Ores, which consist of the primary valuable mineral, predominant gangue content, valuable by-products, and detrimental impurities, are extracted and directed to mineral processing. This article describes the mineral processing facilities, such as crushers, grinders, concentrators, separators, and flotation devices that are used for particle size reduction, separation of particles according to their settling rates in fluids and dewatering of concentrate particles. It explains the basic principles, flow diagrams, ore concentrate preparation methods, and equipment of major types of metallurgical processes, including pyrometallurgical, hydrometallurgical, and electrometallurgical processes.

The electronic microcircuit industry has placed severe demands on metal suppliers to provide metals of the highest reproducible purity attainable as a result of the constant quest for the true values of physical and chemical properties of metals. This article describes the commonly used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio test methods used to characterize purity. Tables list the values for resistance ratios of zone-refined metals and their corresponding chemical compositions, and provide an example of the detection of impurities to concentrations in the parts per billion range, utilizing a combination of the glow discharge mass spectroscopy method and Leco combustion methods.

This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition. Methods such as precipitation from salt solution and gas, chemical embrittlement, hydride decomposition, and thermite reactions are also discussed. The article also discusses the methods used to produce powders electrolytically and the types of metal powders produced. The physical and chemical characteristics of these powders are also reviewed.

Electrochemical refining is the purification process for producing commercially pure metals from crude metals. This article describes the principles of electrochemical reactions. It discusses the physical properties of the basic components of electrochemical refining cell. The article also explains the engineering considerations required in the refining process. Theoretical and technological principles of electrochemical refining are illustrated, with examples.

This article describes the fundamentals of various techniques used for the production of copper and copper alloy powders. These include atomization (water, air, and gas), oxide reduction, and electrolysis. The article discusses the effects of electrolyte composition and operating conditions on the characteristics of copper and copper alloy powders.

Beryllium is a metal with an unusual combination of physical and mechanical properties that make it particularly effective in optical components, precision instruments, and specialized aerospace applications. Almost all of the beryllium in use is a powder metallurgy (P/M) product. Beginning with an overview of the mining and refining processes of beryllium, this article discusses powder production and consolidation methods, beryllium grades and their designations, and the protective measures that have been enacted to reduce exposure to beryllium.

Nickel alloys electroplated for engineering applications include nickel-iron, nickel-cobalt, nickel-manganese, and zinc-nickel. This article provides the process description and discusses the processing variables, properties, advantages, and disadvantages of nickel-iron, nickel-cobalt, nickel-manganese alloys, and nickel chromium binary and ternary alloys. It also includes information on the environmental, health, and safety considerations for these nickel-base alloys.

This article provides a summary of the conventional technologies used for titanium powder production. It focuses on the various processes for titanium powder production, namely, Hunter, Kroll, Armstrong, MER, TIRO, FFC-Cambridge, Chinuka, and CSIR processes. Employment of titanium powder significantly improves the synthesis of titanium and its alloys.

Zirconium, hafnium, and titanium are produced from ore that generally is found in a heavy beach sand containing zircon, rutile, and ilmenite. This article discusses the processing methods of these metals, namely, liquid-liquid separation process, distillation separation process, refining, and melting. It also discusses the primary and secondary fabrication of zirconium and hafnium and its alloys. The article talks about the metallurgy of zirconium and its alloys with emphasis on allotropic transformation, cold work and recrystallization, anisotropy and preferred orientation, and the role of oxygen. It concludes by providing useful information on the applications of reactor and industrial grades of zirconium alloys.

This article discusses three types of powder-feeder systems that are commonly used throughout the thermal spray (TS) industry: gravity-based devices, rotating wheel devices, and fluidized-bed systems. It provides information on the various mechanical methods for producing powders, namely, crushing, milling, attriting, and machining. The article describes two prime methods of agglomeration. One method uses a binder by way of agglutination, while the other relies on a sintering operation. The article discusses the technology and principles of the processes that relate to thermal spraying, and offers an understanding for choosing particular feedstock materials that are classified based on the thermal spray process, material morphology, chemical nature of the material, and applications. Sieving, the most common method of separating powders into their size fractions, is also reviewed. The article also provides information on the topical areas and precautions to be undertaken to protect the operator from safety hazards.

This article describes the Bayer process for the purification of alumina. The process includes four major stages: digestion, clarification, precipitation, and calcination. The article discusses the aluminum electrolytic process in terms of aluminum electrolysis cell design, magnetohydrodynamic forces, and cathode lining. It reviews the electrochemical reactions and thermodynamics for aluminum electrolysis standard Gibbs. The article also describes the cell operations and cell stability, as well as the key indicators of cell performance. It schematically illustrates the typical costs producing aluminum in an aluminum smelter. The article also discusses various environmental issues, such as fluoride recovery; perfluorocarbons, polycyclic aromatic hydrocarbons, and sulfur emissions; spent pot lining; and development of inert anodes and CO2 emissions.

This article focuses on the recycling of metals including iron and steel, stainless steel, superalloys, nickel, aluminum, copper, precious metals, lead, magnesium, tin, titanium, and zinc. It provides information on the identification and sorting of scrap metals and discusses the equipment and procedures used for small-scale and large-scale scrapping operations.

Many nonferrous metals, including aluminum, nickel, copper, and others, are among the few materials that do not degrade or lose their chemical or physical properties in the recycling process. As a result, these metals can be recycled an infinite number of times. This article focuses on the recycling of nonferrous alloys, namely, aluminum, copper, magnesium, tin, lead, zinc, and titanium, providing details on the sources, consumption and classification of scrap, and the technological trends and developments in recycling.

Nickel and nickel-base alloys are vitally important to modern industry because of their ability to withstand a wide variety of severe operating conditions involving corrosive environments, high temperatures, high stresses, and combinations of these factors. This article discusses the mining and extraction of nickel and describes the uses of nickel. It discusses the categories of nickel-base alloys, including wrought corrosion-resistant alloys, cast corrosion-resistant alloys, heat-resistant alloys (superalloys), and special-purpose alloys. The article covers the corrosion resistance of nickel with the inclusion of varying alloying elements. It provides useful information on the behavior of nickel and nickel alloys in specific environments describes its corrosion resistance in certain acids, alkalis, and salts.

Alloy phase diagrams are useful for the development, fabrication, design and control of heat treatment procedures that will produce the required mechanical, physical, and chemical properties of new alloys. They are also useful in solving problems that arise in their performance in commercial applications, thus improving product predictability. This article describes different equilibrium phase diagrams (unary, binary, and ternary) and microstructures, description terms, and general principles of reading alloy phase diagrams. Further, the article discusses plotting schemes; areas in a phase diagram; and the position and shapes of the points, lines, surfaces, and intersections, which are controlled by thermodynamic principles and properties of all phases that comprise the system. It also illustrates the application of the stated principles with suitable phase diagrams.

Aluminum possesses many characteristics that make it highly compatible with recycling. Production of aluminum from scrap has a number of advantages. This article discusses the technology for the recovery, sorting, and remelting of aluminum. It describes the collection and acquisition of aluminum scrap in transportation, packaging, electrical and electronic, and building and construction sectors. The article reviews the technologies used to accomplish comminution for aluminum: shearing, knife shredding, and swing-hammer shredding. It provides a description of the devices used in scrap sorting, such as hand sorting, air classification, magnetic separation, eddy-current separation, heavy-media separation, and sensor-based sorting. The article also describes thermal processing, refining and casting, and dross processing of aluminum. It provides information on reverberatory and electric furnaces used for melting aluminum.

This article provides a detailed account of the various alkaline and acid plating baths used for electrolytic copper plating. Dilute cyanide and Rochelle cyanide baths, high-efficiency sodium and potassium cyanide baths, alkaline noncyanide copper plating baths, and alkaline copper pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used.

A potential pH diagram is a graphical representation of the relations, derived from the Nernst equation, between the pH and the equilibrium potentials (E) of the most probable electrochemical reactions occurring in a solution containing a specific element. This article describes three types of reactions for calculation and construction of E-pH diagrams: electrochemical reactions of pure charge (electron) transfer; reactions involving both electron and solvated proton transfer; and acid-base reactions of pure solvated proton transfer. It illustrates the practical use of E-pH diagrams for temperature aqueous solutions and adsorbed species and in prediction of corrosion of nickel and copper.

Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also discusses selective plating, electroforming, and other processes and where they are typically used.

This article discusses the fundamentals of thermal vaporization and condensation and provides information on the various vaporization sources and methods of vacuum deposition. It offers an overview of reactive evaporation and its deposition techniques. The article also explains the advantages, limitations, and applications of vacuum deposition processes. Finally, it provides information on the gas evaporation process, its processing chamber, and related systems.