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Book Chapter
Potential Measurements with Reference Electrodes
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003592
EISBN: 978-1-62708-182-5
... Abstract Electrode potential is a key parameter in the thermodynamic and kinetic processes that drive aqueous corrosion. This article discusses the complexities associated with measuring electrode potential and explains where and how to use reference electrodes to improve measurement accuracy...
Abstract
Electrode potential is a key parameter in the thermodynamic and kinetic processes that drive aqueous corrosion. This article discusses the complexities associated with measuring electrode potential and explains where and how to use reference electrodes to improve measurement accuracy. It describes a three-electrode approach that compensates for measurement error stemming from nonequilibrium conditions. It also examines electrode materials and behaviors and offers insights on selection and operating conditions.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001740
EISBN: 978-1-62708-178-8
... Abstract Potentiometric membrane electrodes are electrochemical devices that can be used to quantify numerous ionic and nonionic species. This class of electrochemical sensors can be divided into ion-selective and gas-sensing membrane electrodes. The first half of this article mainly focuses...
Abstract
Potentiometric membrane electrodes are electrochemical devices that can be used to quantify numerous ionic and nonionic species. This class of electrochemical sensors can be divided into ion-selective and gas-sensing membrane electrodes. The first half of this article mainly focuses on the subclasses, the membrane potential, electrode selectivity limitations and the methods of analysis of the ion-selective membrane electrodes. These methods of analysis include the use of calibration curves, addition techniques, subtraction techniques, and titration. The second half outlines gas sensing membrane electrodes, and discusses important elements that must be considered in addition to the potentiometric membrane electrode to ensure proper electrode response. These elements are reference electrodes, temperature controls, recording of the potential with respect to time, electrode storages, and sample pretreatment. The article also explains the applications of the potentiometric membrane electrodes with the aid of an example.
Book Chapter
Reference Electrodes
Available to PurchaseBook: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003799
EISBN: 978-1-62708-183-2
... Abstract This article discusses a tool for the conversion of measurements made against various reference electrodes at different temperatures. It reviews different electrode potential temperature coefficients, namely, isothermal temperature coefficient and thermal temperature coefficient...
Abstract
This article discusses a tool for the conversion of measurements made against various reference electrodes at different temperatures. It reviews different electrode potential temperature coefficients, namely, isothermal temperature coefficient and thermal temperature coefficient. The article contains a table that lists the electrode potentials and conversion factors for various reference electrodes.
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Test electrodes and electrode holders. (a) Cylindrical electrodes. (b) Flat...
Available to PurchasePublished: 01 January 2003
Fig. 1 Test electrodes and electrode holders. (a) Cylindrical electrodes. (b) Flat disk or sheet electrodes. OD, outside diameter
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Test electrodes. (a) Rotating disk electrodes. (b) Rotating cylinder electr...
Available to PurchasePublished: 01 January 2003
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Soil test cell with three corrosion electrodes and four resistivity electro...
Available to PurchasePublished: 01 January 2006
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Published: 01 January 2006
Fig. 9 Soil corrosion electrodes used in the soil test cell in Fig. 8 .
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Carbon steel electrodes exposed to aerobic and anaerobic natural seawater f...
Available to Purchase
in Microbiologically Influenced Corrosion in Military Environments
> Corrosion: Environments and Industries
Published: 01 January 2006
Fig. 7 Carbon steel electrodes exposed to aerobic and anaerobic natural seawater for 290 days. (a) Aerobic. (b) Aerobic. Scanning electron micrograph of iron-oxide encrusted bacteria enmeshed in corrosion products. (c) Anaerobic. (d) Anaerobic. Scanning electron micrograph of sulfide-encrusted
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Schematics of apparatuses for raising and lowering electrodes. (a) Arrangem...
Available to PurchasePublished: 01 December 2008
Fig. 4 Schematics of apparatuses for raising and lowering electrodes. (a) Arrangement of electrode and mast. (b) Electrode arm arrangement with power-operated electrode holder in which clamp shoe is held in place by a push rod mechanism. (c) Typical arrangement of electrode arm using power
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Effect of arcs on furnace refractories due to electrodes not being vertical...
Available to PurchasePublished: 01 December 2008
Fig. 5 Effect of arcs on furnace refractories due to electrodes not being vertical (a) on section left of center and (b) running too high a tap after meltdown
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Schematic of an ESR furnace with multiple electrodes for large ingot produc...
Available to PurchasePublished: 01 December 2008
Fig. 1 Schematic of an ESR furnace with multiple electrodes for large ingot production
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Comparison of electrodes for conventional and orbital-movement machining pr...
Available to PurchasePublished: 01 January 2006
Fig. 10 Comparison of electrodes for conventional and orbital-movement machining processes
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(a) Sheet-electrode system with curved-face electrodes. (b) Zone of analysi...
Available to Purchase
in Modeling of Thermal-Electrical-Mechanical Coupling in Fusion Welding
> Welding Fundamentals and Processes
Published: 31 October 2011
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Discretized sheet-electrode geometry with spherical tip electrodes. (a) Com...
Available to Purchase
in Modeling of Thermal-Electrical-Mechanical Coupling in Fusion Welding
> Welding Fundamentals and Processes
Published: 31 October 2011
Fig. 9 Discretized sheet-electrode geometry with spherical tip electrodes. (a) Complete geometry. (b) Zoomed view of elements across contact areas
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Published: 31 October 2011
Fig. 14 Tandem gas metal arc welding uses two electrodes in close proximity.
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Classification system for carbon steel flux cored electrodes. The letter “X...
Available to PurchasePublished: 31 October 2011
Fig. 4 Classification system for carbon steel flux cored electrodes. The letter “X” as used in this figure and in electrode classification designations in AWS specification A5.20-79 substitutes for specific designations indicated by this figure. Source: Ref 3
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CAUTION with thoriated electrodes. Statement of appropriate safety precauti...
Available to PurchasePublished: 31 October 2011
Fig. 17 CAUTION with thoriated electrodes. Statement of appropriate safety precautions when using thoriated electrodes, developed by the International Institute of Welding Commission VIII on Health and Safety. Source: Ref 7
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Selected electrodes and guides (nozzles) used in electroslag welding. (a) S...
Available to PurchasePublished: 31 October 2011
Fig. 15 Selected electrodes and guides (nozzles) used in electroslag welding. (a) Single flux-covered tube. (b) Cluster of rods taped together. (c) Flux-covered wing nozzle. (d) Flux-covered wing or web nozzle with two tubes
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