abstract
The article discusses the fundamentals of fusion welding processes with an emphasis on the underlying scientific principles. It describes how surface temperature varies on steel with surface power densities that range from 400 to 8000 W/cm2. The article illustrates the spectrum of practical heat intensities used for fusion welding. It contains tables that present information on the thermal diffusivities of common elements and alloys from 20 to 100 °C.
Series: ASM Handbook
Volume: 17
Publisher: ASM International
Published: 01 August 2018
DOI: 10.31399/asm.hb.v17.a0006448
EISBN: 978-1-62708-190-0
... MeV. Therefore, in addition to producing radiation that is more penetrating, high-energy sources produce a greater intensity of useful radiation for a given amount of electrical energy consumed. Fig. 9 Effect of tube voltage or electron energy on the efficiency of energy conversion...
Abstract
Radiography is the process or technique of producing images of a solid material on a paper/photographic film or on a fluorescent screen by means of radiation particles or electromagnetic waves of short wavelength. This article reviews the general characteristics and safety principles associated with radiography. There are two main aspects of safety: monitoring radiation dosage and protecting personnel. The article summarizes the major factors involved in both and discusses the operating characteristics of X-ray tubes. It describes the various methods of controlling scattered radiation: use of lead screens; protection against backscatter and scatter from external objects; and use of masks, diaphragms, collimators, and filtration. The article concludes with a discussion on image conversion media, including recording media, lead screens, lead oxide screens, and fluorescent intensifying screens.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006645
EISBN: 978-1-62708-213-6
... as wave, then the proper meaning of the intensity of electromagnetic radiation is the energy per unit area per unit time. If the radiation is being described as particle interaction, then the intensity refers to the number of counts per unit time from the detector. X-rays occur from various sources...
Abstract
This article provides a detailed account of X-ray spectroscopy used for elemental identification and determination. It begins with an overview of the operating principles of X-ray fluorescence (XRF) spectrometer, as well as a comparison of the operating principles of wavelength-dispersive spectrometer (WDS) and energy-dispersive spectrometer (EDS). This is followed by a discussion on the mechanism and effects of X-ray radiation, X-ray emission, and X-ray absorption. The article then discusses components used, operation, and applications of WDS and EDS. Some of the factors and processes involved in sample preparation for XRF analysis are also included. The article further provides information on the practical procedure for and the applications of WDS and EDS qualitative and quantitative analyses.
Book Chapter
Characterization and Modeling of the Heat Source
Available to PurchaseSeries: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005603
EISBN: 978-1-62708-174-0
... electrical resistance is also common for welding of thin material. However, fusion welding using internal joule heating, that is, resistance welding, does not involve the use of a direct heat source. The intensity or energy distribution associated with the direct heat sources may vary dramatically...
Abstract
Three types of energy are used primarily as direct heat sources for fusion welding: electric arcs, laser beams, and electron beams. This article reviews the physical phenomena that influence the input-energy distribution of the heat source for fusion welding. It also discusses several simplified and detailed heat-source models that have been used in the modeling of arc welding, high-energy-density welding, and resistance welding.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006640
EISBN: 978-1-62708-213-6
...-lying excited states almost always produce the most intense emission. The higher the energy of such transitions, the hotter the source required for efficient excitation. The denominator on the right side of Eq 3 is the partition function for the species. The value of the partition function increases...
Abstract
This article is a detailed account of optical emission spectroscopy (OES) for elemental analysis. It begins with a discussion on the historical background of OES and development trends in OES methods. This is followed by a description of the general principles and optical systems of OES, along with various types of emission sources commonly used for OES. Some of the processes involved in calibration and quantification of OES for direct solids analysis by the ratio method are then described. The article ends with a discussion on the applications of each type of emission sources.
Book Chapter
Radiography
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003238
EISBN: 978-1-62708-199-3
... are shorter and there are no extra costs for x-ray film and processing. Field inspection of thick sections is a time-consuming process. Portable x-ray sources generally emit relatively low-energy radiation, up to approximately 400 keV, and also are limited as to the intensity of radiation output...
Abstract
Radiography is a nondestructive-inspection method that is based on the differential absorption of penetrating radiation by the part or test piece (object) being inspected. This article discusses the fundamentals and general applications of radiography, and describes the sources of radiation in radiographic inspection, including X-rays and gamma rays. It deals with the characteristics that differentiate neutron radiography from X-ray or gamma-ray radiography. The geometric principles of shadow formation, image conversion, variation of attenuation with test-piece thickness, and many other factors that govern the exposure and processing of a neutron radiograph are similar to those for radiography using X-rays or gamma rays.
Book Chapter
Energy Sources for Fusion Additive Manufacturing Processes
Available to PurchaseSeries: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006545
EISBN: 978-1-62708-290-7
... energy source to generate melt pool widths on the order of the laser spot size, typically ranging from hundreds of micrometers to several millimeters. E-beams are similar to lasers in that they also provide high intensities over a small spot size but add the additional capability of very rapid, magnetic...
Abstract
Fusion-based additive manufacturing (AM) processes rely on the formation of a metallurgical bond between a substrate and a feedstock material. Energy sources employed in the fusion AM process include conventional arcs, lasers, and electron beams. Each of these sources is discussed, with an emphasis on their principles of operation, key processing variables, and the influence of each source on the transfer of heat and material. Common energy sources used for metals AM processes, particularly powder-bed fusion and directed-energy deposition, are also discussed. Brief sections at the end of the article discuss the factors dictating the choice of each of these energy sources and provide information on alternative sources of AM.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001733
EISBN: 978-1-62708-178-8
... found wide application in elemental identification and determination. The technique depends on the emission of characteristic x-radiation, usually in the 1 - to 60-keV energy range, following excitation of atomic electron energy levels by an external energy source, such as an electron beam, a charged...
Abstract
This article provides an introduction to x-ray spectrometry, and discusses the role of electromagnetic radiation, x-ray emission, and x-ray absorption. It focuses on the instrumentation of wavelength-dispersive x-ray spectrometers, and energy dispersive x-ray spectrometers (EDS) that comprise x-ray tubes, the analyzing system, and detectors. The fundamentals of EDS operation are described. The article also provides useful information on preparation of various samples, explaining the qualitative and quantitative analyses of EDS. It reviews the applications of the x-ray spectrometry.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003250
EISBN: 978-1-62708-199-3
... and the intensities of the various characteristic energies Qualitative analysis (determination of which elements are present) is done by comparing the energies of the x-rays emitted from the sample with the known characteristic x-ray spectra of each element ( Fig. 3 ). Quantitative determination...
Abstract
The overall chemical composition of metals and alloys is most commonly determined by X-ray fluorescence (XRF) and optical emission spectroscopy (OES), and combustion and inert gas fusion analysis. This article provides information on the capabilities, uses, detection threshold and precision methods, and sample requirements. The amount of material that needs to be sampled, operating principles, and limitations of the stated methods are also discussed.
Book Chapter
Electron Probe X-Ray Microanalysis
Available to PurchaseSeries: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001768
EISBN: 978-1-62708-178-8
... volume in an iron target with a beam energy of 20 keV. Source: Ref 7 Most of the energy imparted to the specimen is in the form of heat. However, a small but important fraction of the interactions ionizes the inner shells of the target atoms. The ionized atoms emit x-rays and Auger electrons...
Abstract
Electron probe microanalysis (EPMA) makes it possible to combine structural and compositional analysis in one operation. This article describes the basic concepts of microanalysis and the processing of EPMA that involves the measurement of the characteristic X-rays emitted from a microscopic part of a solid specimen bombarded by a beam of accelerated electrons. It provides information on the various aspects of energy-dispersive spectrometry (EDS) and wavelength-dispersive spectrometry (WDS), and elucidates the qualitative analysis of the major constituents of EDS and WDS. The article includes information on the analog and digital compositional mapping of elemental distribution, and describes the strengths and weaknesses of WDS and EDS spectrometers in X-ray mapping. It also outlines the application of EPMA for solving various problems in materials science.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006639
EISBN: 978-1-62708-213-6
... compared with other common microanalytical techniques that use electron and ion excitation sources. Polymers and plastics can be analyzed because the binding energies of saturated and unsaturated bonds in atoms can be separated. Extremely thin layers, including materials with layered structures, can...
Abstract
This article focuses on the principles and applications of X-ray photoelectron spectroscopy (XPS) for the analysis of elemental and chemical composition. The discussion covers the nomenclature, instruments, and specimen preparation process of XPS. Some of the factors pertinent to the calibration of materials for accurate measurements using XPS are provided, along with some aspects of the accuracy in quantitative analysis by XPS. In addition, the article presents examples of how XPS data can be used to solve problems with surface interactions.
Book Chapter
Digital Imaging–Real-Time, Computed, and Digital Radiography
Available to PurchaseSeries: ASM Handbook
Volume: 17
Publisher: ASM International
Published: 01 August 2018
DOI: 10.31399/asm.hb.v17.a0006459
EISBN: 978-1-62708-190-0
... for an x-ray source. A cobalt-60 source with an activity of 3700 GBq (100 Ci) generates 60,000 photons per second per square millimeter at 1 m with energies of 1.1 and 1.3 MeV. After passing through a 100 mm (4 in.) thick steel specimen, the radiation is attenuated in intensity by a factor of 15. Therefore...
Abstract
Digital radiography is a technique that uses digital detector arrays (linear or area) to capture an X-ray photonic signal and convert it to an electronic signal for display on a computer. This article begins with an overview of real-time radiography and provides a schematic illustration of a typical radioscopic system using an X-ray image intensifier. It discusses the advantages and limitations of real-time radiography. Computed radiography (CR) is one of the radiography techniques that utilizes a reusable detector comprised of photostimuable luminescence (PSL) storage phosphor. The article provides a schematic illustration of a typical storage phosphor imaging plate. It concludes with a discussion on the benefits of digital radiography.
Image
Chart of principal Auger electron energies. Data points indicate the electr...
Available to PurchasePublished: 15 December 2019
Fig. 3 Chart of principal Auger electron energies. Data points indicate the electron energies of the principal Auger peaks from each element. Larger data points represent the most intense peaks for each element. Source: Ref 1 . Courtesy of Physical Electronics, USA
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Image
Schematic illustrations of the three basic ways in which electrical energy,...
Available to PurchasePublished: 31 October 2011
Fig. 5 Schematic illustrations of the three basic ways in which electrical energy, supplied by a power source, can be used to heat and fusion weld a metal, including (a) use of the kinetic energy of electrons and positive ions in an arc to bombard the workpiece and produce heat (in arc welding
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001732
EISBN: 978-1-62708-178-8
... of broad bands, resulting in a high degree of spectral overlap. Source: Ref 1 Quantitative Analysis The fluorescence emission intensity I F for a particular species is directly proportional to its molar concentration, c, according to: (Eq 10) I F = I 0 k Φ F ϵ b c...
Abstract
This article provides an introduction to the molecular fluorescence spectroscopy, and discusses the theory of fluorescence and its application to chemical analysis. It provides information on fluorescence that occurs in organic compounds and inorganic atoms and molecules. The article describes the instruments used in the spectroscopy, namely, radiation sources, sample holders, wavelength selectors, detectors, computers, and ratiometric instruments. The practical considerations include solvent effects, corrected spectra, wavelength calibration, temperature, and scattered light. The article also discusses the uses of some special techniques used in molecular fluorescence spectroscopy.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001771
EISBN: 978-1-62708-178-8
... be used for compound identification. Fig. 8 The iron 2 p 3/2 spectrum showing a model calculation of the deconvolution into component lines whose intensity and energy were rationalized on the basis of multiplet splitting. CG, center of gravity. Source: Ref 14 Shake-up Satellites When...
Abstract
This article provides a detailed account of the principles, instrumentation,and applications of x-ray photoelectron spectroscopy (XPS), a technique used for elemental and compositional analysis of surfaces and thin films. It reviews the nomenclature of energy states and sensitivity of electrons at the surface that are capable of producing peaks in XPS. Additionally, it presents information on the instrumentation and the preparation and mounting of samples for XPS analysis. The article explains qualitative analysis, namely, measuring of shifts in the binding energy of core electrons, multiplet splitting, and the Auger parameter; and quantitative analysis such as depth analysis carried out using XPS. It also discusses the applications of XPS with examples.
Image
Plot of all the x-ray lines in the energy range from 1 to 10 keV observed i...
Available to PurchasePublished: 01 January 1986
Fig. 8 Plot of all the x-ray lines in the energy range from 1 to 10 keV observed in practical EDS. The escape peak associated with the highest intensity line in each family is also plotted. The approximate peak width (FWHM) produced at each keV unit of energy across the spectrum is plotted
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