Search Results for elemental composition analysis

This article describes some of the common elemental composition analysis methods and explains the concept of referee and economy test methods in failure analysis. It discusses different types of microchemical analyses, including backscattered electron imaging, energy-dispersive spectrometry, and wavelength-dispersive spectrometry. The article concludes with information on specimen handling.

This article is an overview of the division Surface Analysis of this volume. The division covers various developed surface-analysis techniques, such as scanning probe and atomic force microscopy. The division focuses on the analysis of surface layers that are less than 100 nm. A quick reference summary of surface-analysis methods is presented in this article.

This article briefly discusses popular techniques for metals characterization. It begins with a description of the most common techniques for determining chemical composition of metals, namely X-ray fluorescence, optical emission spectroscopy, inductively coupled plasma optical emission spectroscopy, high-temperature combustion, and inert gas fusion. This is followed by a section on techniques for determining the atomic structure of crystals, namely X-ray diffraction, neutron diffraction, and electron diffraction. Types of electron microscopies most commonly used for microstructural analysis of metals, such as scanning electron microscopy, electron probe microanalysis, and transmission electron microscopy, are then reviewed. The article contains tables listing analytical methods used for characterization of metals and alloys and surface analysis techniques. It ends by discussing the objective of metallography.

This article provides an overview of the finite-element-based analyses (FEA) of advanced composite structures and highlights key aspects such as the homogenization of materials properties and post-processing of numerical results. It discusses the analysis of composite structures based on micromechanics and macromechanics. The article describes the FEA of 3-D solid elements, 2-D cylindrical shell elements, and 1-D beam elements. It contains a table that lists the commercially available finite element codes related to the analysis of fibrous composite materials. The article presents classical examples of the mechanics of composite materials to illustrate the aspects of multilayered composite structures.

This article provides a general introduction of materials characterization and describes the principles and applications of a limited number of techniques that are most commonly used to characterize the composition and structure of metals used in engineering systems. It briefly describes the classification of materials characterization methods including, bulk elemental characterization, bulk structural characterization, microstructural characterization, and surface characterization. Further, the article reviews the selection of materials characterization methods most commonly used with metals.

Detailed analyses and test correlations are typically required to support design development, structural sizing, and certification. This article addresses issues concerning building block levels ranging from design-allowables coupons up through subcomponents, as these levels exhibit a wide variety of test-analysis correlation objectives. At these levels, enhanced analysis capability can be used most effectively in minimizing test complexity and cost while also reducing design weight and risk. The article discusses the examples of tests for which good correlative capability has shown significant benefit. These include notched (open and/or filled hole) tension and compression, inter/intralaminar shear and tension, and pin bearing.

The overall chemical composition of metals and alloys is most commonly determined by X-ray fluorescence (XRF) and optical emission spectroscopy (OES), and combustion and inert gas fusion analysis. This article provides information on the capabilities, uses, detection threshold and precision methods, and sample requirements. The amount of material that needs to be sampled, operating principles, and limitations of the stated methods are also discussed.

This article discusses the methods of analyzing the directional dependence of the mechanical properties of composites, especially those perpendicular to the major plane of the laminate. It provides a description of the common indirect load cases and direct out-of-plane load cases. The article concludes with a discussion on composite materials that are reinforced in the z-direction (also known as three-dimensional, or 3-D composites).

This article is a detailed account of the principles of electron-excited X-ray microanalysis. It begins by discussing the physical basis of electron-excited X-ray microanalysis and the advantages and limitations of energy dispersive spectrometry (EDS) and wavelength dispersive spectrometry for electron probe microanalysis. Key concepts for performing qualitative analysis and quantitative analysis by electron-excited X-ray spectrometry are then presented. Several sources that lead to measurement uncertainties in the k-ratio/matrix corrections protocol are provided, along with the significance of the raw analytical total. Sections on accuracy of the standards-based k-ratio/matrix corrections protocol with EDS and processes of analysis when severe peak overlap occurs are also included. The article provides information on low-atomic-number elements, iterative qualitative-quantitative analysis for complex compositions, and significance of standardless analysis in the EDS software. It ends with a section on the processes involved in elemental mapping for major and minor constituents.

X-ray spectroscopy is generally accepted as the most useful ancillary technique that can be added to any scanning electron microscope (SEM), even to the point of being considered a necessity by most operators. While “stand-alone” x-ray detection systems are used less frequently in failure analysis than the more exact instrumentation employed in SEMs, the technology is advancing and is worthy of note due to its capability for nondestructive analysis and application in the field. This article begins with information on the basis of the x-ray signal. This is followed by information on the operating principles and applications of detectors for x-ray spectroscopy, namely energy-dispersive spectrometers, wavelength-dispersive spectrometers, and handheld x-ray fluorescence systems. The processes involved in x-ray analysis in the SEM and handheld x-ray fluorescence analysis are then covered. The article ends with a discussion on the applications of x-ray spectroscopy in failure analysis.

This article discusses the capabilities and limitations of various material characterization methods that assist in the selection of a proper analytical tool for analyzing particulate materials. Commonly used methods are microanalysis, surface analysis, and bulk analysis. The techniques used for performing microanalysis include scanning electron microscopy and electron probe X-ray microanalysis. The article describes surface analysis techniques, including Auger electron spectroscopy, X-ray photoelectron spectroscopy, and ion-scattering spectroscopy. Bulk analysis techniques, such as X-ray powder diffraction, inductively coupled plasma atomic emission spectroscopy, atomic absorption spectroscopy, and atomic fluorescence spectrometry, are also discussed.

This article explores why structural element and subcomponent testing are conducted. It discusses the different types of failure modes in composites, and provides information on the testing methodology, fixturing, instrumentation, and data reporting. The article reviews various standard elements used to characterize composite materials for the various failure modes. Simple structural-element testing under in-plane unidirectional, multidirectional, and combined loading, as well as out-of-plane loading are discussed. Simple bolted and bonded joints, as well as data correlation are reviewed with analytical predictions. The article also provides a list of the ASTM testing standards applicable at the element level of testing for both polymer-matrix composites and metal-matrix composites. It concludes with a discussion on durability and damage tolerance testing.

This article describes the role of the full-scale testing in assessing composite structural systems of aircraft and qualifying them for in-service use. The typical full-scale tests include static, durability, and damage tolerance. The article discusses the parameters to be considered when developing the basic requirements for the static test. These parameters consist of material considerations, moisture and temperature effects, structure size, load application alternatives, instrumentation requirements, test procedure considerations, ultimate load requirements, and test results correlation. The basic requirements common for durability and damage tolerance tests, including environmental effects and inspection requirements, are also discussed.

This article focuses on the modes of operation, physical basis, sample requirements, properties characterized, advantages, and limitations of the characterization methods used to evaluate the physical morphology and chemical properties of component surfaces for medical devices. These methods include light microscopy, scanning electron microscopy, atomic force microscopy, energy-dispersive X-ray spectroscopy, Auger electron spectroscopy, secondary ion mass spectrometry, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy.

Electron probe microanalysis (EPMA) makes it possible to combine structural and compositional analysis in one operation. This article describes the basic concepts of microanalysis and the processing of EPMA that involves the measurement of the characteristic X-rays emitted from a microscopic part of a solid specimen bombarded by a beam of accelerated electrons. It provides information on the various aspects of energy-dispersive spectrometry (EDS) and wavelength-dispersive spectrometry (WDS), and elucidates the qualitative analysis of the major constituents of EDS and WDS. The article includes information on the analog and digital compositional mapping of elemental distribution, and describes the strengths and weaknesses of WDS and EDS spectrometers in X-ray mapping. It also outlines the application of EPMA for solving various problems in materials science.

Identification of alloys using quantitative chemical analysis is an essential step during a metallurgical failure analysis process. There are several methods available for quantitative analysis of metal alloys, and the analyst should carefully approach selection of the method used. The choice of appropriate analytical techniques is determined by the specific chemical information required, the condition of the sample, and any limitations imposed by interested parties. This article discusses some of the commonly used quantitative chemical analysis techniques for metals. The discussion covers the operating principles, applications, advantages, and disadvantages of optical emission spectroscopy (OES), inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray spectroscopy, and ion chromatography (IC). In addition, information on combustion analysis and inert gas fusion analysis is provided.

This article discusses several purposes and types of materials characterization techniques. Some of the factors to be considered when selecting appropriate characterization methods are described. The article also presents the scope and organization of this volume.

Affordability is the key issue facing design engineers and manufacturers of composite components for current and next-generation aircraft, spacecraft, propulsion systems, and other advanced applications. This article describes the software tools available for modeling and analyzing costs associated with design and manufacturing options for advanced composites programs. It presents an example of a composite exhaust nozzle shroud where the design and manufacture options were analyzed and adjusted, based on the use of cost analysis tools. The article also lists some of the attributes found in various cost modeling software and the potential cost benefits.

Delamination is one of the most commonly observed failure modes in composite materials. This article describes the three fundamental fracture failure modes of composite delamination, namely, opening, in-plane shearing, and tearing or scissoring shearing modes. It discusses the characterization and analysis of delamination. The article also reviews the prediction of delamination factors, such as flexbeam fatigue life, and skin/stiffener pull-off strength and life.

Coatings and thin films can be studied with surface analysis methods because their inherently small depth allows characterization of the surface composition, interface composition, and in-depth distribution of composition. This article describes principles and examples of common surface analysis methods, namely, Auger electron spectroscopy, X-ray photoelectron spectroscopy, ion scattering spectroscopy, secondary ion mass spectroscopy, and Rutherford backscattering spectroscopy. It also provides useful information on the applications of surface analysis.